A five-coordinate Ni(i) complex supported by 1,4,7-triisopropyl-1,4,7-triazacyclononane

Leonel Griego, Toby J. Woods, Liviu M. Mirica

Research output: Contribution to journalArticlepeer-review

Abstract

An isolated Ni(ii)-nitrosyl complex supported by the bulky tridentate 1,4,7-triisopropyl-1,4,7-triazacyclononane (iPr3TACN) ligand was obtained from the reaction of a Ni(ii) dimethyl complex with NOPF6, suggesting the in situ formation of a Ni(i) species that reacts with the resulting NO product. Use of a π-acceptor ancillary isocyanide ligand led to the isolation and characterization of an uncommon 5-coordinate Ni(i) complex supported by the iPr3TACN ligand and tert-butylisocyanide.

Original languageEnglish (US)
Pages (from-to)7360-7363
Number of pages4
JournalChemical Communications
Volume58
Issue number53
DOIs
StatePublished - Jun 14 2022

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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