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Author

  • Thomas B Rauchfuss
2019

Synthetic Designs and Structural Investigations of Biomimetic Ni-Fe Thiolates

Basu, D., Bailey, T. S., Lalaoui, N., Richers, C. P., Woods, T. J., Rauchfuss, T. B., Arrigoni, F. & Zampella, G., Feb 18 2019, In : Inorganic Chemistry. 58, 4, p. 2430-2443 14 p.

Research output: Contribution to journalArticle

2017

Syntheses of transition metal methoxysiloxides

Richers, C. P., Bertke, J. A. & Rauchfuss, T. B., Jan 1 2017, In : Dalton Transactions. 46, 27, p. 8756-8762 7 p.

Research output: Contribution to journalArticle

2016

Cobalt Phosphino-α-Iminopyridine-Catalyzed Hydrofunctionalization of Alkenes: Catalyst Development and Mechanistic Analysis

Chu, W. Y., Gilbert-Wilson, R., Rauchfuss, T. B., Van Gastel, M. & Neese, F., Sep 12 2016, In : Organometallics. 35, 17, p. 2900-2914 15 p.

Research output: Contribution to journalArticle

2015

Spectroscopic Investigations of [FeFe] Hydrogenase Maturated with [57Fe2(adt)(CN)2(CO)4]2-

Gilbert-Wilson, R., Siebel, J. F., Adamska-Venkatesh, A., Pham, C. C., Reijerse, E., Wang, H., Cramer, S. P., Lubitz, W. & Rauchfuss, T. B., Jul 22 2015, In : Journal of the American Chemical Society. 137, 28, p. 8998-9005 8 p.

Research output: Contribution to journalArticle

2014

Ferrous carbonyl dithiolates as precursors to FeFe, FeCo, and FeMn carbonyl dithiolates

Carroll, M. E., Chen, J., Gray, D. E., Lansing, J. C., Rauchfuss, T. B., Schilter, D., Volkers, P. I. & Wilson, S. R., Feb 24 2014, In : Organometallics. 33, 4, p. 858-867 10 p.

Research output: Contribution to journalArticle

2013

Organo ruthenium-nickel dithiolates with redox-responsive nickel sites

Chambers, G. M., Angamuthu, R., Gray, D. L. & Rauchfuss, T., Nov 11 2013, In : Organometallics. 32, 21, p. 6324-6329 6 p.

Research output: Contribution to journalArticle

2019

Asymmetry in the Ligand Coordination Sphere of the [FeFe] Hydrogenase Active Site Is Reflected in the Magnetic Spin Interactions of the Aza-propanedithiolate Ligand

Reijerse, E. J., Pelmenschikov, V., Birrell, J. A., Richers, C. P., Kaupp, M., Rauchfuss, T. B., Cramer, S. P. & Lubitz, W., Nov 7 2019, In : Journal of Physical Chemistry Letters. 10, 21, p. 6794-6799 6 p.

Research output: Contribution to journalArticle

Open Access
2012

Reaction of aryl diazonium salts and diiron(I) dithiolato carbonyls: Evidence for radical intermediates

Olsen, M. T., Rauchfuss, T. B. & Zaffaroni, R., Apr 23 2012, In : Organometallics. 31, 8, p. 3447-3450 4 p.

Research output: Contribution to journalArticle

2011

Coordination chemistry of the soft chiral Lewis acid [Cp*Ir(TsDPEN)] +

Letko, C. S., Heiden, Z. M., Rauchfuss, T. B. & Wilson, S. R., Jun 20 2011, In : Inorganic Chemistry. 50, 12, p. 5558-5566 9 p.

Research output: Contribution to journalArticle

2015

N-Substituted Derivatives of the Azadithiolate Cofactor from the [FeFe] Hydrogenases: Stability and Complexation

Angamuthu, R., Chen, C. S., Cochrane, T. R., Gray, D. L., Schilter, D., Ulloa, O. A. & Rauchfuss, T. B., Jun 15 2015, In : Inorganic Chemistry. 54, 12, p. 5717-5724 8 p.

Research output: Contribution to journalArticle

2018

Ni(ii) complexes of the phosphine-oxime Ph2PC6H4-2-CH=NOH

Basu, D., Woods, T. J. & Rauchfuss, T. B., Jan 1 2018, In : Dalton Transactions. 47, 21, p. 7256-7262 7 p.

Research output: Contribution to journalArticle

Electron-Rich, Diiron Bis(monothiolato) Carbonyls: C-S Bond Homolysis in a Mixed Valence Diiron Dithiolate

Li, Q., Lalaoui, N., Woods, T. J., Rauchfuss, T. B., Arrigoni, F. & Zampella, G., Apr 16 2018, In : Inorganic Chemistry. 57, 8, p. 4409-4418 10 p.

Research output: Contribution to journalArticle

2014

Lignol cleavage by Pd/C under mild conditions and without hydrogen: A role for benzylic C=H activation?

Zhou, X., Mitra, J. & Rauchfuss, T. B., Jun 2014, In : ChemSusChem. 7, 6, p. 1623-1626 4 p.

Research output: Contribution to journalArticle

2015

Cooperative metal-ligand reactivity and catalysis in low-spin ferrous alkoxides

Chu, W. Y., Zhou, X. & Rauchfuss, T., May 11 2015, In : Organometallics. 34, 9, p. 1619-1625 7 p.

Research output: Contribution to journalArticle

2017

Characterization of a borane σ complex of a diiron dithiolate: Model for an elusive dihydrogen adduct

Lalaoui, N., Woods, T., Rauchfuss, T. B. & Zampella, G., Jun 12 2017, In : Organometallics. 36, 11, p. 2054-2057 4 p.

Research output: Contribution to journalArticle

Synthetic Models for Nickel-Iron Hydrogenase Featuring Redox-Active Ligands

Schilter, D., Gray, D. L., Fuller, A. L. & Rauchfuss, T. B., 2017, In : Australian Journal of Chemistry. 70, 5, p. 505-515 11 p.

Research output: Contribution to journalArticle

2013

Crystallographic characterization of a fully rotated, basic diiron dithiolate: Model for the Hred state?

Wang, W., Rauchfuss, T. B., Moore, C. E., Rheingold, A. L., Degioia, L. & Zampella, G., Nov 11 2013, In : Chemistry - A European Journal. 19, 46, p. 15476-15479 4 p.

Research output: Contribution to journalArticle

Ligand effects on the overpotential for dioxygen reduction by tris(2-pyridylmethyl)amine derivatives

Thorseth, M. A., Letko, C. S., Tse, E. C. M., Rauchfuss, T. B. & Gewirth, A. A., Jan 18 2013, In : Inorganic Chemistry. 52, 2, p. 628-634 7 p.

Research output: Contribution to journalArticle

2014

Borane-protected cyanides as surrogates of h-bonded cyanides in [FeFe]-hydrogenase active site models

Manor, B. C., Ringenberg, M. R. & Rauchfuss, T. B., Jul 21 2014, In : Inorganic Chemistry. 53, 14, p. 7241-7247 7 p.

Research output: Contribution to journalArticle

2018

A [RuRu] Analogue of an [FeFe]-Hydrogenase Traps the Key Hydride Intermediate of the Catalytic Cycle

Sommer, C., Richers, C. P., Lubitz, W., Rauchfuss, T. B. & Reijerse, E. J., May 4 2018, In : Angewandte Chemie - International Edition. 57, 19, p. 5429-5432 4 p.

Research output: Contribution to journalArticle

2012

Nickel-iron dithiolates related to the deactivated [NiFe]-hydrogenases

Schilter, D. & Rauchfuss, T. B., Nov 21 2012, In : Dalton Transactions. 41, 43, p. 13324-13329 6 p.

Research output: Contribution to journalArticle

2015

Phosphine-iminopyridines as platforms for catalytic hydrofunctionalization of alkenes

Gilbert-Wilson, R., Chu, W. Y. & Rauchfuss, T., Jun 1 2015, In : Inorganic Chemistry. 54, 11, p. 5596-5603 8 p.

Research output: Contribution to journalArticle

2017

Interplay between terminal and bridging diiron hydrides in neutral and oxidized states

Yu, X., Tung, C. H., Wang, W., Huynh, M. T., Gray, D. L., Hammes-Schiffer, S. & Rauchfuss, T. B., Jun 12 2017, In : Organometallics. 36, 11, p. 2245-2253 9 p.

Research output: Contribution to journalArticle

2016

Mechanism of H2 Production by Models for the [NiFe]-Hydrogenases: Role of Reduced Hydrides

Ulloa, O. A., Huynh, M. T., Richers, C. P., Bertke, J. A., Nilges, M. J., Hammes-Schiffer, S. & Rauchfuss, T. B., Jul 27 2016, In : Journal of the American Chemical Society. 138, 29, p. 9234-9245 12 p.

Research output: Contribution to journalArticle

Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides

Schilter, D., Camara, J. M., Huynh, M. T., Hammes-Schiffer, S. & Rauchfuss, T. B., Aug 10 2016, In : Chemical reviews. 116, 15, p. 8693-8749 57 p.

Research output: Contribution to journalReview article

2012

EPR/ENDOR, Mössbauer, and quantum-chemical investigations of diiron complexes mimicking the active oxidized state of [FeFe]hydrogenase

Silakov, A., Olsen, M. T., Sproules, S., Reijerse, E. J., Rauchfuss, T. B. & Lubitz, W., Aug 6 2012, In : Inorganic Chemistry. 51, 15, p. 8617-8628 12 p.

Research output: Contribution to journalArticle

Influence of second coordination sphere hydroxyl groups on the reactivity of copper(I) complexes

Letko, C. S., Rauchfuss, T., Zhou, X. & Gray, D. L., Apr 16 2012, In : Inorganic Chemistry. 51, 8, p. 4511-4520 10 p.

Research output: Contribution to journalArticle

2011

Mild redox complementation enables H 2 activation by [FeFe]-hydrogenase models

Camara, J. M. & Rauchfuss, T., Jun 1 2011, In : Journal of the American Chemical Society. 133, 21, p. 8098-8101 4 p.

Research output: Contribution to journalArticle

2017

Direct Observation of an Iron-Bound Terminal Hydride in [FeFe]-Hydrogenase by Nuclear Resonance Vibrational Spectroscopy

Reijerse, E. J., Pham, C. C., Pelmenschikov, V., Gilbert-Wilson, R., Adamska-Venkatesh, A., Siebel, J. F., Gee, L. B., Yoda, Y., Tamasaku, K., Lubitz, W., Rauchfuss, T. B. & Cramer, S. P., Mar 29 2017, In : Journal of the American Chemical Society. 139, 12, p. 4306-4309 4 p.

Research output: Contribution to journalArticle

2013

Frontiers, opportunities, and challenges in biochemical and chemical catalysis of CO2 fixation

Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., Dubois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., Kerfeld, C. A., Morris, R. H., Peden, C. H. F., Portis, A. R., Ragsdale, S. W., Rauchfuss, T. B., Reek, J. N. H., Seefeldt, L. C., Thauer, R. K. & Waldrop, G. L., Aug 14 2013, In : Chemical reviews. 113, 8, p. 6621-6658 38 p.

Research output: Contribution to journalReview article

2015
Open Access
2011

A new route to azadithiolato complexes

Angamuthu, R., Carroll, M. E., Ramesh, M. & Rauchfuss, T. B., Mar 1 2011, In : European Journal of Inorganic Chemistry. 7, p. 1029-1032 4 p.

Research output: Contribution to journalArticle

2013

Contrasting protonation behavior of diphosphido vs dithiolato diiron(I) carbonyl complexes

Zaffaroni, R., Rauchfuss, T. B., Fuller, A., De Gioia, L. & Zampella, G., Jan 14 2013, In : Organometallics. 32, 1, p. 232-238 7 p.

Research output: Contribution to journalArticle

2011

Stereochemistry of electrophilic attack at 34e- dimetallic complexes: The case of diiron dithiolato carbonyls + MeS+

Olsen, M. T., Gray, D. L., Rauchfuss, T. B., De Gioia, L. & Zampella, G., Jun 21 2011, In : Chemical Communications. 47, 23, p. 6554-6556 3 p.

Research output: Contribution to journalArticle

2012

Synthetic models for the active site of the [FeFe]-hydrogenase: Catalytic proton reduction and the structure of the doubly protonated intermediate

Carroll, M. E., Barton, B. E., Rauchfuss, T. B. & Carroll, P. J., Nov 14 2012, In : Journal of the American Chemical Society. 134, 45, p. 18843-18852 10 p.

Research output: Contribution to journalArticle

2016

Synthesis of Diiron(I) Dithiolato Carbonyl Complexes

Li, Y. & Rauchfuss, T. B., Jun 22 2016, In : Chemical reviews. 116, 12, p. 7043-7077 35 p.

Research output: Contribution to journalReview article

2017

Diiron Dithiolate Hydrides Complemented with Proton-Responsive Phosphine–Amine Ligands

Carlson, M. R., Gilbert-Wilson, R., Gray, D. R., Mitra, J., Rauchfuss, T. B. & Richers, C. P., Jul 7 2017, In : European Journal of Inorganic Chemistry. 2017, 25, p. 3169-3173 5 p.

Research output: Contribution to journalArticle

Open Access

Reaction Coordinate Leading to H2 Production in [FeFe]-Hydrogenase Identified by Nuclear Resonance Vibrational Spectroscopy and Density Functional Theory

Pelmenschikov, V., Birrell, J. A., Pham, C. C., Mishra, N., Wang, H., Sommer, C., Reijerse, E., Richers, C. P., Tamasaku, K., Yoda, Y., Rauchfuss, T. B., Lubitz, W. & Cramer, S. P., Nov 22 2017, In : Journal of the American Chemical Society. 139, 46, p. 16894-16902 9 p.

Research output: Contribution to journalArticle

2016

Models of the Ni-L and Ni-SIa States of the [NiFe]-Hydrogenase Active Site

Chambers, G. M., Huynh, M. T., Li, Y., Hammes-Schiffer, S., Rauchfuss, T. B., Reijerse, E. & Lubitz, W., Jan 19 2016, In : Inorganic Chemistry. 55, 2, p. 419-431 13 p.

Research output: Contribution to journalReview article

2014

Diiron azamonothiolates by the scission of dithiadiazacyclooctanes by iron carbonyls

Lin, T., Ulloa, O. A., Rauchfuss, T. B. & Gray, D. L., Sep 1 2014, In : European Journal of Inorganic Chemistry. 2014, 25, p. 4109-4114 6 p.

Research output: Contribution to journalArticle

2013

And the winner is⋯azadithiolate: An amine proton relay in the [FeFe] hydrogenases

Schilter, D. & Rauchfuss, T. B., Dec 16 2013, In : Angewandte Chemie - International Edition. 52, 51, p. 13518-13520 3 p.

Research output: Contribution to journalArticle

2014

Computational investigation of [FeFe]-hydrogenase models: Characterization of singly and doubly protonated intermediates and mechanistic insights

Huynh, M. T., Wang, W., Rauchfuss, T. B. & Hammes-Schiffer, S., Oct 6 2014, In : Inorganic Chemistry. 53, 19, p. 10301-10311 11 p.

Research output: Contribution to journalArticle

2013

Production of hybrid diesel fuel precursors from carbohydrates and petrochemicals using formic acid as a reactive solvent

Zhou, X. & Rauchfuss, T. B., Feb 1 2013, In : ChemSusChem. 6, 2, p. 383-388 6 p.

Research output: Contribution to journalArticle

2012

Connecting [NiFe]- and [FeFe]-hydrogenases: Mixed-valence nickel-iron dithiolates with rotated structures

Schilter, D., Rauchfuss, T. B. & Stein, M., Aug 20 2012, In : Inorganic Chemistry. 51, 16, p. 8931-8941 11 p.

Research output: Contribution to journalArticle

2014

NiI/RuII model for the Ni-L state of the [NiFe]hydrogenases: Synthesis, spectroscopy, and reactivity

Chambers, G. M., Mitra, J., Rauchfuss, T. & Stein, M., Apr 21 2014, In : Inorganic Chemistry. 53, 8, p. 4243-4249 7 p.

Research output: Contribution to journalArticle

2019

The binuclear cluster of [FeFe] hydrogenase is formed with sulfur donated by cysteine of an [Fe(Cys)(CO)2(CN)] organometallic precursor

Rao, G., Pattenaude, S. A., Alwan, K., Blackburn, N. J., Britt, R. D. & Rauchfuss, T. B., Oct 15 2019, In : Proceedings of the National Academy of Sciences of the United States of America. 116, 42, p. 20850-20855 6 p.

Research output: Contribution to journalArticle

Open Access
2011

Dioxygen and hydrogen peroxide reduction with hemocyanin model complexes

Thorseth, M. A., Letko, C. S., Rauchfuss, T. B. & Gewirth, A. A., Jul 4 2011, In : Inorganic Chemistry. 50, 13, p. 6158-6162 5 p.

Research output: Contribution to journalArticle

2015
2012

Protonation-enhanced Lewis acidity of iridium complexes containing noninnocent amidophenolates

Ringenberg, M. R. & Rauchfuss, T., Jan 1 2012, In : European Journal of Inorganic Chemistry. 3, p. 490-495 6 p.

Research output: Contribution to journalArticle

2019

Iron Carbide-Sulfide Carbonyl Clusters

Liu, L., Rauchfuss, T. B. & Woods, T. J., Jul 1 2019, In : Inorganic Chemistry. 58, 13, p. 8271-8274 4 p.

Research output: Contribution to journalArticle