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Author

  • Thomas B Rauchfuss
2011

Active-site models for the nickel-iron hydrogenases: Effects of ligands on reactivity and catalytic properties

Carroll, M. E., Barton, B. E., Gray, D. L., MacK, A. E. & Rauchfuss, T. B., Oct 3 2011, In : Inorganic Chemistry. 50, 19, p. 9554-9563 10 p.

Research output: Contribution to journalArticle

A new route to azadithiolato complexes

Angamuthu, R., Carroll, M. E., Ramesh, M. & Rauchfuss, T. B., Mar 1 2011, In : European Journal of Inorganic Chemistry. 7, p. 1029-1032 4 p.

Research output: Contribution to journalArticle

Coordination chemistry of the soft chiral Lewis acid [Cp*Ir(TsDPEN)] +

Letko, C. S., Heiden, Z. M., Rauchfuss, T. B. & Wilson, S. R., Jun 20 2011, In : Inorganic Chemistry. 50, 12, p. 5558-5566 9 p.

Research output: Contribution to journalArticle

Dioxygen and hydrogen peroxide reduction with hemocyanin model complexes

Thorseth, M. A., Letko, C. S., Rauchfuss, T. B. & Gewirth, A. A., Jul 4 2011, In : Inorganic Chemistry. 50, 13, p. 6158-6162 5 p.

Research output: Contribution to journalArticle

Mild redox complementation enables H 2 activation by [FeFe]-hydrogenase models

Camara, J. M. & Rauchfuss, T., Jun 1 2011, In : Journal of the American Chemical Society. 133, 21, p. 8098-8101 4 p.

Research output: Contribution to journalArticle

Oxidative addition of a diphosphine anhydride to iron(0) and nickel(0): A simple approach to installing four ligands

Ringenberg, M. R., Gray, D. L. & Rauchfuss, T. B., May 23 2011, In : Organometallics. 30, 10, p. 2885-2888 4 p.

Research output: Contribution to journalArticle

Stereochemistry of electrophilic attack at 34e- dimetallic complexes: The case of diiron dithiolato carbonyls + MeS+

Olsen, M. T., Gray, D. L., Rauchfuss, T. B., De Gioia, L. & Zampella, G., Jun 21 2011, In : Chemical Communications. 47, 23, p. 6554-6556 3 p.

Research output: Contribution to journalArticle

Under sulfur's spell

Rauchfuss, T., Aug 1 2011, In : Nature Chemistry. 3, 8, 1 p.

Research output: Contribution to journalComment/debate

2012

C 2-symmetric iron(II) diphosphine-dialkoxide dicarbonyl and related complexes

Lei, H., Royer, A. M., Rauchfuss, T. B. & Gray, D., Sep 10 2012, In : Organometallics. 31, 17, p. 6408-6414 7 p.

Research output: Contribution to journalArticle

Combining acid-base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase

Camara, J. M. & Rauchfuss, T. B., Jan 2012, In : Nature Chemistry. 4, 1, p. 26-30 5 p.

Research output: Contribution to journalArticle

Connecting [NiFe]- and [FeFe]-hydrogenases: Mixed-valence nickel-iron dithiolates with rotated structures

Schilter, D., Rauchfuss, T. B. & Stein, M., Aug 20 2012, In : Inorganic Chemistry. 51, 16, p. 8931-8941 11 p.

Research output: Contribution to journalArticle

EPR/ENDOR, Mössbauer, and quantum-chemical investigations of diiron complexes mimicking the active oxidized state of [FeFe]hydrogenase

Silakov, A., Olsen, M. T., Sproules, S., Reijerse, E. J., Rauchfuss, T. B. & Lubitz, W., Aug 6 2012, In : Inorganic Chemistry. 51, 15, p. 8617-8628 12 p.

Research output: Contribution to journalArticle

Influence of second coordination sphere hydroxyl groups on the reactivity of copper(I) complexes

Letko, C. S., Rauchfuss, T., Zhou, X. & Gray, D. L., Apr 16 2012, In : Inorganic Chemistry. 51, 8, p. 4511-4520 10 p.

Research output: Contribution to journalArticle

Mixed-valence nickel-iron dithiolate models of the [NiFe]-hydrogenase active site

Schilter, D., Nilges, M. J., Chakrabarti, M., Lindahl, P. A., Rauchfuss, T. B. & Stein, M., Feb 20 2012, In : Inorganic Chemistry. 51, 4, p. 2338-2348 11 p.

Research output: Contribution to journalArticle

Nickel-iron dithiolates related to the deactivated [NiFe]-hydrogenases

Schilter, D. & Rauchfuss, T. B., Nov 21 2012, In : Dalton Transactions. 41, 43, p. 13324-13329 6 p.

Research output: Contribution to journalArticle

Protonation-enhanced Lewis acidity of iridium complexes containing noninnocent amidophenolates

Ringenberg, M. R. & Rauchfuss, T., Jan 1 2012, In : European Journal of Inorganic Chemistry. 3, p. 490-495 6 p.

Research output: Contribution to journalArticle

Reaction of aryl diazonium salts and diiron(I) dithiolato carbonyls: Evidence for radical intermediates

Olsen, M. T., Rauchfuss, T. B. & Zaffaroni, R., Apr 23 2012, In : Organometallics. 31, 8, p. 3447-3450 4 p.

Research output: Contribution to journalArticle

Synthetic models for the active site of the [FeFe]-hydrogenase: Catalytic proton reduction and the structure of the doubly protonated intermediate

Carroll, M. E., Barton, B. E., Rauchfuss, T. B. & Carroll, P. J., Nov 14 2012, In : Journal of the American Chemical Society. 134, 45, p. 18843-18852 10 p.

Research output: Contribution to journalArticle

Terminal vs bridging hydrides of diiron dithiolates: Protonation of Fe 2(dithiolate)(CO)2(PMe3)4

Zaffaroni, R., Rauchfuss, T. B., Gray, D. L., De Gioia, L. & Zampella, G., Nov 21 2012, In : Journal of the American Chemical Society. 134, 46, p. 19260-19269 10 p.

Research output: Contribution to journalArticle

Unsensitized photochemical hydrogen production catalyzed by diiron hydrides

Wang, W., Rauchfuss, T. B., Bertini, L. & Zampella, G., Mar 14 2012, In : Journal of the American Chemical Society. 134, 10, p. 4525-4528 4 p.

Research output: Contribution to journalArticle

2013

And the winner is⋯azadithiolate: An amine proton relay in the [FeFe] hydrogenases

Schilter, D. & Rauchfuss, T. B., Dec 16 2013, In : Angewandte Chemie - International Edition. 52, 51, p. 13518-13520 3 p.

Research output: Contribution to journalArticle

Contrasting protonation behavior of diphosphido vs dithiolato diiron(I) carbonyl complexes

Zaffaroni, R., Rauchfuss, T. B., Fuller, A., De Gioia, L. & Zampella, G., Jan 14 2013, In : Organometallics. 32, 1, p. 232-238 7 p.

Research output: Contribution to journalArticle

Crystallographic characterization of a fully rotated, basic diiron dithiolate: Model for the Hred state?

Wang, W., Rauchfuss, T. B., Moore, C. E., Rheingold, A. L., Degioia, L. & Zampella, G., Nov 11 2013, In : Chemistry - A European Journal. 19, 46, p. 15476-15479 4 p.

Research output: Contribution to journalArticle

Frontiers, opportunities, and challenges in biochemical and chemical catalysis of CO2 fixation

Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., Dubois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., Kerfeld, C. A., Morris, R. H., Peden, C. H. F., Portis, A. R., Ragsdale, S. W., Rauchfuss, T. B., Reek, J. N. H., Seefeldt, L. C., Thauer, R. K. & Waldrop, G. L., Aug 14 2013, In : Chemical reviews. 113, 8, p. 6621-6658 38 p.

Research output: Contribution to journalReview article

Hydrogen activation by biomimetic [NiFe]-hydrogenase model containing protected cyanide cofactors

Manor, B. C. & Rauchfuss, T. B., Aug 14 2013, In : Journal of the American Chemical Society. 135, 32, p. 11895-11900 6 p.

Research output: Contribution to journalArticle

Isolation of a mixed valence diiron hydride: Evidence for a spectator hydride in hydrogen evolution catalysis

Wang, W., Nilges, M. J., Rauchfuss, T. B. & Stein, M., Mar 6 2013, In : Journal of the American Chemical Society. 135, 9, p. 3633-3639 7 p.

Research output: Contribution to journalArticle

Ligand effects on the overpotential for dioxygen reduction by tris(2-pyridylmethyl)amine derivatives

Thorseth, M. A., Letko, C. S., Tse, E. C. M., Rauchfuss, T. B. & Gewirth, A. A., Jan 18 2013, In : Inorganic Chemistry. 52, 2, p. 628-634 7 p.

Research output: Contribution to journalArticle

Observation of the Fe-CN and Fe-CO vibrations in the active site of [NiFe] hydrogenase by nuclear resonance vibrational spectroscopy

Kamali, S., Wang, H., Mitra, D., Ogata, H., Lubitz, W., Manor, B. C., Rauchfuss, T. B., Byrne, D., Bonnefoy, V., Jenney, F. E., Adams, M. W. W., Yoda, Y., Alp, E., Zhao, J. & Cramer, S. P., Jan 7 2013, In : Angewandte Chemie - International Edition. 52, 2, p. 724-728 5 p.

Research output: Contribution to journalArticle

Organo ruthenium-nickel dithiolates with redox-responsive nickel sites

Chambers, G. M., Angamuthu, R., Gray, D. L. & Rauchfuss, T., Nov 11 2013, In : Organometallics. 32, 21, p. 6324-6329 6 p.

Research output: Contribution to journalArticle

Production of hybrid diesel fuel precursors from carbohydrates and petrochemicals using formic acid as a reactive solvent

Zhou, X. & Rauchfuss, T. B., Feb 1 2013, In : ChemSusChem. 6, 2, p. 383-388 6 p.

Research output: Contribution to journalArticle

2014

Borane-protected cyanides as surrogates of h-bonded cyanides in [FeFe]-hydrogenase active site models

Manor, B. C., Ringenberg, M. R. & Rauchfuss, T. B., Jul 21 2014, In : Inorganic Chemistry. 53, 14, p. 7241-7247 7 p.

Research output: Contribution to journalArticle

Computational investigation of [FeFe]-hydrogenase models: Characterization of singly and doubly protonated intermediates and mechanistic insights

Huynh, M. T., Wang, W., Rauchfuss, T. B. & Hammes-Schiffer, S., Oct 6 2014, In : Inorganic Chemistry. 53, 19, p. 10301-10311 11 p.

Research output: Contribution to journalArticle

Diiron azamonothiolates by the scission of dithiadiazacyclooctanes by iron carbonyls

Lin, T., Ulloa, O. A., Rauchfuss, T. B. & Gray, D. L., Sep 1 2014, In : European Journal of Inorganic Chemistry. 2014, 25, p. 4109-4114 6 p.

Research output: Contribution to journalArticle

Electrochemical Synthesis of Tetraethylammonium Tetrathiooxalate

Breitzer, J. G., Holloway, G. A., Rauchfuss, T. B., Salata, M. R., Kee, C. L. & Yan, Y. K., May 12 2014, Inorganic Syntheses. Wiley-Blackwell, Vol. 36. p. 201-203 3 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Ferrous carbonyl dithiolates as precursors to FeFe, FeCo, and FeMn carbonyl dithiolates

Carroll, M. E., Chen, J., Gray, D. E., Lansing, J. C., Rauchfuss, T. B., Schilter, D., Volkers, P. I. & Wilson, S. R., Feb 24 2014, In : Organometallics. 33, 4, p. 858-867 10 p.

Research output: Contribution to journalArticle

Heptacarbonyl(Disulfido)Dimanganese(I)

Adams, R. D., Kwon, O. S., Miao, S., Spahn, C. W. & Rauchfuss, T. B., May 12 2014, Inorganic Syntheses. Wiley-Blackwell, Vol. 36. p. 123-125 3 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Hydrogen production catalyzed by bidirectional, biomimetic models of the [FeFe]-hydrogenase active site

Lansing, J. C., Camara, J. M., Gray, D. E. & Rauchfuss, T. B., Oct 27 2014, In : Organometallics. 33, 20, p. 5897-5906 10 p.

Research output: Contribution to journalArticle

Lignol cleavage by Pd/C under mild conditions and without hydrogen: A role for benzylic C=H activation?

Zhou, X., Mitra, J. & Rauchfuss, T. B., Jun 2014, In : ChemSusChem. 7, 6, p. 1623-1626 4 p.

Research output: Contribution to journalArticle

Multicopper models for the laccase active site: Effect of nuclearity on electrocatalytic oxygen reduction

Tse, E. C. M., Schilter, D., Gray, D. L., Rauchfuss, T. B. & Gewirth, A. A., Aug 18 2014, In : Inorganic Chemistry. 53, 16, p. 8505-8516 12 p.

Research output: Contribution to journalArticle

New reactions of terminal hydrides on a diiron dithiolate

Wang, W., Rauchfuss, T. B., Zhu, L. & Zampella, G., Apr 16 2014, In : Journal of the American Chemical Society. 136, 15, p. 5773-5782 10 p.

Research output: Contribution to journalArticle

NiI/RuII model for the Ni-L state of the [NiFe]hydrogenases: Synthesis, spectroscopy, and reactivity

Chambers, G. M., Mitra, J., Rauchfuss, T. & Stein, M., Apr 21 2014, In : Inorganic Chemistry. 53, 8, p. 4243-4249 7 p.

Research output: Contribution to journalArticle

Protonation of nickel-iron hydrogenase models proceeds after isomerization at nickel

Huynh, M. T., Schilter, D., Hammes-Schiffer, S. & Rauchfuss, T. B., Sep 3 2014, In : Journal of the American Chemical Society. 136, 35, p. 12385-12395 11 p.

Research output: Contribution to journalArticle

Synthesis and vibrational spectroscopy of 57Fe-labeled models of [NiFe] hydrogenase: first direct observation of a nickel–iron interaction

Schilter, D., Pelmenschikov, V., Wang, H., Meier, F., Gee, L. B., Yoda, Y., Kaupp, M., Rauchfuss, T. B. & Cramer, S. P., Oct 9 2014, In : Chemical Communications. 50, 88, p. 13469-13472 4 p.

Research output: Contribution to journalArticle

2015

Cooperative metal-ligand reactivity and catalysis in low-spin ferrous alkoxides

Chu, W. Y., Zhou, X. & Rauchfuss, T., May 11 2015, In : Organometallics. 34, 9, p. 1619-1625 7 p.

Research output: Contribution to journalArticle

Crystal structure of di-μ-hydroxido-κ4O:O-bis-[bis(acetylacetonato-κ2O,O')Cobalt(III)]

Richers, C. P., Bertke, J. A. & Rauchfuss, T. B., Jan 1 2015, In : Acta Crystallographica Section E: Crystallographic Communications. 71, p. 983-985 3 p.

Research output: Contribution to journalArticle

Open Access
Open Access

Hydride bridge in [NiFe]-hydrogenase observed by nuclear resonance vibrational spectroscopy

Ogata, H., Krämer, T., Wang, H., Schilter, D., Pelmenschikov, V., Van Gastel, M., Neese, F., Rauchfuss, T. B., Gee, L. B., Scott, A. D., Yoda, Y., Tanaka, Y., Lubitz, W. & Cramer, S. P., Aug 10 2015, In : Nature communications. 6, 7890.

Research output: Contribution to journalArticle