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A manganese catalyst for highly reactive yet chemoselective intramolecular C(sp 3)-H amination
Shauna M. Paradine
, Jennifer R. Griffin
, Jinpeng Zhao
, Aaron L. Petronico
, Shannon M. Miller
,
M. Christina White
Chemistry
Biomedical and Translational Sciences
Research output
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Contribution to journal
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Article
›
peer-review
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Keyphrases
Manganese
100%
Chemoselective
100%
Tert
100%
Amination
100%
Manganese Catalyst
100%
Hydrogen Bonds (H-bonds)
66%
Chemoselectivity
66%
High Selectivity
33%
Mechanistic Studies
33%
Noble Metals
33%
Oxidation Reaction
33%
C-H Bond
33%
High Reactivity
33%
Oxidizable
33%
Rhodium
33%
Base Metals
33%
Aminated
33%
Propargylic
33%
C-H Bond Oxidation
33%
H-abstraction
33%
Nitrenes
33%
C(sp3)-H Bond
33%
C-H Insertion
33%
Chemistry
Chemoselectivity
100%
Manganese
100%
amination
100%
Base
25%
Oxidation Reaction
25%
Mechanistic Study
25%
Rhodium
25%
Noble Metal
25%