3D Scaffolded Nickel-Tin Li-Ion Anodes with Enhanced Cyclability

Huigang Zhang; Tan Shi; David J. Wetzel; Ralph G. Nuzzo; Paul V. Braun

doi:10.1002/adma.201504780

3D Scaffolded Nickel-Tin Li-Ion Anodes with Enhanced Cyclability

Huigang Zhang, Tan Shi, David J. Wetzel, Ralph G. Nuzzo, Paul V. Braun

Research output: Contribution to journal › Article › peer-review

Abstract

A 3D mechanically stable scaffold is shown to accommodate the volume change of a high-specific-capacity nickel-tin nanocomposite during operation as a Li-ion battery anode. The nickel-tin anode is supported by an electrochemically inactive conductive scaffold with an engineered free volume and controlled characteristic dimensions, which engender the electrode with significantly improved cyclability.

Original language	English (US)
Pages (from-to)	742-747
Number of pages	6
Journal	Advanced Materials
Volume	28
Issue number	4
DOIs	https://doi.org/10.1002/adma.201504780
State	Published - Jan 27 2016

Keywords

3D scaffolds
anode materials
lithium ion batteries
mesostructures
nickel-tin anodes

ASJC Scopus subject areas

Materials Science(all)
Mechanics of Materials
Mechanical Engineering

Online availability

10.1002/adma.201504780

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abstract = "A 3D mechanically stable scaffold is shown to accommodate the volume change of a high-specific-capacity nickel-tin nanocomposite during operation as a Li-ion battery anode. The nickel-tin anode is supported by an electrochemically inactive conductive scaffold with an engineered free volume and controlled characteristic dimensions, which engender the electrode with significantly improved cyclability.",

keywords = "3D scaffolds, anode materials, lithium ion batteries, mesostructures, nickel-tin anodes",

author = "Huigang Zhang and Tan Shi and Wetzel, {David J.} and Nuzzo, {Ralph G.} and Braun, {Paul V.}",

note = "Funding Information: This work was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering under Award No. DE-FG02-07ER46471, through the Frederick Seitz Materials Research Laboratory at the University of Illinois at Urbana-Champaign. H.Z. acknowledges partial support by the Nanjing University Creation Talent Program (Grant No. 021314310023). Publisher Copyright: {\textcopyright} 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",

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doi = "10.1002/adma.201504780",

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AU - Zhang, Huigang

AU - Shi, Tan

AU - Wetzel, David J.

AU - Nuzzo, Ralph G.

AU - Braun, Paul V.

N1 - Funding Information: This work was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering under Award No. DE-FG02-07ER46471, through the Frederick Seitz Materials Research Laboratory at the University of Illinois at Urbana-Champaign. H.Z. acknowledges partial support by the Nanjing University Creation Talent Program (Grant No. 021314310023). Publisher Copyright: © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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N2 - A 3D mechanically stable scaffold is shown to accommodate the volume change of a high-specific-capacity nickel-tin nanocomposite during operation as a Li-ion battery anode. The nickel-tin anode is supported by an electrochemically inactive conductive scaffold with an engineered free volume and controlled characteristic dimensions, which engender the electrode with significantly improved cyclability.

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3D Scaffolded Nickel-Tin Li-Ion Anodes with Enhanced Cyclability

Abstract

Keywords

ASJC Scopus subject areas

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