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  • Scott E Denmark
2020

Asymmetric Hydrogenation of Unfunctionalized Tetrasubstituted Acyclic Olefins

Bigler, R., Mack, K. A., Shen, J., Tosatti, P., Han, C., Bachmann, S., Zhang, H., Scalone, M., Pfaltz, A., Denmark, S. E., Hildbrand, S. & Gosselin, F., Feb 10 2020, In : Angewandte Chemie - International Edition. 59, 7, p. 2844-2849 6 p.

Research output: Contribution to journalArticle

2014
2013

Organosilicon Compounds in Cross-Coupling Reactions

Denmark, S. E. & Sweis, R. F., Nov 30 2013, Metal Catalyzed Cross-Coupling Reactions and More. Wiley-VCH Verlag, Vol. 3. p. 475-532 58 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

2017

Unexpected Rearrangement of 2-Bromoaniline under Biphasic Alkylation Conditions

Barraza, S. J. & Denmark, S. E., Dec 18 2017, In : Synlett. 28, 20, p. 2891-2895 5 p.

Research output: Contribution to journalArticle

Room Temperature, Reductive Alkylation of Activated Methylene Compounds: Carbon-Carbon Bond Formation Driven by the Rhodium-Catalyzed Water-Gas Shift Reaction

Denmark, S. E., Ibrahim, M. Y. S. & Ambrosi, A., Jan 6 2017, In : ACS Catalysis. 7, 1, p. 613-630 18 p.

Research output: Contribution to journalArticle

2019

Potassium Trimethylsilanolate Enables Rapid, Homogeneous Suzuki-Miyaura Cross-Coupling of Boronic Esters

Delaney, C. P., Kassel, V. M. & Denmark, S. E., Jan 1 2019, (Accepted/In press) In : ACS Catalysis. p. 73-80 8 p.

Research output: Contribution to journalArticle

2011
2012

Lewis base catalyzed enantioselective additions of an N-silyl vinylketene imine

Denmark, S. E. & Wilson, T. W., Mar 26 2012, In : Angewandte Chemie - International Edition. 51, 13, p. 3236-3239 4 p.

Research output: Contribution to journalArticle

2016

Toward Catalytic, Enantioselective Chlorolactonization of 1,2-Disubstituted Styrenyl Carboxylic Acids

Denmark, S. E., Ryabchuk, P., Burk, M. T. & Gilbert, B. B., Nov 4 2016, In : Journal of Organic Chemistry. 81, 21, p. 10411-10423 13 p.

Research output: Contribution to journalArticle

2020

Development of a Computer-Guided Workflow for Catalyst Optimization. Descriptor Validation, Subset Selection, and Training Set Analysis

Henle, J. J., Zahrt, A. F., Rose, B. T., Darrow, W. T., Wang, Y. & Denmark, S. E., Jul 1 2020, In : Journal of the American Chemical Society. 142, 26, p. 11578-11592 15 p.

Research output: Contribution to journalArticle

2012

Total synthesis of papulacandin D

Kobayashi, T., Regens, C. S. & Denmark, S. E., 2012, Strategies and Tactics in Organic Synthesis. Academic Press Inc., p. 79-126 48 p. (Strategies and Tactics in Organic Synthesis; vol. 8).

Research output: Chapter in Book/Report/Conference proceedingChapter

2015

Catalytic, Stereoselective Dihalogenation of Alkenes: Challenges and Opportunities

Cresswell, A. J., Eey, S. T. C. & Denmark, S. E., Dec 21 2015, In : Angewandte Chemie - International Edition. 54, 52, p. 15642-15682 41 p.

Research output: Contribution to journalReview article

2014

Tandem [4+2]/[3+2] Cycloadditions

Baiazitov, R. Y. & Denmark, S. E., Feb 10 2014, Methods and Applications of Cycloaddition Reactions in Organic Syntheses. Wiley-Blackwell, Vol. 9781118299883. p. 471-550 80 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

2019

Evaluating continuous chirality measure as a 3D descriptor in chemoinformatics applied to asymmetric catalysis

Zahrt, A. F. & Denmark, S. E., Mar 29 2019, In : Tetrahedron. 75, 13, p. 1841-1851 11 p.

Research output: Contribution to journalArticle

2017
2011

Stereocontrolled total syntheses of isodomoic acids G and H via a unified strategy

Denmark, S. E., Liu, J. H. C. & Muhuhi, J. M., Jan 7 2011, In : Journal of Organic Chemistry. 76, 1, p. 201-215 15 p.

Research output: Contribution to journalArticle

2015

Development of a Phase-Transfer-Catalyzed, [2,3]-Wittig Rearrangement

Denmark, S. E. & Cullen, L. R., Oct 2 2015, In : Journal of Organic Chemistry. 80, 23, p. 11818-11848 31 p.

Research output: Contribution to journalArticle

2017

Synthesis of 2-Alkenyl-Tethered Anilines

Denmark, S. E. & Chi, H. M., Jul 3 2017, In : Synthesis (Germany). 49, 13, p. 2873-2888 16 p.

Research output: Contribution to journalArticle

2015

Reinvestigation of a Catalytic, Enantioselective Alkene Dibromination and Chlorohydroxylation

Denmark, S. E. & Carson, N., Nov 13 2015, In : Organic Letters. 17, 23, p. 5728-5731 4 p.

Research output: Contribution to journalArticle

2018

Investigating the Enantiodetermining Step of a Chiral Lewis Base Catalyzed Bromocycloetherification of Privileged Alkenes

Böse, D. & Denmark, S. E., Mar 1 2018, In : Synlett. 29, 4, p. 433-439 7 p., st-2017-b0700-c.

Research output: Contribution to journalArticle

2013
2011

Probing the electronic demands of transmetalation in the palladium-catalyzed cross-coupling of arylsilanolates

Denmark, S. E., Smith, R. C. & Chang, W. T. T., Jun 17 2011, In : Tetrahedron. 67, 24, p. 4391-4396 6 p.

Research output: Contribution to journalArticle

2019

Enantioselective, lewis base-catalyzed, intermolecular sulfenoamination of alkenes

Roth, A. & Denmark, S. E., Sep 4 2019, In : Journal of the American Chemical Society. 141, 35, p. 13767-13771 5 p.

Research output: Contribution to journalArticle

2011

Cross-coupling with organosilicon compounds

Chang, W. T. T., Smith, R. C., Regens, C. S., Bailey, A. D., Werner, N. S. & Denmark, S. E., Dec 1 2011, In : Organic Reactions. 75, 1, p. 213-745 533 p.

Research output: Contribution to journalArticle

2013

Catalytic, enantioselective, intramolecular carbosulfenylation of olefins

Denmark, S. E. & Jaunet, A., May 1 2013, In : Journal of the American Chemical Society. 135, 17, p. 6419-6422 4 p.

Research output: Contribution to journalArticle

2014

ExCage

Dale, E. J., Vermeulen, N. A., Thomas, A. A., Barnes, J. C., Juríček, M., Blackburn, A. K., Strutt, N. L., Sarjeant, A. A., Stern, C. L., Denmark, S. E. & Stoddart, J. F., Jul 30 2014, In : Journal of the American Chemical Society. 136, 30, p. 10669-10682 14 p.

Research output: Contribution to journalArticle

Catalytic, Enantioselective Sulfenylation of Ketone-Derived Enoxysilanes

Denmark, S. E., Rossi, S., Webster, M. P. & Wang, H., Sep 5 2014, In : Journal of the American Chemical Society. 136, 37, p. 13016-13028 13 p.

Research output: Contribution to journalArticle

2020

Katalytische enantioselektive Sulfenofunktionalisierung von Alkenen: Entwicklung und aktuelle Fortschritte

Matviitsuk, A., Panger, J. L. & Denmark, S. E., 2020, (Accepted/In press) In : Angewandte Chemie.

Research output: Contribution to journalArticle

2012

Enantioselective bromocycloetherification by Lewis base/chiral Brønsted acid cooperative catalysis

Denmark, S. E. & Burk, M. T., Jan 6 2012, In : Organic Letters. 14, 1, p. 256-259 4 p.

Research output: Contribution to journalArticle

2013

The interplay of invention, observation, and discovery in the development of lewis base activation of lewis acids for catalytic enantioselective synthesis

Beutner, G. L. & Denmark, S. E., Jan 1 2013, Inventing Reactions. Goossen, L. (ed.). p. 55-89 35 p. (Topics in Organometallic Chemistry; vol. 44).

Research output: Chapter in Book/Report/Conference proceedingChapter

2016

Bifunctional Lewis Base Catalysis With Dual Activation of X3Si Nu and C=O(n → σ*)

Fu, J., Fujimori, S. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 1. p. 281-338 58 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

2012

Organic reactions. Volume 76

Denmark, S. E., 2012, Hoboken, N, J: Wiley.

Research output: Book/Report/Conference proceedingBook

2016

Lewis Base-Catalyzed, Lewis Acid-Mediated Reactions (n → σ*)

Rossi, S. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1039-1076 38 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Reactions of epoxides (n → σ*)

Wilson, T. W. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1113-1151 39 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Preface to volume 91

Denmark, S. E., Jan 1 2016, In : Organic Reactions. 91, 1, p. vii-viii

Research output: Contribution to journalEditorial

2015

Preface to volume 88

Denmark, S. E., Jan 1 2015, In : Organic Reactions. 88, 1, p. vii-viii

Research output: Contribution to journalEditorial

2016

Principles, Definitions, Terminology, and Orbital Analysis of Lewis Base-Lewis Acid Interactions Leading to Catalysis

Denmark, S. E. & Beutner, G. L., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 1. p. 33-54 22 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

2014
2016

Preface

Vedejs, E. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 1-3. p. xxvii-xxxii

Research output: Chapter in Book/Report/Conference proceedingForeword/postscript

2015

Catalytic, stereospecific syn-dichlorination of alkenes

Cresswell, A. J., Eey, S. T. C. & Denmark, S. E., Feb 2015, In : Nature Chemistry. 7, 2, p. 146-152 7 p.

Research output: Contribution to journalArticle

2016

Lewis Base Catalysis: A Platform for Enantioselective Addition to Alkenes Using Group 16 and 17 Lewis Acids (n → σ*)

Kalyani, D., Kornfilt, D. J. P., Burk, M. T. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1153-1211 59 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

2012

Effects of charge separation, effective concentration, and aggregate formation on the phase transfer catalyzed alkylation of phenol

Denmark, S. E., Weintraub, R. C. & Gould, N. D., Aug 15 2012, In : Journal of the American Chemical Society. 134, 32, p. 13415-13429 15 p.

Research output: Contribution to journalArticle

2020

Quantitative Structure-Selectivity Relationships in Enantioselective Catalysis: Past, Present, and Future

Zahrt, A. F., Athavale, S. V. & Denmark, S. E., Feb 12 2020, In : Chemical reviews. 120, 3, p. 1620-1689 70 p.

Research output: Contribution to journalReview article

2017

Understanding Site Selectivity in the Palladium-Catalyzed Cross-Coupling of Allenylsilanolates

Denmark, S. E. & Ambrosi, A., Nov 13 2017, In : Synlett. 28, 18, p. 2415-2420 6 p.

Research output: Contribution to journalArticle

2013

Lewis base activation of Lewis acids: Group 13. in situ generation and reaction of borenium ions

Denmark, S. E. & Ueki, Y., Nov 25 2013, In : Organometallics. 32, 22, p. 6631-6634 4 p.

Research output: Contribution to journalArticle

2014

Enantioselective construction of quaternary stereogenic carbon atoms by the lewis base catalyzed additions of silyl ketene imines to aldehydes

Denmark, S. E., Wilson, T. W. & Burk, M. T., Jul 21 2014, In : Chemistry - A European Journal. 20, 30, p. 9268-9279 12 p.

Research output: Contribution to journalArticle

2019

Enantio- and Diastereoselective, Lewis Base Catalyzed, Cascade Sulfenoacetalization of Alkenyl Aldehydes

Matviitsuk, A. & Denmark, S. E., Jan 1 2019, In : Angewandte Chemie - International Edition. 58, 36, p. 12486-12490 5 p.

Research output: Contribution to journalArticle

2018

Enantioselective, Lewis Base-Catalyzed Sulfenocyclization of Polyenes

Tao, Z., Robb, K. A., Zhao, K. & Denmark, S. E., Mar 14 2018, In : Journal of the American Chemical Society. 140, 10, p. 3569-3573 5 p.

Research output: Contribution to journalArticle

Catalytic Nucleophilic Allylation Driven by the Water-Gas Shift Reaction

Denmark, S. E., Matesich, Z. D., Nguyen, S. T. & Milicevic Sephton, S., Jan 5 2018, In : Journal of Organic Chemistry. 83, 1, p. 23-48 26 p.

Research output: Contribution to journalArticle