A manganese catalyst for highly reactive yet chemoselective intramolecular C(sp 3)-H amination

Keyphrases

• Manganese 100%
• Chemoselective 100%
• Tert 100%
• Amination 100%
• Manganese Catalyst 100%
• Hydrogen Bonds (H-bonds) 66%
• Chemoselectivity 66%
• High Selectivity 33%
• Mechanistic Studies 33%
• Noble Metals 33%
• Oxidation Reaction 33%
• C-H Bond 33%
• High Reactivity 33%
• Oxidizable 33%
• Rhodium 33%
• Base Metals 33%
• Aminated 33%
• Propargylic 33%
• C-H Bond Oxidation 33%
• H-abstraction 33%
• Nitrenes 33%
• C(sp3)-H Bond 33%
• C-H Insertion 33%

Chemistry

• Chemoselectivity 100%
• Manganese 100%
• Noble Metal 25%
• Base 25%
• Oxidation Reaction 25%
• Mechanistic Study 25%
• Rhodium 25%