A metal-free electrocatalyst for carbon dioxide reduction to multi-carbon hydrocarbons and oxygenates

Jingjie Wu, Sichao Ma, Jing Sun, Jake I. Gold, Chandrasekhar Tiwary, Byoungsu Kim, Lingyang Zhu, Nitin Chopra, Ihab N. Odeh, Robert Vajtai, Aaron Z. Yu, Raymond Luo, Jun Lou, Guqiao Ding, Paul J.A. Kenis, Pulickel M. Ajayan

Research output: Contribution to journalArticlepeer-review

Abstract

Electroreduction of carbon dioxide into higher-energy liquid fuels and chemicals is a promising but challenging renewable energy conversion technology. Among the electrocatalysts screened so far for carbon dioxide reduction, which includes metals, alloys, organometallics, layered materials and carbon nanostructures, only copper exhibits selectivity towards formation of hydrocarbons and multi-carbon oxygenates at fairly high efficiencies, whereas most others favour production of carbon monoxide or formate. Here we report that nanometre-size N-doped graphene quantum dots (NGQDs) catalyse the electrochemical reduction of carbon dioxide into multi-carbon hydrocarbons and oxygenates at high Faradaic efficiencies, high current densities and low overpotentials. The NGQDs show a high total Faradaic efficiency of carbon dioxide reduction of up to 90%, with selectivity for ethylene and ethanol conversions reaching 45%. The C2 and C3 product distribution and production rate for NGQD-catalysed carbon dioxide reduction is comparable to those obtained with copper nanoparticle-based electrocatalysts.

Original languageEnglish (US)
Article number13869
JournalNature communications
Volume7
DOIs
StatePublished - Dec 13 2016

ASJC Scopus subject areas

  • Chemistry(all)
  • Biochemistry, Genetics and Molecular Biology(all)
  • Physics and Astronomy(all)

Fingerprint Dive into the research topics of 'A metal-free electrocatalyst for carbon dioxide reduction to multi-carbon hydrocarbons and oxygenates'. Together they form a unique fingerprint.

Cite this