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  • Scott E Denmark
2016

Lewis Base Catalysis: A Platform for Enantioselective Addition to Alkenes Using Group 16 and 17 Lewis Acids (n → σ*)

Kalyani, D., Kornfilt, D. J. P., Burk, M. T. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1153-1211 59 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

2011

Development and mechanistic investigation of the palladium-catalyzed α-arylation of aldehydes and N-arylation of ammonia

Vo, G. D., White, M. C., Hartwig, J. F., Denmark, S. E. & Girolami, G. S., 2011, Urbana, Il: University of Illinois.

Research output: Book/Report/Conference proceedingBook

2015

Redefining q: Quaternary ammonium cross sectional area (XSA) as a general descriptor for transport-limiting PTC rate approximations

Denmark, S. E. & Henle, J. J., Apr 1 2015, In : Chemical Science. 6, 4, p. 2211-2218 8 p.

Research output: Contribution to journalArticle

2019

Evaluating continuous chirality measure as a 3D descriptor in chemoinformatics applied to asymmetric catalysis

Zahrt, A. F. & Denmark, S. E., Mar 29 2019, In : Tetrahedron. 75, 13, p. 1841-1851 11 p.

Research output: Contribution to journalArticle

2012

Organic reactions. Volume 77

Denmark, S. E., 2012, Hoboken, N, J: Wiley-Blackwell.

Research output: Book/Report/Conference proceedingBook

2016

Summation

Vedejs, E. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1351-1353 3 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

2012

On the stereochemical course of the addition of allylsilanes to aldehydes

Denmark, S. E., Weber, E. J., Almstead, N. G. & Wolf, L. M., Sep 16 2012, In : Tetrahedron. 68, 37, p. 7701-7718 18 p.

Research output: Contribution to journalArticle

2014

Asymmetric construction of quaternary stereogenic centers via auxiliary-based SN2′ reactions: A case of 1,7-relative stereogenesis

Denmark, S. E. & Marble, L. K., Jan 1 2014, In : Heterocycles. 88, 1, p. 559-590 32 p.

Research output: Contribution to journalArticle

2019

Dynamically Chiral Helical Polymers: A New Frontier in Asymmetric Catalysis?

Denmark, S. E., Jul 24 2019, In : ACS Central Science. 5, 7, p. 1117-1119 3 p.

Research output: Contribution to journalArticle

Open Access

Preparation of a diisopropylselenophosphoramide catalyst and its use in enantioselective sulfenoetherification

Denmark, S. E., Ryabchuk, P., Chi, H. M. & Matviitsuk, A., Jan 1 2019, In : Organic Syntheses. 96, p. 400-417 18 p.

Research output: Contribution to journalArticle

Open Access
2018

Preface to volume 95

Denmark, S. E., Jan 1 2018, In : Organic Reactions. 95, p. vii-ix

Research output: Contribution to journalEditorial

2017

Preface to volume 92

Denmark, S. E., Jan 1 2017, In : Organic Reactions. 92, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 94

Denmark, S. E., Jan 1 2017, In : Organic Reactions. 94, p. vii-viii

Research output: Contribution to journalEditorial

2016

Preface to volume 90

Denmark, S. E., Jan 1 2016, In : Organic Reactions. 90, 1, p. vii-viii

Research output: Contribution to journalEditorial

2015

Reinvestigation of a Catalytic, Enantioselective Alkene Dibromination and Chlorohydroxylation

Denmark, S. E. & Carson, N., Nov 13 2015, In : Organic Letters. 17, 23, p. 5728-5731 4 p.

Research output: Contribution to journalArticle

2020

Demystifying the asymmetry-amplifying, autocatalytic behaviour of the Soai reaction through structural, mechanistic and computational studies

Athavale, S. V., Simon, A., Houk, K. N. & Denmark, S. E., Apr 1 2020, In : Nature Chemistry. 12, 4, p. 412-423 12 p.

Research output: Contribution to journalArticle

2014

Preface to volume 84

Denmark, S. E., Jan 1 2014, In : Organic Reactions. 84, 1, p. vii-viii

Research output: Contribution to journalEditorial

2011

Cross-coupling with organosilicon compounds

Chang, W. T. T., Smith, R. C., Regens, C. S., Bailey, A. D., Werner, N. S. & Denmark, S. E., Dec 1 2011, In : Organic Reactions. 75, 1, p. 213-745 533 p.

Research output: Contribution to journalArticle

2015

Preface to volume 87

Denmark, S. E., Jan 1 2015, In : Organic Reactions. 87, 1, p. vii-ix

Research output: Contribution to journalEditorial

2016

Preface to volume 89

Denmark, S. E., Jan 1 2016, In : Organic Reactions. 89, 1, p. vii-viii

Research output: Contribution to journalEditorial

2011

Stereocontrolled total syntheses of isodomoic acids G and H via a unified strategy

Denmark, S. E., Liu, J. H. C. & Muhuhi, J. M., Jan 7 2011, In : Journal of Organic Chemistry. 76, 1, p. 201-215 15 p.

Research output: Contribution to journalArticle

2013

Lewis base activation of Lewis acids: Group 13. in situ generation and reaction of borenium ions

Denmark, S. E. & Ueki, Y., Nov 25 2013, In : Organometallics. 32, 22, p. 6631-6634 4 p.

Research output: Contribution to journalArticle

2016

Toward Catalytic, Enantioselective Chlorolactonization of 1,2-Disubstituted Styrenyl Carboxylic Acids

Denmark, S. E., Ryabchuk, P., Burk, M. T. & Gilbert, B. B., Nov 4 2016, In : Journal of Organic Chemistry. 81, 21, p. 10411-10423 13 p.

Research output: Contribution to journalArticle

2014

Catalytic, enantioselective, intramolecular carbosulfenylation of olefins. preparative and stereochemical aspects

Denmark, S. E. & Jaunet, A., Jan 3 2014, In : Journal of Organic Chemistry. 79, 1, p. 140-171 32 p.

Research output: Contribution to journalArticle

2013

Carbanion-accelerated claisen rearrangements: Asymmetric induction with chiral phosphorus-stabilized anions

Denmark, S. E., Marlin, J. E. & Rajendra, G., Jan 4 2013, In : Journal of Organic Chemistry. 78, 1, p. 66-82 17 p.

Research output: Contribution to journalArticle

2018

Selective extraction of supported Rh nanoparticles under mild, non-acidic conditions with carbon monoxide

Ibrahim, M. Y. S. & Denmark, S. E., Jan 1 2018, In : Journal of Materials Chemistry A. 6, 37, p. 18075-18083 9 p.

Research output: Contribution to journalArticle

2019

A Dinuclear Mechanism Implicated in Controlled Carbene Polymerization

Zhukhovitskiy, A. V., Kobylianskii, I. J., Thomas, A. A., Evans, A. M., Delaney, C. P., Flanders, N. C., Denmark, S. E., DIchtel, W. R. & Toste, F. D., Apr 24 2019, In : Journal of the American Chemical Society. 141, 16, p. 6473-6478 6 p.

Research output: Contribution to journalArticle

2015

Mechanistic significance of the Si-O-Pd bond in the palladium-catalyzed cross-coupling reactions of alkenylsilanolates

Tymonko, S. A., Smith, R. C., Ambrosi, A. & Denmark, S. E., May 20 2015, In : Journal of the American Chemical Society. 137, 19, p. 6192-6199 8 p.

Research output: Contribution to journalArticle

Open Access
2014

Lewis base catalyzed, enantioselective, intramolecular sulfenoamination of olefins

Denmark, S. E. & Chi, H. M., Jun 25 2014, In : Journal of the American Chemical Society. 136, 25, p. 8915-8918 4 p.

Research output: Contribution to journalArticle

2013

Catalytic, enantioselective, intramolecular carbosulfenylation of olefins

Denmark, S. E. & Jaunet, A., May 1 2013, In : Journal of the American Chemical Society. 135, 17, p. 6419-6422 4 p.

Research output: Contribution to journalArticle

2019

Enantioselective, lewis base-catalyzed, intermolecular sulfenoamination of alkenes

Roth, A. & Denmark, S. E., Sep 4 2019, In : Journal of the American Chemical Society. 141, 35, p. 13767-13771 5 p.

Research output: Contribution to journalArticle

2013

Organosilicon Compounds in Cross-Coupling Reactions

Denmark, S. E. & Sweis, R. F., Nov 30 2013, Metal Catalyzed Cross-Coupling Reactions and More. Wiley-VCH Verlag, Vol. 3. p. 475-532 58 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

2016

Principles, Definitions, Terminology, and Orbital Analysis of Lewis Base-Lewis Acid Interactions Leading to Catalysis

Denmark, S. E. & Beutner, G. L., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 1. p. 33-54 22 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

2014

Enantioselective construction of quaternary stereogenic carbon atoms by the lewis base catalyzed additions of silyl ketene imines to aldehydes

Denmark, S. E., Wilson, T. W. & Burk, M. T., Jul 21 2014, In : Chemistry - A European Journal. 20, 30, p. 9268-9279 12 p.

Research output: Contribution to journalArticle

2020

Asymmetric Hydrogenation of Unfunctionalized Tetrasubstituted Acyclic Olefins

Bigler, R., Mack, K. A., Shen, J., Tosatti, P., Han, C., Bachmann, S., Zhang, H., Scalone, M., Pfaltz, A., Denmark, S. E., Hildbrand, S. & Gosselin, F., Feb 10 2020, In : Angewandte Chemie - International Edition. 59, 7, p. 2844-2849 6 p.

Research output: Contribution to journalArticle

2012

Lewis base catalyzed enantioselective additions of an N-silyl vinylketene imine

Denmark, S. E. & Wilson, T. W., Mar 26 2012, In : Angewandte Chemie - International Edition. 51, 13, p. 3236-3239 4 p.

Research output: Contribution to journalArticle

2015

Catalytic, Stereoselective Dihalogenation of Alkenes: Challenges and Opportunities

Cresswell, A. J., Eey, S. T. C. & Denmark, S. E., Dec 21 2015, In : Angewandte Chemie - International Edition. 54, 52, p. 15642-15682 41 p.

Research output: Contribution to journalReview article

2014

Tandem [4+2]/[3+2] Cycloadditions

Baiazitov, R. Y. & Denmark, S. E., Feb 10 2014, Methods and Applications of Cycloaddition Reactions in Organic Syntheses. Wiley-Blackwell, Vol. 9781118299883. p. 471-550 80 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

2017

Room Temperature, Reductive Alkylation of Activated Methylene Compounds: Carbon-Carbon Bond Formation Driven by the Rhodium-Catalyzed Water-Gas Shift Reaction

Denmark, S. E., Ibrahim, M. Y. S. & Ambrosi, A., Jan 6 2017, In : ACS Catalysis. 7, 1, p. 613-630 18 p.

Research output: Contribution to journalArticle

2012

Organic reactions. Volume 78

Denmark, S. E., 2012, Hoboken, N, J: Wiley.

Research output: Book/Report/Conference proceedingBook

2019

Potassium Trimethylsilanolate Enables Rapid, Homogeneous Suzuki-Miyaura Cross-Coupling of Boronic Esters

Delaney, C. P., Kassel, V. M. & Denmark, S. E., Jan 1 2019, (Accepted/In press) In : ACS Catalysis. p. 73-80 8 p.

Research output: Contribution to journalArticle

Enantio- and Diastereoselective, Lewis Base Catalyzed, Cascade Sulfenoacetalization of Alkenyl Aldehydes

Matviitsuk, A. & Denmark, S. E., Jan 1 2019, In : Angewandte Chemie - International Edition. 58, 36, p. 12486-12490 5 p.

Research output: Contribution to journalArticle

2016

Bifunctional and Synergistic Catalysis: Lewis Acid Catalysis and Lewis Base-Assisted Bond Polarization (n → σ*)

Chung, W. J. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1213-1258 46 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

2018

Organic Synthesis: Wherefrom and Whither? (Some Very Personal Reflections)

Denmark, S. E., Feb 2018, In : Israel Journal of Chemistry. 58, 1, p. 61-72 12 p.

Research output: Contribution to journalArticle

2013

Lewis base catalysis of the Mukaiyama directed aldol reaction: 40years of inspiration and advances

Beutner, G. L. & Denmark, S. E., Aug 26 2013, In : Angewandte Chemie - International Edition. 52, 35, p. 9086-9096 11 p.

Research output: Contribution to journalReview article

2018
2016

Lewis Base Catalysis in Organic Synthesis

Vedejs, E. & Denmark, S. E., Aug 17 2016, Wiley-VCH Verlag. 1400 p.

Research output: Book/Report/Conference proceedingBook

2017