A novel phenylene topology: Total syntheses of zigzag [4]- and [5]phenylene

Christian Eickmeier; Daniel Holmes; Heiko Junga; Adam J. Matzger; Frank Scherhag; Moonsub Shim; K. Peter C. Vollhardt

doi:10.1002/(SICI)1521-3773(19990315)38:6<800::AID-ANIE800>3.0.CO;2-M

A novel phenylene topology: Total syntheses of zigzag [4]- and [5]phenylene

Christian Eickmeier, Daniel Holmes, Heiko Junga, Adam J. Matzger, Frank Scherhag, Moonsub Shim, K. Peter C. Vollhardt

Research output: Contribution to journal › Article › peer-review

Abstract

In agreement with theory, the title compounds 1 and 2, which were prepared by CpCo-catalyzed cycloisomerizations of appropriate oligoalkynylbenzenes, display physical properties that are in contrast with those of the corresponding linear isomers, but that are very similar to those of the angular topomers.

Original language	English (US)
Pages (from-to)	800-804
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	38
Issue number	6
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19990315)38:6<800::AID-ANIE800>3.0.CO;2-M
State	Published - Mar 15 1999
Externally published	Yes

Keywords

Antiaromaticity
Hydrocarbons
Phenylenes
Polycycles
Strained molecules

ASJC Scopus subject areas

General Chemistry

Online availability

10.1002/(SICI)1521-3773(19990315)38:6<800::AID-ANIE800>3.0.CO;2-M

Library availability

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AU - Holmes, Daniel

AU - Junga, Heiko

AU - Matzger, Adam J.

AU - Scherhag, Frank

AU - Shim, Moonsub

AU - Vollhardt, K. Peter C.

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AB - In agreement with theory, the title compounds 1 and 2, which were prepared by CpCo-catalyzed cycloisomerizations of appropriate oligoalkynylbenzenes, display physical properties that are in contrast with those of the corresponding linear isomers, but that are very similar to those of the angular topomers.

KW - Antiaromaticity

KW - Hydrocarbons

KW - Phenylenes

KW - Polycycles

KW - Strained molecules

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A novel phenylene topology: Total syntheses of zigzag [4]- and [5]phenylene

Abstract

Keywords

ASJC Scopus subject areas

Online availability

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