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  • Scott E Denmark
Article

(R)-n,n’-dimethyl-1,1’-binaphthyldiamine

Denmark, S. E. & Ryabchuk, P. G., 2019, In : Organic Syntheses. 96, p. 382-399 18 p.

Research output: Contribution to journalArticle

Open Access

A Dinuclear Mechanism Implicated in Controlled Carbene Polymerization

Zhukhovitskiy, A. V., Kobylianskii, I. J., Thomas, A. A., Evans, A. M., Delaney, C. P., Flanders, N. C., Denmark, S. E., DIchtel, W. R. & Toste, F. D., Apr 24 2019, In : Journal of the American Chemical Society. 141, 16, p. 6473-6478 6 p.

Research output: Contribution to journalArticle

Asymmetric construction of quaternary stereogenic centers via auxiliary-based SN2′ reactions: A case of 1,7-relative stereogenesis

Denmark, S. E. & Marble, L. K., Jan 1 2014, In : Heterocycles. 88, 1, p. 559-590 32 p.

Research output: Contribution to journalArticle

Asymmetric Hydrogenation of Unfunctionalized Tetrasubstituted Acyclic Olefins

Bigler, R., Mack, K. A., Shen, J., Tosatti, P., Han, C., Bachmann, S., Zhang, H., Scalone, M., Pfaltz, A., Denmark, S. E., Hildbrand, S. & Gosselin, F., Feb 10 2020, In : Angewandte Chemie - International Edition. 59, 7, p. 2844-2849 6 p.

Research output: Contribution to journalArticle

Carbanion-accelerated claisen rearrangements: Asymmetric induction with chiral phosphorus-stabilized anions

Denmark, S. E., Marlin, J. E. & Rajendra, G., Jan 4 2013, In : Journal of Organic Chemistry. 78, 1, p. 66-82 17 p.

Research output: Contribution to journalArticle

Catalytic, enantioselective, intramolecular carbosulfenylation of olefins

Denmark, S. E. & Jaunet, A., May 1 2013, In : Journal of the American Chemical Society. 135, 17, p. 6419-6422 4 p.

Research output: Contribution to journalArticle

Catalytic, enantioselective, intramolecular carbosulfenylation of olefins. preparative and stereochemical aspects

Denmark, S. E. & Jaunet, A., Jan 3 2014, In : Journal of Organic Chemistry. 79, 1, p. 140-171 32 p.

Research output: Contribution to journalArticle

Catalytic, Enantioselective, Intramolecular Sulfenoamination of Alkenes with Anilines

Denmark, S. E. & Chi, H. M., Apr 7 2017, In : Journal of Organic Chemistry. 82, 7, p. 3826-3843 18 p.

Research output: Contribution to journalArticle

Catalytic, Enantioselective, Intramolecular Sulfenofunctionalization of Alkenes with Phenols

Denmark, S. E. & Kornfilt, D. J. P., Mar 17 2017, In : Journal of Organic Chemistry. 82, 6, p. 3192-3222 31 p.

Research output: Contribution to journalArticle

Catalytic, Enantioselective Sulfenylation of Ketone-Derived Enoxysilanes

Denmark, S. E., Rossi, S., Webster, M. P. & Wang, H., Sep 5 2014, In : Journal of the American Chemical Society. 136, 37, p. 13016-13028 13 p.

Research output: Contribution to journalArticle

Catalytic, Enantioselective syn-Diamination of Alkenes

Tao, Z., Gilbert, B. B. & Denmark, S. E., Dec 4 2019, In : Journal of the American Chemical Society. 141, 48, p. 19161-19170 10 p.

Research output: Contribution to journalArticle

Catalytic, stereospecific syn-dichlorination of alkenes

Cresswell, A. J., Eey, S. T. C. & Denmark, S. E., Feb 2015, In : Nature Chemistry. 7, 2, p. 146-152 7 p.

Research output: Contribution to journalArticle

Catalytic asymmetric thiofunctionalization of unactivated alkenes

Denmark, S. E., Kornfilt, D. J. P. & Vogler, T., Oct 5 2011, In : Journal of the American Chemical Society. 133, 39, p. 15308-15311 4 p.

Research output: Contribution to journalArticle

Catalytic conjugate addition of acyl anion equivalents promoted by fluorodesilylation

Denmark, S. E. & Cullen, L. R., Jan 3 2014, In : Organic Letters. 16, 1, p. 70-73 4 p.

Research output: Contribution to journalArticle

Catalytic Nucleophilic Allylation Driven by the Water-Gas Shift Reaction

Denmark, S. E., Matesich, Z. D., Nguyen, S. T. & Milicevic Sephton, S., Jan 5 2018, In : Journal of Organic Chemistry. 83, 1, p. 23-48 26 p.

Research output: Contribution to journalArticle

Cross-coupling with organosilicon compounds

Chang, W. T. T., Smith, R. C., Regens, C. S., Bailey, A. D., Werner, N. S. & Denmark, S. E., Dec 1 2011, In : Organic Reactions. 75, 1, p. 213-745 533 p.

Research output: Contribution to journalArticle

Demystifying the asymmetry-amplifying, autocatalytic behaviour of the Soai reaction through structural, mechanistic and computational studies

Athavale, S. V., Simon, A., Houk, K. N. & Denmark, S. E., Apr 1 2020, In : Nature Chemistry. 12, 4, p. 412-423 12 p.

Research output: Contribution to journalArticle

Development of a Computer-Guided Workflow for Catalyst Optimization. Descriptor Validation, Subset Selection, and Training Set Analysis

Henle, J. J., Zahrt, A. F., Rose, B. T., Darrow, W. T., Wang, Y. & Denmark, S. E., Jul 1 2020, In : Journal of the American Chemical Society. 142, 26, p. 11578-11592 15 p.

Research output: Contribution to journalArticle

Development of a Phase-Transfer-Catalyzed, [2,3]-Wittig Rearrangement

Denmark, S. E. & Cullen, L. R., Oct 2 2015, In : Journal of Organic Chemistry. 80, 23, p. 11818-11848 31 p.

Research output: Contribution to journalArticle

Development of chiral bis-hydrazone ligands for the enantioselective cross-coupling reactions of aryldimethylsilanolates

Denmark, S. E., Chang, W. T. T., Houk, K. N. & Liu, P., Jan 1 2015, In : Journal of Organic Chemistry. 80, 1, p. 313-366 54 p.

Research output: Contribution to journalArticle

Dynamically Chiral Helical Polymers: A New Frontier in Asymmetric Catalysis?

Denmark, S. E., Jul 24 2019, In : ACS Central Science. 5, 7, p. 1117-1119 3 p.

Research output: Contribution to journalArticle

Open Access

Effects of charge separation, effective concentration, and aggregate formation on the phase transfer catalyzed alkylation of phenol

Denmark, S. E., Weintraub, R. C. & Gould, N. D., Aug 15 2012, In : Journal of the American Chemical Society. 134, 32, p. 13415-13429 15 p.

Research output: Contribution to journalArticle

Elucidating the Role of the Boronic Esters in the Suzuki-Miyaura Reaction: Structural, Kinetic, and Computational Investigations

Thomas, A. A., Zahrt, A. F., Delaney, C. P. & Denmark, S. E., Mar 28 2018, In : Journal of the American Chemical Society. 140, 12, p. 4401-4416 16 p.

Research output: Contribution to journalArticle

Enantio- and Diastereoselective, Lewis Base Catalyzed, Cascade Sulfenoacetalization of Alkenyl Aldehydes

Matviitsuk, A. & Denmark, S. E., Jan 1 2019, In : Angewandte Chemie - International Edition. 58, 36, p. 12486-12490 5 p.

Research output: Contribution to journalArticle

Enantioselective, lewis base-catalyzed, intermolecular sulfenoamination of alkenes

Roth, A. & Denmark, S. E., Sep 4 2019, In : Journal of the American Chemical Society. 141, 35, p. 13767-13771 5 p.

Research output: Contribution to journalArticle

Enantioselective, Lewis Base-Catalyzed Carbosulfenylation of Alkenylboronates by 1,2-Boronate Migration

Tao, Z., Robb, K. A., Panger, J. L. & Denmark, S. E., Nov 21 2018, In : Journal of the American Chemical Society. 140, 46, p. 15621-15625 5 p.

Research output: Contribution to journalArticle

Enantioselective, Lewis Base-Catalyzed Sulfenocyclization of Polyenes

Tao, Z., Robb, K. A., Zhao, K. & Denmark, S. E., Mar 14 2018, In : Journal of the American Chemical Society. 140, 10, p. 3569-3573 5 p.

Research output: Contribution to journalArticle

Enantioselective bromocycloetherification by Lewis base/chiral Brønsted acid cooperative catalysis

Denmark, S. E. & Burk, M. T., Jan 6 2012, In : Organic Letters. 14, 1, p. 256-259 4 p.

Research output: Contribution to journalArticle

Enantioselective construction of quaternary stereogenic carbon atoms by the lewis base catalyzed additions of silyl ketene imines to aldehydes

Denmark, S. E., Wilson, T. W. & Burk, M. T., Jul 21 2014, In : Chemistry - A European Journal. 20, 30, p. 9268-9279 12 p.

Research output: Contribution to journalArticle

Enantioselective Synthesis of γ-Lactams by Lewis Base Catalyzed Sulfenoamidation of Alkenes

Panger, J. L. & Denmark, S. E., Apr 3 2020, In : Organic Letters. 22, 7, p. 2501-2505 5 p.

Research output: Contribution to journalArticle

Evaluating continuous chirality measure as a 3D descriptor in chemoinformatics applied to asymmetric catalysis

Zahrt, A. F. & Denmark, S. E., Mar 29 2019, In : Tetrahedron. 75, 13, p. 1841-1851 11 p.

Research output: Contribution to journalArticle

ExCage

Dale, E. J., Vermeulen, N. A., Thomas, A. A., Barnes, J. C., Juríček, M., Blackburn, A. K., Strutt, N. L., Sarjeant, A. A., Stern, C. L., Denmark, S. E. & Stoddart, J. F., Jul 30 2014, In : Journal of the American Chemical Society. 136, 30, p. 10669-10682 14 p.

Research output: Contribution to journalArticle

Investigating the Enantiodetermining Step of a Chiral Lewis Base Catalyzed Bromocycloetherification of Privileged Alkenes

Böse, D. & Denmark, S. E., Mar 1 2018, In : Synlett. 29, 4, p. 433-439 7 p., st-2017-b0700-c.

Research output: Contribution to journalArticle

Iron-catalyzed cross-coupling of unactivated secondary alkyl thio ethers and sulfones with aryl grignard reagents

Denmark, S. E. & Cresswell, A. J., Dec 20 2013, In : Journal of Organic Chemistry. 78, 24, p. 12593-12628 36 p.

Research output: Contribution to journalArticle

Katalytische enantioselektive Sulfenofunktionalisierung von Alkenen: Entwicklung und aktuelle Fortschritte

Matviitsuk, A., Panger, J. L. & Denmark, S. E., 2020, (Accepted/In press) In : Angewandte Chemie.

Research output: Contribution to journalArticle

Lewis base activation of Lewis acids: Group 13. in situ generation and reaction of borenium ions

Denmark, S. E. & Ueki, Y., Nov 25 2013, In : Organometallics. 32, 22, p. 6631-6634 4 p.

Research output: Contribution to journalArticle

Lewis base catalyzed, enantioselective, intramolecular sulfenoamination of olefins

Denmark, S. E. & Chi, H. M., Jun 25 2014, In : Journal of the American Chemical Society. 136, 25, p. 8915-8918 4 p.

Research output: Contribution to journalArticle

Lewis base catalyzed enantioselective additions of an N-silyl vinylketene imine

Denmark, S. E. & Wilson, T. W., Mar 26 2012, In : Angewandte Chemie - International Edition. 51, 13, p. 3236-3239 4 p.

Research output: Contribution to journalArticle

Mechanistic, crystallographic, and computational studies on the catalytic, enantioselective sulfenofunctionalization of alkenes

Denmark, S. E., Hartmann, E., Kornfilt, D. J. P. & Wang, H., Dec 2014, In : Nature Chemistry. 6, 12, p. 1056-1064 9 p.

Research output: Contribution to journalArticle

Mechanistic significance of the Si-O-Pd bond in the palladium-catalyzed cross-coupling reactions of alkenylsilanolates

Tymonko, S. A., Smith, R. C., Ambrosi, A. & Denmark, S. E., May 20 2015, In : Journal of the American Chemical Society. 137, 19, p. 6192-6199 8 p.

Research output: Contribution to journalArticle

Open Access

Mechanistic significance of the Si-O-Pd bond in the palladium-catalyzed cross-coupling reactions of arylsilanolates

Tymonko, S. A., Smith, R. C., Ambrosi, A., Ober, M. H., Wang, H. & Denmark, S. E., May 20 2015, In : Journal of the American Chemical Society. 137, 19, p. 6200-6218 19 p.

Research output: Contribution to journalArticle

Open Access

On the stereochemical course of the addition of allylsilanes to aldehydes

Denmark, S. E., Weber, E. J., Almstead, N. G. & Wolf, L. M., Sep 16 2012, In : Tetrahedron. 68, 37, p. 7701-7718 18 p.

Research output: Contribution to journalArticle

Organic Synthesis: Wherefrom and Whither? (Some Very Personal Reflections)

Denmark, S. E., Feb 2018, In : Israel Journal of Chemistry. 58, 1, p. 61-72 12 p.

Research output: Contribution to journalArticle