2D Kagomé ordering in the 3D frustrated spinel Li2Mn 2O4

C. R. Wiebe, P. L. Russo, A. T. Savici, Y. J. Uemura, G. J. MacDougall, G. M. Luke, S. Kuchta, J. E. Greedan

Research output: Contribution to journalReview article

Abstract

Muon spin relaxation (μSR) experiments on the geometrically frustrated spinel oxide, Li2Mn2O4, show the development of spin correlations over a range of lengthscales with decreasing temperature. Increased relaxation below ∼150 K is consistent with the onset of spin correlations. Below 50 K, spin order, on a lengthscale which is long range for the μSR probe, appears abruptly in temperature, consistent with prior neutron diffraction results. The oscillations in the zero field asymmetry are analysed using a three frequency model. By locating the muon site, this is shown to be consistent with the unexpected 2D structure on the Kagomé planes proposed originally from neutron data. Longitudinal field data demonstrate that some spin dynamics persist even at 2 K. Thus, a very complex magnetic ground state, featuring the coexistence of long lengthscale 2D ordering and significant spin dynamics, is proposed. This is unusual considering the 3D topology of the Mn3+ spins in this material.

Original languageEnglish (US)
Pages (from-to)6469-6482
Number of pages14
JournalJournal of Physics Condensed Matter
Volume17
Issue number41
DOIs
StatePublished - Oct 19 2005
Externally publishedYes

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Spin dynamics
spinel
Neutron diffraction
Oxides
Ground state
Neutrons
Topology
spin dynamics
Temperature
muons
Experiments
neutron diffraction
spinell
topology
asymmetry
neutrons
oscillations
ground state
temperature
oxides

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Wiebe, C. R., Russo, P. L., Savici, A. T., Uemura, Y. J., MacDougall, G. J., Luke, G. M., ... Greedan, J. E. (2005). 2D Kagomé ordering in the 3D frustrated spinel Li2Mn 2O4. Journal of Physics Condensed Matter, 17(41), 6469-6482. https://doi.org/10.1088/0953-8984/17/41/017

2D Kagomé ordering in the 3D frustrated spinel Li2Mn 2O4. / Wiebe, C. R.; Russo, P. L.; Savici, A. T.; Uemura, Y. J.; MacDougall, G. J.; Luke, G. M.; Kuchta, S.; Greedan, J. E.

In: Journal of Physics Condensed Matter, Vol. 17, No. 41, 19.10.2005, p. 6469-6482.

Research output: Contribution to journalReview article

Wiebe, CR, Russo, PL, Savici, AT, Uemura, YJ, MacDougall, GJ, Luke, GM, Kuchta, S & Greedan, JE 2005, '2D Kagomé ordering in the 3D frustrated spinel Li2Mn 2O4', Journal of Physics Condensed Matter, vol. 17, no. 41, pp. 6469-6482. https://doi.org/10.1088/0953-8984/17/41/017
Wiebe, C. R. ; Russo, P. L. ; Savici, A. T. ; Uemura, Y. J. ; MacDougall, G. J. ; Luke, G. M. ; Kuchta, S. ; Greedan, J. E. / 2D Kagomé ordering in the 3D frustrated spinel Li2Mn 2O4. In: Journal of Physics Condensed Matter. 2005 ; Vol. 17, No. 41. pp. 6469-6482.
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abstract = "Muon spin relaxation (μSR) experiments on the geometrically frustrated spinel oxide, Li2Mn2O4, show the development of spin correlations over a range of lengthscales with decreasing temperature. Increased relaxation below ∼150 K is consistent with the onset of spin correlations. Below 50 K, spin order, on a lengthscale which is long range for the μSR probe, appears abruptly in temperature, consistent with prior neutron diffraction results. The oscillations in the zero field asymmetry are analysed using a three frequency model. By locating the muon site, this is shown to be consistent with the unexpected 2D structure on the Kagom{\'e} planes proposed originally from neutron data. Longitudinal field data demonstrate that some spin dynamics persist even at 2 K. Thus, a very complex magnetic ground state, featuring the coexistence of long lengthscale 2D ordering and significant spin dynamics, is proposed. This is unusual considering the 3D topology of the Mn3+ spins in this material.",
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AU - Wiebe, C. R.

AU - Russo, P. L.

AU - Savici, A. T.

AU - Uemura, Y. J.

AU - MacDougall, G. J.

AU - Luke, G. M.

AU - Kuchta, S.

AU - Greedan, J. E.

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N2 - Muon spin relaxation (μSR) experiments on the geometrically frustrated spinel oxide, Li2Mn2O4, show the development of spin correlations over a range of lengthscales with decreasing temperature. Increased relaxation below ∼150 K is consistent with the onset of spin correlations. Below 50 K, spin order, on a lengthscale which is long range for the μSR probe, appears abruptly in temperature, consistent with prior neutron diffraction results. The oscillations in the zero field asymmetry are analysed using a three frequency model. By locating the muon site, this is shown to be consistent with the unexpected 2D structure on the Kagomé planes proposed originally from neutron data. Longitudinal field data demonstrate that some spin dynamics persist even at 2 K. Thus, a very complex magnetic ground state, featuring the coexistence of long lengthscale 2D ordering and significant spin dynamics, is proposed. This is unusual considering the 3D topology of the Mn3+ spins in this material.

AB - Muon spin relaxation (μSR) experiments on the geometrically frustrated spinel oxide, Li2Mn2O4, show the development of spin correlations over a range of lengthscales with decreasing temperature. Increased relaxation below ∼150 K is consistent with the onset of spin correlations. Below 50 K, spin order, on a lengthscale which is long range for the μSR probe, appears abruptly in temperature, consistent with prior neutron diffraction results. The oscillations in the zero field asymmetry are analysed using a three frequency model. By locating the muon site, this is shown to be consistent with the unexpected 2D structure on the Kagomé planes proposed originally from neutron data. Longitudinal field data demonstrate that some spin dynamics persist even at 2 K. Thus, a very complex magnetic ground state, featuring the coexistence of long lengthscale 2D ordering and significant spin dynamics, is proposed. This is unusual considering the 3D topology of the Mn3+ spins in this material.

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