A condensation of [Ru 3S 2(cymene) 3] 2+ with sulfide to give the dendridic cluster [Ru 9S 8(cymene) 6] 2+

Matthew L. Kuhlman; Thomas B. Rauchfuss

doi:10.1021/om0496941

A condensation of [Ru ₃S ₂(cymene) ₃] ²⁺ with sulfide to give the dendridic cluster [Ru ₉S ₈(cymene) ₆] ²⁺

Matthew L. Kuhlman, Thomas B. Rauchfuss

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of [(cymene) ₂Ru ₃S ₂(NCMe) ₃] ²⁺ with sulfide sources efficiently affords the cluster of clusters [(cymene) ₆Ru ₉S ₈](PF ₆) ₂. The synthesis is subject to coformation of [(cymene) ₄Ru ₅S ₄](PF ₆) ₂, which arises via the reaction of [(cymene) ₂Ru ₃S ₂(NCMe) ₃](PF ₆) ₂ and [(cymene) ₆Ru ₉S ₈(PF ₆) ₂. Crystallographic analysis demonstrates that [(cymene) ₆Ru ₉S ₈](PF ₆) ₂ features three [(cymene) ₂Ru ₃S ₂] ²⁺ units linked through a pair of μ ₃-S ligands.

Original language	English (US)
Pages (from-to)	5085-5087
Number of pages	3
Journal	Organometallics
Volume	23
Issue number	21
DOIs	https://doi.org/10.1021/om0496941
State	Published - Oct 11 2004

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Online availability

10.1021/om0496941

Library availability

Discover UIUC Full Text

Cite this

@article{bed4b53311f0481e974f9833b170a9d1,

title = "A condensation of [Ru 3S 2(cymene) 3] 2+ with sulfide to give the dendridic cluster [Ru 9S 8(cymene) 6] 2+ ",

abstract = "Reaction of [(cymene) 2Ru 3S 2(NCMe) 3] 2+ with sulfide sources efficiently affords the cluster of clusters [(cymene) 6Ru 9S 8](PF 6) 2. The synthesis is subject to coformation of [(cymene) 4Ru 5S 4](PF 6) 2, which arises via the reaction of [(cymene) 2Ru 3S 2(NCMe) 3](PF 6) 2 and [(cymene) 6Ru 9S 8(PF 6) 2. Crystallographic analysis demonstrates that [(cymene) 6Ru 9S 8](PF 6) 2 features three [(cymene) 2Ru 3S 2] 2+ units linked through a pair of μ 3-S ligands.",

author = "Kuhlman, {Matthew L.} and Rauchfuss, {Thomas B.}",

year = "2004",

month = oct,

day = "11",

doi = "10.1021/om0496941",

language = "English (US)",

volume = "23",

pages = "5085--5087",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - A condensation of [Ru 3S 2(cymene) 3] 2+ with sulfide to give the dendridic cluster [Ru 9S 8(cymene) 6] 2+

AU - Kuhlman, Matthew L.

AU - Rauchfuss, Thomas B.

PY - 2004/10/11

Y1 - 2004/10/11

N2 - Reaction of [(cymene) 2Ru 3S 2(NCMe) 3] 2+ with sulfide sources efficiently affords the cluster of clusters [(cymene) 6Ru 9S 8](PF 6) 2. The synthesis is subject to coformation of [(cymene) 4Ru 5S 4](PF 6) 2, which arises via the reaction of [(cymene) 2Ru 3S 2(NCMe) 3](PF 6) 2 and [(cymene) 6Ru 9S 8(PF 6) 2. Crystallographic analysis demonstrates that [(cymene) 6Ru 9S 8](PF 6) 2 features three [(cymene) 2Ru 3S 2] 2+ units linked through a pair of μ 3-S ligands.

AB - Reaction of [(cymene) 2Ru 3S 2(NCMe) 3] 2+ with sulfide sources efficiently affords the cluster of clusters [(cymene) 6Ru 9S 8](PF 6) 2. The synthesis is subject to coformation of [(cymene) 4Ru 5S 4](PF 6) 2, which arises via the reaction of [(cymene) 2Ru 3S 2(NCMe) 3](PF 6) 2 and [(cymene) 6Ru 9S 8(PF 6) 2. Crystallographic analysis demonstrates that [(cymene) 6Ru 9S 8](PF 6) 2 features three [(cymene) 2Ru 3S 2] 2+ units linked through a pair of μ 3-S ligands.

UR - http://www.scopus.com/inward/record.url?scp=6344258882&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=6344258882&partnerID=8YFLogxK

U2 - 10.1021/om0496941

DO - 10.1021/om0496941

M3 - Article

AN - SCOPUS:6344258882

SN - 0276-7333

VL - 23

SP - 5085

EP - 5087

JO - Organometallics

JF - Organometallics

IS - 21

ER -