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2017

Catalytic, Enantioselective, Intramolecular Sulfenofunctionalization of Alkenes with Phenols

Denmark, S. E. & Kornfilt, D. J. P., Mar 17 2017, In : Journal of Organic Chemistry. 82, 6, p. 3192-3222 31 p.

Research output: Contribution to journalArticle

Phenols
Alkenes
Lewis Bases
Cyclization
Benzoxepins

Understanding Site Selectivity in the Palladium-Catalyzed Cross-Coupling of Allenylsilanolates

Denmark, S. E. & Ambrosi, A., Nov 13 2017, In : Synlett. 28, 18, p. 2415-2420 6 p.

Research output: Contribution to journalArticle

Palladium
Isomers
Tuning
2016

Preface to volume 91

Denmark, S. E., Jan 1 2016, In : Organic Reactions. 91, 1, p. vii-viii

Research output: Contribution to journalEditorial

Lewis Base-Catalyzed, Lewis Acid-Mediated Reactions (n → σ*)

Rossi, S. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1039-1076 38 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Lewis Acids
Silicon
Phosphoramides
Methyl Ethers
2010

Lewis base catalysis of bromo- and iodolactonization, and cycloetherification

Denmark, S. E. & Burk, M. T., Nov 30 2010, In : Proceedings of the National Academy of Sciences of the United States of America. 107, 48, p. 20655-20660 6 p.

Research output: Contribution to journalArticle

Lewis Bases
Cyclization
Catalysis
Ions
2015

Development of a Phase-Transfer-Catalyzed, [2,3]-Wittig Rearrangement

Denmark, S. E. & Cullen, L. R., Oct 2 2015, In : Journal of Organic Chemistry. 80, 23, p. 11818-11848 31 p.

Research output: Contribution to journalArticle

Catalysis
Carbonyl compounds
Catalysts
Enantioselectivity
Substrates

Reinvestigation of a Catalytic, Enantioselective Alkene Dibromination and Chlorohydroxylation

Denmark, S. E. & Carson, N., Nov 13 2015, In : Organic Letters. 17, 23, p. 5728-5731 4 p.

Research output: Contribution to journalArticle

Enantioselectivity
Alkenes
Nuclear magnetic resonance spectroscopy
alkenes
High Pressure Liquid Chromatography
2012

Organic reactions. Volume 78

Denmark, S. E., 2012, Hoboken, N, J: Wiley.

Research output: Book/ReportBook

Organic reactions. Volume 77

Denmark, S. E., 2012, Hoboken, N, J: Wiley-Blackwell.

Research output: Book/ReportBook

2018

Synthesis, Reactivity, Functionalization, and ADMET Properties of Silicon-Containing Nitrogen Heterocycles

Barraza, S. J. & Denmark, S. E., May 30 2018, In : Journal of the American Chemical Society. 140, 21, p. 6668-6684 17 p.

Research output: Contribution to journalArticle

Silicon
Metabolism
excretion
silicon
Toxicity
2019

Enantioselective, lewis base-catalyzed, intermolecular sulfenoamination of alkenes

Roth, A. & Denmark, S. E., Sep 4 2019, In : Journal of the American Chemical Society. 141, 35, p. 13767-13771 5 p.

Research output: Contribution to journalArticle

Lewis Bases
alkene
Alkenes
Sulfur
Olefins
2013

Preface to volume 82

Denmark, S. E., 2013, In : Organic Reactions. 82, 1, p. Vii-Viii

Research output: Contribution to journalEditorial

2010

Preface to special issue of heterocycles honoring the 85th birthday of prof. Dr. Albert eschenmoser

Denmark, S. E. & Sorensen, E. J., Dec 1 2010, In : Heterocycles. 82, 1, p. 5-10 6 p.

Research output: Contribution to journalReview article

2011
Ammonium Compounds
Catalyst activity
Ions
Catalysts
Catalysis
2013
Acetaldehyde
acetaldehyde
Static Electricity
Chemical activation
Electrostatics
2012

Enantioselective bromocycloetherification by Lewis base/chiral Brønsted acid cooperative catalysis

Denmark, S. E. & Burk, M. T., Jan 6 2012, In : Organic Letters. 14, 1, p. 256-259 4 p.

Research output: Contribution to journalArticle

Lewis Bases
Lewis base
Enantioselectivity
Cyclization
Catalysis
2017

Catalytic, Enantioselective, Intramolecular Sulfenoamination of Alkenes with Anilines

Denmark, S. E. & Chi, H. M., Apr 7 2017, In : Journal of Organic Chemistry. 82, 7, p. 3826-3843 18 p.

Research output: Contribution to journalArticle

Aniline Compounds
Nucleophiles
Enantioselectivity
Alkenes
Catalysts
2011

Stereocontrolled total syntheses of isodomoic acids G and H via a unified strategy

Denmark, S. E., Liu, J. H. C. & Muhuhi, J. M., Jan 7 2011, In : Journal of Organic Chemistry. 76, 1, p. 201-215 15 p.

Research output: Contribution to journalArticle

Iodides
Silicon
Rhodium
Cyclization
Molecules
2015

Development of chiral bis-hydrazone ligands for the enantioselective cross-coupling reactions of aryldimethylsilanolates

Denmark, S. E., Chang, W. T. T., Houk, K. N. & Liu, P., Jan 1 2015, In : Journal of Organic Chemistry. 80, 1, p. 313-366 54 p.

Research output: Contribution to journalArticle

Hydrazones
Enantioselectivity
Ligands
Glyoxal
Stereoselectivity
2014
Lewis Bases
Alkenes
catalysis
Catalysis
Olefins
2019

Unusual Kinetic Profiles for Lewis Base-Catalyzed Sulfenocyclization of ortho -Geranylphenols in Hexafluoroisopropyl Alcohol

Robb, K. A., Athavale, S. V. & Denmark, S. E., Jan 1 2019, In : Synlett. 30, 14, p. 1656-1661 6 p.

Research output: Contribution to journalArticle

Lewis Bases
Polyenes
Alcohols
Nucleophiles
Kinetics
2010

Sequential processes in palladium-catalyzed silicon-based cross-coupling

Denmark, S. E. & Liu, J. H. C., Dec 1 2010, In : Israel Journal of Chemistry. 50, 5-6, p. 577-587 11 p.

Research output: Contribution to journalReview article

Palladium
Silicon
Substrates
Biological Products
Toxicity
2011

Probing the electronic demands of transmetalation in the palladium-catalyzed cross-coupling of arylsilanolates

Denmark, S. E., Smith, R. C. & Chang, W. T. T., Jun 17 2011, In : Tetrahedron. 67, 24, p. 4391-4396 6 p.

Research output: Contribution to journalArticle

Palladium
Electrons
Nucleophiles
Cross Reactions
Silicon
2010

Palladium-catalyzed cross-coupling of five-membered heterocyclic silanolates

Denmark, S. E., Baird, J. & Regens, C., Mar 2010, In : Chemtracts. 23, 2, p. 41-46 6 p.

Research output: Contribution to journalReview article

Cross Reactions
Palladium
Alkali Metals
Iodides
Derivatives
2011
Cross Reactions
Palladium
2013

Lewis base catalysis of the Mukaiyama directed aldol reaction: 40years of inspiration and advances

Beutner, G. L. & Denmark, S. E., Aug 26 2013, In : Angewandte Chemie - International Edition. 52, 35, p. 9086-9096 11 p.

Research output: Contribution to journalReview article

Lewis Bases
Addition reactions
Catalysis
Catalyst selectivity
Enantioselectivity
2015

Why You Really Should Consider Using Palladium-Catalyzed Cross-Coupling of Silanols and Silanolates

Denmark, S. E. & Ambrosi, A., Jul 30 2015, In : Organic Process Research and Development. 19, 8, p. 982-994 13 p.

Research output: Contribution to journalArticle

cross coupling
Palladium
Silicon
palladium
Fluorides
2014

ExCage

Dale, E. J., Vermeulen, N. A., Thomas, A. A., Barnes, J. C., Juríček, M., Blackburn, A. K., Strutt, N. L., Sarjeant, A. A., Stern, C. L., Denmark, S. E. & Stoddart, J. F., Jul 30 2014, In : Journal of the American Chemical Society. 136, 30, p. 10669-10682 14 p.

Research output: Contribution to journalArticle

Polycyclic Aromatic Hydrocarbons
Polycyclic aromatic hydrocarbons
PAH
Pyrene
Complexation
2016

Bifunctional and Synergistic Catalysis: Lewis Acid Catalysis and Lewis Base-Assisted Bond Polarization (n → σ*)

Chung, W. J. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1213-1258 46 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Lewis Acids
Catalysis
Polarization
Chemical activation
2019

Dynamically Chiral Helical Polymers: A New Frontier in Asymmetric Catalysis?

Denmark, S. E., Jul 24 2019, In : ACS Central Science. 5, 7, p. 1117-1119 3 p.

Research output: Contribution to journalArticle

Open Access
Catalysis
Polymers
Catalysts

Prediction of higher-selectivity catalysts by computer-driven workflow and machine learning

Zahrt, A. F., Henle, J. J., Rose, B. T., Wang, Y., Darrow, W. T. & Denmark, S. E., Jan 18 2019, In : Science. 363, 6424, eaau5631.

Research output: Contribution to journalArticle

Workflow
Empiricism
Sulfhydryl Compounds
Machine Learning
Support Vector Machine
2015

Mechanistic significance of the Si-O-Pd bond in the palladium-catalyzed cross-coupling reactions of arylsilanolates

Tymonko, S. A., Smith, R. C., Ambrosi, A., Ober, M. H., Wang, H. & Denmark, S. E., May 20 2015, In : Journal of the American Chemical Society. 137, 19, p. 6200-6218 19 p.

Research output: Contribution to journalArticle

Open Access
Cross Reactions
palladium
Palladium
phosphine
Hot Temperature
2018

Organic Synthesis: Wherefrom and Whither? (Some Very Personal Reflections)

Denmark, S. E., Feb 2018, In : Israel Journal of Chemistry. 58, 1, p. 61-72 12 p.

Research output: Contribution to journalArticle

Steroid hormones
Oral Contraceptives
Biological Products
Health
Molecules
2014

Lewis base catalyzed, enantioselective, intramolecular sulfenoamination of olefins

Denmark, S. E. & Chi, H. M., Jun 25 2014, In : Journal of the American Chemical Society. 136, 25, p. 8915-8918 4 p.

Research output: Contribution to journalArticle

Lewis Bases
alkene
Alkenes
Olefins
Pyrrolidines
Allylation
Water gas shift
Aldehydes
Acetates
Carbon
2012

On the stereochemical course of the addition of allylsilanes to aldehydes

Denmark, S. E., Weber, E. J., Almstead, N. G. & Wolf, L. M., Sep 16 2012, In : Tetrahedron. 68, 37, p. 7701-7718 18 p.

Research output: Contribution to journalArticle

Cyclization
Aldehydes
Lewis Acids
allylsilane
2019

Organoselenium-catalyzed enantioselective syn-dichlorination of unbiased alkenes

Gilbert, B. B., Eey, S. T. C., Ryabchuk, P., Garry, O. & Denmark, S. E., Aug 2 2019, In : Tetrahedron. 75, 31, p. 4086-4098 13 p.

Research output: Contribution to journalArticle

Alkenes
Synthetic Chemistry Techniques
Biological Products
Chlorides
Kinetics
2012

Organic reactions. Volume 76

Denmark, S. E., 2012, Hoboken, N, J: Wiley.

Research output: Book/ReportBook

2017

Preface to volume 92

Denmark, S. E., Jan 1 2017, In : Organic Reactions. 92, 1, p. vii-viii

Research output: Contribution to journalEditorial

2019

Catalytic, Enantioselective syn-Diamination of Alkenes

Tao, Z., Gilbert, B. B. & Denmark, S. E., Dec 4 2019, In : Journal of the American Chemical Society. 141, 48, p. 19161-19170 10 p.

Research output: Contribution to journalArticle

alkene
Alkenes
Olefins
Bearings (structural)
catalysis
2014

Preface to volume 83

Denmark, S. E., 2014, In : Organic Reactions. 83, 1, p. Vii-Viii

Research output: Contribution to journalEditorial

2011
Catalyst selectivity
Ammonium Compounds
Catalyst activity
Ions
Catalysts
2018

Catalytic Nucleophilic Allylation Driven by the Water-Gas Shift Reaction

Denmark, S. E., Matesich, Z. D., Nguyen, S. T. & Milicevic Sephton, S., Jan 5 2018, In : Journal of Organic Chemistry. 83, 1, p. 23-48 26 p.

Research output: Contribution to journalArticle

Allylation
Nucleophiles
Water gas shift
Aldehydes
Carbon
2016

Principles, Definitions, Terminology, and Orbital Analysis of Lewis Base-Lewis Acid Interactions Leading to Catalysis

Denmark, S. E. & Beutner, G. L., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 1. p. 33-54 22 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Lewis Acids
Terminology
Catalysis
Quantum theory
2017

Room Temperature, Reductive Alkylation of Activated Methylene Compounds: Carbon-Carbon Bond Formation Driven by the Rhodium-Catalyzed Water-Gas Shift Reaction

Denmark, S. E., Ibrahim, M. Y. S. & Ambrosi, A., Jan 6 2017, In : ACS Catalysis. 7, 1, p. 613-630 18 p.

Research output: Contribution to journalArticle

Rhodium
Water gas shift
Alkylation
Carbon
Alkylating Agents
2010
Lewis Bases
Imines
Ketones
Aldehydes
Carbon
2017

Structural, Kinetic, and Computational Characterization of the Elusive Arylpalladium(II)boronate Complexes in the Suzuki-Miyaura Reaction

Thomas, A. A., Wang, H., Zahrt, A. F. & Denmark, S. E., Mar 15 2017, In : Journal of the American Chemical Society. 139, 10, p. 3805-3821 17 p.

Research output: Contribution to journalArticle

ligand
Ligands
Boronic Acids
kinetics
Kinetics
2019

Preface to volume 99

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 99, p. vii-ix

Research output: Contribution to journalEditorial

2016

Preface

Vedejs, E. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 1-3. p. xxvii-xxxii

Research output: Chapter in Book/Report/Conference proceedingForeword/postscript

Speech synthesis