A new route to organic nanotubes from porphyrin dendrimers

Yoonkyung Kim, Michael F. Mayer, Steven C. Zimmerman

Research output: Contribution to journalArticle

Abstract

By chemically cleaving out the core of a dendritic metalloporphyrin coordination polymer, organic nanotubes can be created (see schematic representation). This is made possible by intramolecularly cross-linking the periphery of the oligomer with a ring-closing metathesis reaction prior to coring.

Original languageEnglish (US)
Pages (from-to)1121-1126
Number of pages6
JournalAngewandte Chemie - International Edition
Volume42
Issue number10
DOIs
StatePublished - Mar 10 2003

Keywords

  • Coordination polymers
  • Dendrimers
  • Metathesis
  • Nanotubes
  • Porphyrinoids

ASJC Scopus subject areas

  • Chemistry(all)

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