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  • Scott E Denmark
2011

Development and mechanistic investigation of the palladium-catalyzed α-arylation of aldehydes and N-arylation of ammonia

Vo, G. D., White, M. C., Hartwig, J. F., Denmark, S. E. & Girolami, G. S., 2011, Urbana, Il: University of Illinois.

Research output: Book/Report/Conference proceedingBook

2012

Organic reactions. Volume 77

Denmark, S. E., 2012, Hoboken, N, J: Wiley-Blackwell.

Research output: Book/Report/Conference proceedingBook

2017

Preface to volume 92

Denmark, S. E., Jan 1 2017, In : Organic Reactions. 92, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 94

Denmark, S. E., Jan 1 2017, In : Organic Reactions. 94, p. vii-viii

Research output: Contribution to journalEditorial

2016

Preface to volume 90

Denmark, S. E., Jan 1 2016, In : Organic Reactions. 90, 1, p. vii-viii

Research output: Contribution to journalEditorial

2014

Preface to volume 84

Denmark, S. E., Jan 1 2014, In : Organic Reactions. 84, 1, p. vii-viii

Research output: Contribution to journalEditorial

2015

Preface to volume 87

Denmark, S. E., Jan 1 2015, In : Organic Reactions. 87, 1, p. vii-ix

Research output: Contribution to journalEditorial

2016

Preface to volume 89

Denmark, S. E., Jan 1 2016, In : Organic Reactions. 89, 1, p. vii-viii

Research output: Contribution to journalEditorial

Summation

Vedejs, E. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1351-1353 3 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

2019

Prediction of higher-selectivity catalysts by computer-driven workflow and machine learning

Zahrt, A. F., Henle, J. J., Rose, B. T., Wang, Y., Darrow, W. T. & Denmark, S. E., Jan 18 2019, In : Science. 363, 6424, eaau5631.

Research output: Contribution to journalArticle

2011
2013

Carbanion-accelerated claisen rearrangements: Asymmetric induction with chiral phosphorus-stabilized anions

Denmark, S. E., Marlin, J. E. & Rajendra, G., Jan 4 2013, In : Journal of Organic Chemistry. 78, 1, p. 66-82 17 p.

Research output: Contribution to journalArticle

2019

(R)-n,n’-dimethyl-1,1’-binaphthyldiamine

Denmark, S. E. & Ryabchuk, P. G., 2019, In : Organic Syntheses. 96, p. 382-399 18 p.

Research output: Contribution to journalArticle

Open Access
2011
2015

Redefining q: Quaternary ammonium cross sectional area (XSA) as a general descriptor for transport-limiting PTC rate approximations

Denmark, S. E. & Henle, J. J., Apr 1 2015, In : Chemical Science. 6, 4, p. 2211-2218 8 p.

Research output: Contribution to journalArticle

Development of chiral bis-hydrazone ligands for the enantioselective cross-coupling reactions of aryldimethylsilanolates

Denmark, S. E., Chang, W. T. T., Houk, K. N. & Liu, P., Jan 1 2015, In : Journal of Organic Chemistry. 80, 1, p. 313-366 54 p.

Research output: Contribution to journalArticle

2012

On the stereochemical course of the addition of allylsilanes to aldehydes

Denmark, S. E., Weber, E. J., Almstead, N. G. & Wolf, L. M., Sep 16 2012, In : Tetrahedron. 68, 37, p. 7701-7718 18 p.

Research output: Contribution to journalArticle

2019

Preparation of a diisopropylselenophosphoramide catalyst and its use in enantioselective sulfenoetherification

Denmark, S. E., Ryabchuk, P., Chi, H. M. & Matviitsuk, A., Jan 1 2019, In : Organic Syntheses. 96, p. 400-417 18 p.

Research output: Contribution to journalArticle

Open Access
2013

Iron-catalyzed cross-coupling of unactivated secondary alkyl thio ethers and sulfones with aryl grignard reagents

Denmark, S. E. & Cresswell, A. J., Dec 20 2013, In : Journal of Organic Chemistry. 78, 24, p. 12593-12628 36 p.

Research output: Contribution to journalArticle

2011

Catalytic asymmetric thiofunctionalization of unactivated alkenes

Denmark, S. E., Kornfilt, D. J. P. & Vogler, T., Oct 5 2011, In : Journal of the American Chemical Society. 133, 39, p. 15308-15311 4 p.

Research output: Contribution to journalArticle

2017

Catalytic, Enantioselective, Intramolecular Sulfenoamination of Alkenes with Anilines

Denmark, S. E. & Chi, H. M., Apr 7 2017, In : Journal of Organic Chemistry. 82, 7, p. 3826-3843 18 p.

Research output: Contribution to journalArticle

2016

Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link

Thomas, A. A. & Denmark, S. E., Apr 15 2016, In : Science. 352, 6283, p. 329-332 4 p.

Research output: Contribution to journalArticle

2012

Silyl ketene imines: Highly versatile nucleophiles for catalytic, asymmetric synthesis

Denmark, S. E. & Wilson, T. W., Oct 1 2012, In : Angewandte Chemie - International Edition. 51, 40, p. 9980-9992 13 p.

Research output: Contribution to journalReview article

2017

Catalytic, Enantioselective, Intramolecular Sulfenofunctionalization of Alkenes with Phenols

Denmark, S. E. & Kornfilt, D. J. P., Mar 17 2017, In : Journal of Organic Chemistry. 82, 6, p. 3192-3222 31 p.

Research output: Contribution to journalArticle

2016

Lewis Base Catalysis in Organic Synthesis

Vedejs, E. & Denmark, S. E., Aug 17 2016, Wiley-VCH Verlag. 1400 p.

Research output: Book/Report/Conference proceedingBook

2014

Catalytic, enantioselective, intramolecular carbosulfenylation of olefins. preparative and stereochemical aspects

Denmark, S. E. & Jaunet, A., Jan 3 2014, In : Journal of Organic Chemistry. 79, 1, p. 140-171 32 p.

Research output: Contribution to journalArticle

2015

Mechanistic significance of the Si-O-Pd bond in the palladium-catalyzed cross-coupling reactions of alkenylsilanolates

Tymonko, S. A., Smith, R. C., Ambrosi, A. & Denmark, S. E., May 20 2015, In : Journal of the American Chemical Society. 137, 19, p. 6192-6199 8 p.

Research output: Contribution to journalArticle

Open Access

Why You Really Should Consider Using Palladium-Catalyzed Cross-Coupling of Silanols and Silanolates

Denmark, S. E. & Ambrosi, A., Jul 30 2015, In : Organic Process Research and Development. 19, 8, p. 982-994 13 p.

Research output: Contribution to journalArticle

2016

Harnessing the Power of the Water-Gas Shift Reaction for Organic Synthesis

Ambrosi, A. & Denmark, S. E., Jan 1 2016, In : Angewandte Chemie - International Edition. 55, 40, p. 12164-12189 26 p.

Research output: Contribution to journalReview article

2012

Organic reactions. Volume 78

Denmark, S. E., 2012, Hoboken, N, J: Wiley.

Research output: Book/Report/Conference proceedingBook

2016

Bifunctional and Synergistic Catalysis: Lewis Acid Catalysis and Lewis Base-Assisted Bond Polarization (n → σ*)

Chung, W. J. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1213-1258 46 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

2013

Lewis base catalysis of the Mukaiyama directed aldol reaction: 40years of inspiration and advances

Beutner, G. L. & Denmark, S. E., Aug 26 2013, In : Angewandte Chemie - International Edition. 52, 35, p. 9086-9096 11 p.

Research output: Contribution to journalReview article

2015

Preface to volume 86

Denmark, S. E., Jan 1 2015, In : Organic Reactions. 86, 1, p. vii-viii

Research output: Contribution to journalEditorial

2017

Preface to volume 93

Denmark, S. E., Jan 1 2017, In : Organic Reactions. 93, 1, p. vii-viii

Research output: Contribution to journalEditorial

2014

Preface to volume 83

Denmark, S. E., 2014, In : Organic Reactions. 83, 1, p. Vii-Viii

Research output: Contribution to journalEditorial

2019

Preface to volume 99

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 99, p. vii-ix

Research output: Contribution to journalEditorial

Preface for volume 100

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 100, p. xxi-xxvii

Research output: Contribution to journalEditorial

2013

Preface to volume 82

Denmark, S. E., 2013, In : Organic Reactions. 82, 1, p. Vii-Viii

Research output: Contribution to journalEditorial

2019

Preface to volume 97

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 97, p. vii-ix

Research output: Contribution to journalEditorial

Preface to volume 98

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 98, p. vii-x

Research output: Contribution to journalEditorial

2014

Preface to volume 85

Denmark, S. E., Jan 1 2014, In : Organic Reactions. 85, 1, p. vii-viii

Research output: Contribution to journalEditorial

2011
2019

Dynamically Chiral Helical Polymers: A New Frontier in Asymmetric Catalysis?

Denmark, S. E., Jul 24 2019, In : ACS Central Science. 5, 7, p. 1117-1119 3 p.

Research output: Contribution to journalArticle

Open Access
2020

Asymmetric Hydrogenation of Unfunctionalized Tetrasubstituted Acyclic Olefins

Bigler, R., Mack, K. A., Shen, J., Tosatti, P., Han, C., Bachmann, S., Zhang, H., Scalone, M., Pfaltz, A., Denmark, S. E., Hildbrand, S. & Gosselin, F., Feb 10 2020, In : Angewandte Chemie - International Edition. 59, 7, p. 2844-2849 6 p.

Research output: Contribution to journalArticle

2014
2013

Organosilicon Compounds in Cross-Coupling Reactions

Denmark, S. E. & Sweis, R. F., Nov 30 2013, Metal Catalyzed Cross-Coupling Reactions and More. Wiley-VCH Verlag, Vol. 3. p. 475-532 58 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

2017

Unexpected Rearrangement of 2-Bromoaniline under Biphasic Alkylation Conditions

Barraza, S. J. & Denmark, S. E., Dec 18 2017, In : Synlett. 28, 20, p. 2891-2895 5 p.

Research output: Contribution to journalArticle

Room Temperature, Reductive Alkylation of Activated Methylene Compounds: Carbon-Carbon Bond Formation Driven by the Rhodium-Catalyzed Water-Gas Shift Reaction

Denmark, S. E., Ibrahim, M. Y. S. & Ambrosi, A., Jan 6 2017, In : ACS Catalysis. 7, 1, p. 613-630 18 p.

Research output: Contribution to journalArticle

2019

Potassium Trimethylsilanolate Enables Rapid, Homogeneous Suzuki-Miyaura Cross-Coupling of Boronic Esters

Delaney, C. P., Kassel, V. M. & Denmark, S. E., Jan 1 2019, (Accepted/In press) In : ACS Catalysis. p. 73-80 8 p.

Research output: Contribution to journalArticle