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2019

Prediction of higher-selectivity catalysts by computer-driven workflow and machine learning

Zahrt, A. F., Henle, J. J., Rose, B. T., Wang, Y., Darrow, W. T. & Denmark, S. E., Jan 18 2019, In : Science. 363, 6424, eaau5631.

Research output: Contribution to journalArticle

Workflow
Empiricism
Sulfhydryl Compounds
Machine Learning
Support Vector Machine
2012

Organic reactions. Volume 78

Denmark, S. E., 2012, Hoboken, N, J: Wiley.

Research output: Book/ReportBook

Organic reactions. Volume 77

Denmark, S. E., 2012, Hoboken, N, J: Wiley-Blackwell.

Research output: Book/ReportBook

2010

Preface to special issue of heterocycles honoring the 85th birthday of prof. Dr. Albert eschenmoser

Denmark, S. E. & Sorensen, E. J., Dec 1 2010, In : Heterocycles. 82, 1, p. 5-10 6 p.

Research output: Contribution to journalReview article

2011
cross coupling
Bromides
adducts
bromides
Salts
2014

Catalytic, Enantioselective Sulfenylation of Ketone-Derived Enoxysilanes

Denmark, S. E., Rossi, S., Webster, M. P. & Wang, H., Sep 5 2014, In : Journal of the American Chemical Society. 136, 37, p. 13016-13028 13 p.

Research output: Contribution to journalArticle

Lewis Bases
Enantioselectivity
ketone
Ketones
ether

Tandem [4+2]/[3+2] Cycloadditions

Baiazitov, R. Y. & Denmark, S. E., Feb 10 2014, Methods and Applications of Cycloaddition Reactions in Organic Syntheses. Wiley Blackwell, Vol. 9781118299883. p. 471-550 80 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Cycloaddition
Biological Products
Molecules
2010

Lewis base catalysis of bromo- and iodolactonization, and cycloetherification

Denmark, S. E. & Burk, M. T., Nov 30 2010, In : Proceedings of the National Academy of Sciences of the United States of America. 107, 48, p. 20655-20660 6 p.

Research output: Contribution to journalArticle

Lewis Bases
Cyclization
Catalysis
Ions
2011

Catalytic asymmetric thiofunctionalization of unactivated alkenes

Denmark, S. E., Kornfilt, D. J. P. & Vogler, T., Oct 5 2011, In : Journal of the American Chemical Society. 133, 39, p. 15308-15311 4 p.

Research output: Contribution to journalArticle

Styrenes
Furans
Nucleophiles
alkene
Alkenes

Cross-coupling with organosilicon compounds

Chang, W. T. T., Smith, R. C., Regens, C. S., Bailey, A. D., Werner, N. S. & Denmark, S. E., Dec 1 2011, In : Organic Reactions. 75, 1, p. 213-745 533 p.

Research output: Contribution to journalArticle

cross coupling
2015

Reinvestigation of a Catalytic, Enantioselective Alkene Dibromination and Chlorohydroxylation

Denmark, S. E. & Carson, N., Nov 13 2015, In : Organic Letters. 17, 23, p. 5728-5731 4 p.

Research output: Contribution to journalArticle

Enantioselectivity
Alkenes
Nuclear magnetic resonance spectroscopy
alkenes
High Pressure Liquid Chromatography
2016

Harnessing the Power of the Water-Gas Shift Reaction for Organic Synthesis

Ambrosi, A. & Denmark, S. E., Jan 1 2016, In : Angewandte Chemie - International Edition. 55, 40, p. 12164-12189 26 p.

Research output: Contribution to journalReview article

Water gas shift
Carbon Monoxide
Ammonia
Catalysis
Hydrogenation
2014

Preface to volume 83

Denmark, S. E., 2014, In : Organic Reactions. 83, 1, p. Vii-Viii

Research output: Contribution to journalEditorial

2016

Preface to volume 91

Denmark, S. E., Jan 1 2016, In : Organic Reactions. 91, 1, p. vii-viii

Research output: Contribution to journalEditorial

2017

Synthesis of 2-Alkenyl-Tethered Anilines

Denmark, S. E. & Chi, H. M., Jul 3 2017, In : Synthesis (Germany). 49, 13, p. 2873-2888 16 p.

Research output: Contribution to journalArticle

Aniline Compounds
Aniline
Styrenes
Lewis Acids
Palladium
2010

Sequential processes in palladium-catalyzed silicon-based cross-coupling

Denmark, S. E. & Liu, J. H. C., Dec 1 2010, In : Israel Journal of Chemistry. 50, 5-6, p. 577-587 11 p.

Research output: Contribution to journalReview article

Palladium
Silicon
Substrates
Biological Products
Toxicity
2018

Preface to volume 95

Denmark, S. E., Jan 1 2018, In : Organic Reactions. 95, p. vii-ix

Research output: Contribution to journalEditorial

2019

Preface to volume 98

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 98, p. vii-x

Research output: Contribution to journalEditorial

2018

Preface to volume 96

Denmark, S. E., Jan 1 2018, In : Organic Reactions. 96, p. vii-ix

Research output: Contribution to journalEditorial

2019

Enantioselective, lewis base-catalyzed, intermolecular sulfenoamination of alkenes

Roth, A. & Denmark, S. E., Sep 4 2019, In : Journal of the American Chemical Society. 141, 35, p. 13767-13771 5 p.

Research output: Contribution to journalArticle

Lewis Bases
alkene
Alkenes
Sulfur
Olefins
2017

Preface to volume 94

Denmark, S. E., Jan 1 2017, In : Organic Reactions. 94, p. vii-viii

Research output: Contribution to journalEditorial

2019

Preparation of a diisopropylselenophosphoramide catalyst and its use in enantioselective sulfenoetherification

Denmark, S. E., Ryabchuk, P., Chi, H. M. & Matviitsuk, A., Jan 1 2019, In : Organic Syntheses. 96, p. 400-417 18 p.

Research output: Contribution to journalArticle

Open Access
2013

Lewis base activation of Lewis acids: Group 13. in situ generation and reaction of borenium ions

Denmark, S. E. & Ueki, Y., Nov 25 2013, In : Organometallics. 32, 22, p. 6631-6634 4 p.

Research output: Contribution to journalArticle

Lewis Bases
Lewis Acids
Lewis base
Chemical activation
activation
2016

Lewis Base-Catalyzed, Lewis Acid-Mediated Reactions (n → σ*)

Rossi, S. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1039-1076 38 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Lewis Acids
Silicon
Phosphoramides
Methyl Ethers
2019

Preface to volume 99

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 99, p. vii-ix

Research output: Contribution to journalEditorial

2014
Lewis Bases
Chirality
Catalysis
Catalysts
Kinetics
2016

Bifunctional Lewis Base Catalysis With Dual Activation of X3Si Nu and C=O(n → σ*)

Fu, J., Fujimori, S. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 1. p. 281-338 58 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Catalysis
Chemical activation
Phosphoramides
Catalysts

Lewis Base Catalysis in Organic Synthesis

Vedejs, E. & Denmark, S. E., Aug 17 2016, Wiley-VCH Verlag. 1400 p.

Research output: Book/ReportBook

Lewis Bases
Catalysis
Electrons
2014

Catalytic conjugate addition of acyl anion equivalents promoted by fluorodesilylation

Denmark, S. E. & Cullen, L. R., Jan 3 2014, In : Organic Letters. 16, 1, p. 70-73 4 p.

Research output: Contribution to journalArticle

Anions
anions
Ketones
reaction time
ketones
2016

Reactions of epoxides (n → σ*)

Wilson, T. W. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1113-1151 39 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Epoxy Compounds
Lewis Acids
Lewis Bases
Chemical activation
Reaction kinetics
2011

Stereocontrolled total syntheses of isodomoic acids G and H via a unified strategy

Denmark, S. E., Liu, J. H. C. & Muhuhi, J. M., Jan 7 2011, In : Journal of Organic Chemistry. 76, 1, p. 201-215 15 p.

Research output: Contribution to journalArticle

Iodides
Silicon
Rhodium
Cyclization
Molecules
2014

Enantioselective construction of quaternary stereogenic carbon atoms by the lewis base catalyzed additions of silyl ketene imines to aldehydes

Denmark, S. E., Wilson, T. W. & Burk, M. T., Jul 21 2014, In : Chemistry - A European Journal. 20, 30, p. 9268-9279 12 p.

Research output: Contribution to journalArticle

Lewis Bases
Imines
Aldehydes
Carbon
Enantioselectivity
2019

Enantio- and Diastereoselective, Lewis Base Catalyzed, Cascade Sulfenoacetalization of Alkenyl Aldehydes

Matviitsuk, A. & Denmark, S. E., Jan 1 2019, In : Angewandte Chemie - International Edition. 58, 36, p. 12486-12490 5 p.

Research output: Contribution to journalArticle

Bearings (structural)
Lewis Bases
Acetals
Aldehydes
Ions
2012

Lewis base catalyzed enantioselective additions of an N-silyl vinylketene imine

Denmark, S. E. & Wilson, T. W., Mar 26 2012, In : Angewandte Chemie - International Edition. 51, 13, p. 3236-3239 4 p.

Research output: Contribution to journalArticle

Lewis Bases
Stereoselectivity
Nitriles
Nucleophiles
Imines
2014

Preface to volume 84

Denmark, S. E., Jan 1 2014, In : Organic Reactions. 84, 1, p. vii-viii

Research output: Contribution to journalEditorial

2019

A Dinuclear Mechanism Implicated in Controlled Carbene Polymerization

Zhukhovitskiy, A. V., Kobylianskii, I. J., Thomas, A. A., Evans, A. M., Delaney, C. P., Flanders, N. C., Denmark, S. E., DIchtel, W. R. & Toste, F. D., Apr 24 2019, In : Journal of the American Chemical Society. 141, 16, p. 6473-6478 6 p.

Research output: Contribution to journalArticle

polymerization
Polymerization
Living polymerization
Polyolefins
Dimers
2014

ExCage

Dale, E. J., Vermeulen, N. A., Thomas, A. A., Barnes, J. C., Juríček, M., Blackburn, A. K., Strutt, N. L., Sarjeant, A. A., Stern, C. L., Denmark, S. E. & Stoddart, J. F., Jul 30 2014, In : Journal of the American Chemical Society. 136, 30, p. 10669-10682 14 p.

Research output: Contribution to journalArticle

Polycyclic Aromatic Hydrocarbons
Polycyclic aromatic hydrocarbons
PAH
Pyrene
Complexation
2019

Preface for volume 100

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 100, p. xxi-xxvii

Research output: Contribution to journalEditorial

2015

Preface to volume 88

Denmark, S. E., Jan 1 2015, In : Organic Reactions. 88, 1, p. vii-viii

Research output: Contribution to journalEditorial

Mechanistic significance of the Si-O-Pd bond in the palladium-catalyzed cross-coupling reactions of arylsilanolates

Tymonko, S. A., Smith, R. C., Ambrosi, A., Ober, M. H., Wang, H. & Denmark, S. E., May 20 2015, In : Journal of the American Chemical Society. 137, 19, p. 6200-6218 19 p.

Research output: Contribution to journalArticle

Open Access
Cross Reactions
palladium
Palladium
phosphine
Hot Temperature
2012

Organic reactions. Volume 76

Denmark, S. E., 2012, Hoboken, N, J: Wiley.

Research output: Book/ReportBook

2014
Allylation
Water gas shift
Aldehydes
Acetates
Carbon
2010
Fluorobenzenes
Cross Reactions
palladium
Palladium
Catalysis
Lewis Bases
Imines
Ketones
Aldehydes
Carbon
Syringes
Cross Reactions
iodide
Iodides
Fluorides
2017
Lewis Bases
Lewis base
Enantioselectivity
Alkenes
alkenes

Room Temperature, Reductive Alkylation of Activated Methylene Compounds: Carbon-Carbon Bond Formation Driven by the Rhodium-Catalyzed Water-Gas Shift Reaction

Denmark, S. E., Ibrahim, M. Y. S. & Ambrosi, A., Jan 6 2017, In : ACS Catalysis. 7, 1, p. 613-630 18 p.

Research output: Contribution to journalArticle

Rhodium
Water gas shift
Alkylation
Carbon
Alkylating Agents
2015

Preface to volume 87

Denmark, S. E., Jan 1 2015, In : Organic Reactions. 87, 1, p. vii-ix

Research output: Contribution to journalEditorial

Catalytic, stereospecific syn-dichlorination of alkenes

Cresswell, A. J., Eey, S. T. C. & Denmark, S. E., Feb 2015, In : Nature Chemistry. 7, 2, p. 146-152 7 p.

Research output: Contribution to journalArticle

Alkenes
Olefins
Chlorides
Organic Chemicals
Bromine