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  • Scott E Denmark
2019

Unusual Kinetic Profiles for Lewis Base-Catalyzed Sulfenocyclization of ortho -Geranylphenols in Hexafluoroisopropyl Alcohol

Robb, K. A., Athavale, S. V. & Denmark, S. E., Jan 1 2019, In : Synlett. 30, 14, p. 1656-1661 6 p.

Research output: Contribution to journalArticle

2016

Lewis Base Catalysis: A Platform for Enantioselective Addition to Alkenes Using Group 16 and 17 Lewis Acids (n → σ*)

Kalyani, D., Kornfilt, D. J. P., Burk, M. T. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1153-1211 59 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

2011

Development and mechanistic investigation of the palladium-catalyzed α-arylation of aldehydes and N-arylation of ammonia

Vo, G. D., White, M. C., Hartwig, J. F., Denmark, S. E. & Girolami, G. S., 2011, Urbana, Il: University of Illinois.

Research output: Book/Report/Conference proceedingBook

2016

Preface to volume 91

Denmark, S. E., Jan 1 2016, In : Organic Reactions. 91, 1, p. vii-viii

Research output: Contribution to journalEditorial

2013

Carbanion-accelerated claisen rearrangements: Asymmetric induction with chiral phosphorus-stabilized anions

Denmark, S. E., Marlin, J. E. & Rajendra, G., Jan 4 2013, In : Journal of Organic Chemistry. 78, 1, p. 66-82 17 p.

Research output: Contribution to journalArticle

2015

Redefining q: Quaternary ammonium cross sectional area (XSA) as a general descriptor for transport-limiting PTC rate approximations

Denmark, S. E. & Henle, J. J., Apr 1 2015, In : Chemical Science. 6, 4, p. 2211-2218 8 p.

Research output: Contribution to journalArticle

2010

Palladium-catalyzed cross-coupling of five-membered heterocyclic silanolates

Denmark, S. E., Baird, J. & Regens, C., Mar 2010, In : Chemtracts. 23, 2, p. 41-46 6 p.

Research output: Contribution to journalReview article

Organocerium additions to proline-derived hydrazones: Synthesis of enantiomerically enriched amines

Denmark, S. E., Edwards, J. P., Weber, T. & Piotrowski, D. W., May 17 2010, In : Tetrahedron Asymmetry. 21, 9-10, p. 1278-1302 25 p.

Research output: Contribution to journalArticle

2016

Preface to volume 90

Denmark, S. E., Jan 1 2016, In : Organic Reactions. 90, 1, p. vii-viii

Research output: Contribution to journalEditorial

2010

Sequential processes in palladium-catalyzed silicon-based cross-coupling

Denmark, S. E. & Liu, J. H. C., Dec 1 2010, In : Israel Journal of Chemistry. 50, 5-6, p. 577-587 11 p.

Research output: Contribution to journalReview article

2019

Evaluating continuous chirality measure as a 3D descriptor in chemoinformatics applied to asymmetric catalysis

Zahrt, A. F. & Denmark, S. E., Mar 29 2019, In : Tetrahedron. 75, 13, p. 1841-1851 11 p.

Research output: Contribution to journalArticle

Preface to volume 98

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 98, p. vii-x

Research output: Contribution to journalEditorial

2012

Organic reactions. Volume 77

Denmark, S. E., 2012, Hoboken, N, J: Wiley-Blackwell.

Research output: Book/Report/Conference proceedingBook

2016

Summation

Vedejs, E. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1351-1353 3 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

2011
2012

On the stereochemical course of the addition of allylsilanes to aldehydes

Denmark, S. E., Weber, E. J., Almstead, N. G. & Wolf, L. M., Sep 16 2012, In : Tetrahedron. 68, 37, p. 7701-7718 18 p.

Research output: Contribution to journalArticle

2015

Development of chiral bis-hydrazone ligands for the enantioselective cross-coupling reactions of aryldimethylsilanolates

Denmark, S. E., Chang, W. T. T., Houk, K. N. & Liu, P., Jan 1 2015, In : Journal of Organic Chemistry. 80, 1, p. 313-366 54 p.

Research output: Contribution to journalArticle

2017

Preface to volume 93

Denmark, S. E., Jan 1 2017, In : Organic Reactions. 93, 1, p. vii-viii

Research output: Contribution to journalEditorial

2014

Asymmetric construction of quaternary stereogenic centers via auxiliary-based SN2′ reactions: A case of 1,7-relative stereogenesis

Denmark, S. E. & Marble, L. K., Jan 1 2014, In : Heterocycles. 88, 1, p. 559-590 32 p.

Research output: Contribution to journalArticle

2019

(R)-n,n’-dimethyl-1,1’-binaphthyldiamine

Denmark, S. E. & Ryabchuk, P. G., Jan 1 2019, In : Organic Syntheses. 96, p. 382-399 18 p.

Research output: Contribution to journalArticle

Open Access

Preface to volume 99

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 99, p. vii-ix

Research output: Contribution to journalEditorial

2015

Why You Really Should Consider Using Palladium-Catalyzed Cross-Coupling of Silanols and Silanolates

Denmark, S. E. & Ambrosi, A., Jul 30 2015, In : Organic Process Research and Development. 19, 8, p. 982-994 13 p.

Research output: Contribution to journalArticle

2014

Mechanistic, crystallographic, and computational studies on the catalytic, enantioselective sulfenofunctionalization of alkenes

Denmark, S. E., Hartmann, E., Kornfilt, D. J. P. & Wang, H., Dec 2014, In : Nature Chemistry. 6, 12, p. 1056-1064 9 p.

Research output: Contribution to journalArticle

2011
2014

Catalytic conjugate addition of acyl anion equivalents promoted by fluorodesilylation

Denmark, S. E. & Cullen, L. R., Jan 3 2014, In : Organic Letters. 16, 1, p. 70-73 4 p.

Research output: Contribution to journalArticle

2019

Dynamically Chiral Helical Polymers: A New Frontier in Asymmetric Catalysis?

Denmark, S. E., Jul 24 2019, In : ACS Central Science. 5, 7, p. 1117-1119 3 p.

Research output: Contribution to journalArticle

Open Access
2015

Catalytic, stereospecific syn-dichlorination of alkenes

Cresswell, A. J., Eey, S. T. C. & Denmark, S. E., Feb 2015, In : Nature Chemistry. 7, 2, p. 146-152 7 p.

Research output: Contribution to journalArticle

2017

Catalytic, Enantioselective, Intramolecular Sulfenofunctionalization of Alkenes with Phenols

Denmark, S. E. & Kornfilt, D. J. P., Mar 17 2017, In : Journal of Organic Chemistry. 82, 6, p. 3192-3222 31 p.

Research output: Contribution to journalArticle

2011

Cross-coupling with organosilicon compounds

Chang, W. T. T., Smith, R. C., Regens, C. S., Bailey, A. D., Werner, N. S. & Denmark, S. E., Dec 1 2011, In : Organic Reactions. 75, 1, p. 213-745 533 p.

Research output: Contribution to journalArticle

2010

On the stereochemical course of palladium-catalyzed cross-coupling of allylic silanolate salts with aromatic bromides

Denmark, S. E. & Werner, N. S., Mar 17 2010, In : Journal of the American Chemical Society. 132, 10, p. 3612-3620 9 p.

Research output: Contribution to journalArticle

2019

Catalytic, Enantioselective syn-Diamination of Alkenes

Tao, Z., Gilbert, B. B. & Denmark, S. E., Dec 4 2019, In : Journal of the American Chemical Society. 141, 48, p. 19161-19170 10 p.

Research output: Contribution to journalArticle

2010
2012

Effects of charge separation, effective concentration, and aggregate formation on the phase transfer catalyzed alkylation of phenol

Denmark, S. E., Weintraub, R. C. & Gould, N. D., Aug 15 2012, In : Journal of the American Chemical Society. 134, 32, p. 13415-13429 15 p.

Research output: Contribution to journalArticle

2014

ExCage

Dale, E. J., Vermeulen, N. A., Thomas, A. A., Barnes, J. C., Juríček, M., Blackburn, A. K., Strutt, N. L., Sarjeant, A. A., Stern, C. L., Denmark, S. E. & Stoddart, J. F., Jul 30 2014, In : Journal of the American Chemical Society. 136, 30, p. 10669-10682 14 p.

Research output: Contribution to journalArticle

2019

Enantioselective, lewis base-catalyzed, intermolecular sulfenoamination of alkenes

Roth, A. & Denmark, S. E., Sep 4 2019, In : Journal of the American Chemical Society. 141, 35, p. 13767-13771 5 p.

Research output: Contribution to journalArticle

2015

Mechanistic significance of the Si-O-Pd bond in the palladium-catalyzed cross-coupling reactions of alkenylsilanolates

Tymonko, S. A., Smith, R. C., Ambrosi, A. & Denmark, S. E., May 20 2015, In : Journal of the American Chemical Society. 137, 19, p. 6192-6199 8 p.

Research output: Contribution to journalArticle

Open Access
2014

Lewis base catalyzed, enantioselective, intramolecular sulfenoamination of olefins

Denmark, S. E. & Chi, H. M., Jun 25 2014, In : Journal of the American Chemical Society. 136, 25, p. 8915-8918 4 p.

Research output: Contribution to journalArticle

2015

Mechanistic significance of the Si-O-Pd bond in the palladium-catalyzed cross-coupling reactions of arylsilanolates

Tymonko, S. A., Smith, R. C., Ambrosi, A., Ober, M. H., Wang, H. & Denmark, S. E., May 20 2015, In : Journal of the American Chemical Society. 137, 19, p. 6200-6218 19 p.

Research output: Contribution to journalArticle

Open Access
2013

Catalytic, enantioselective, intramolecular carbosulfenylation of olefins

Denmark, S. E. & Jaunet, A., May 1 2013, In : Journal of the American Chemical Society. 135, 17, p. 6419-6422 4 p.

Research output: Contribution to journalArticle

2018

Synthesis, Reactivity, Functionalization, and ADMET Properties of Silicon-Containing Nitrogen Heterocycles

Barraza, S. J. & Denmark, S. E., May 30 2018, In : Journal of the American Chemical Society. 140, 21, p. 6668-6684 17 p.

Research output: Contribution to journalArticle

Enantioselective, Lewis Base-Catalyzed Sulfenocyclization of Polyenes

Tao, Z., Robb, K. A., Zhao, K. & Denmark, S. E., Mar 14 2018, In : Journal of the American Chemical Society. 140, 10, p. 3569-3573 5 p.

Research output: Contribution to journalArticle

2017

Structural, Kinetic, and Computational Characterization of the Elusive Arylpalladium(II)boronate Complexes in the Suzuki-Miyaura Reaction

Thomas, A. A., Wang, H., Zahrt, A. F. & Denmark, S. E., Mar 15 2017, In : Journal of the American Chemical Society. 139, 10, p. 3805-3821 17 p.

Research output: Contribution to journalArticle

2018

Elucidating the Role of the Boronic Esters in the Suzuki-Miyaura Reaction: Structural, Kinetic, and Computational Investigations

Thomas, A. A., Zahrt, A. F., Delaney, C. P. & Denmark, S. E., Mar 28 2018, In : Journal of the American Chemical Society. 140, 12, p. 4401-4416 16 p.

Research output: Contribution to journalArticle

2014

Catalytic, enantioselective, intramolecular carbosulfenylation of olefins. preparative and stereochemical aspects

Denmark, S. E. & Jaunet, A., Jan 3 2014, In : Journal of Organic Chemistry. 79, 1, p. 140-171 32 p.

Research output: Contribution to journalArticle

2012

Enantioselective bromocycloetherification by Lewis base/chiral Brønsted acid cooperative catalysis

Denmark, S. E. & Burk, M. T., Jan 6 2012, In : Organic Letters. 14, 1, p. 256-259 4 p.

Research output: Contribution to journalArticle

2014

Preface to volume 84

Denmark, S. E., Jan 1 2014, In : Organic Reactions. 84, 1, p. vii-viii

Research output: Contribution to journalEditorial

2019

Enantio- and Diastereoselective, Lewis Base Catalyzed, Cascade Sulfenoacetalization of Alkenyl Aldehydes

Matviitsuk, A. & Denmark, S. E., Jan 1 2019, In : Angewandte Chemie - International Edition. 58, 36, p. 12486-12490 5 p.

Research output: Contribution to journalArticle

2012

Organic reactions. Volume 78

Denmark, S. E., 2012, Hoboken, N, J: Wiley.

Research output: Book/Report/Conference proceedingBook

2014

Enantioselective construction of quaternary stereogenic carbon atoms by the lewis base catalyzed additions of silyl ketene imines to aldehydes

Denmark, S. E., Wilson, T. W. & Burk, M. T., Jul 21 2014, In : Chemistry - A European Journal. 20, 30, p. 9268-9279 12 p.

Research output: Contribution to journalArticle