Scott E Denmark

1991

Configuration, Conformation, and Colligative Properties of a Phosphorus-Stabilized Anion

Denmark, S. E., Miller, P. C. & Wilson, S. R., 1991, In: Journal of the American Chemical Society. 113, 4, p. 1468-1470 3 p.

Research output: Contribution to journal › Article › peer-review

Investigations on Transition-State Geometry in the Aldol Condensation

Denmark, S. E. & Henke, B. R., 1991, In: Journal of the American Chemical Society. 113, 6, p. 2177-2194 18 p.

Research output: Contribution to journal › Article › peer-review

On the Generation and Configurational Stability of (2S,3S)-1,2,3-TriphenyIborirane

Denmark, S. E., Nishide, K. & Faucher, A. M., Aug 1 1991, In: Journal of the American Chemical Society. 113, 17, p. 6675-6676 2 p.

Research output: Contribution to journal › Article › peer-review

On the Stereoselective Opening of Achiral Dioxane Acetals

Denmark, S. E. & Almstead, N. G., Oct 1 1991, In: Journal of Organic Chemistry. 56, 22, p. 6458-6467 10 p.

Research output: Contribution to journal › Article › peer-review

On the Stereoselective Opening of Chiral Dioxane Acetals. Nucleophile Dependence

Denmark, S. E. & Almstead, N. G., Nov 1 1991, In: Journal of Organic Chemistry. 56, 23, p. 6485-6487 3 p.

Research output: Contribution to journal › Article › peer-review

Solution and Solid-State Structure of the “Wittig-Furukawa” Cyclopropanation Reagent

Denmark, S. E., Edwards, J. P. & Wilson, S. R., Jan 1 1991, In: Journal of the American Chemical Society. 113, 2, p. 723-725 3 p.

Research output: Contribution to journal › Article › peer-review

Studies on the Mechanism and Origin of Stereoselective Opening of Chiral Dioxane Acetals

Denmark, S. E. & Almstead, N. G., Oct 1 1991, In: Journal of the American Chemical Society. 113, 21, p. 8089-8110 22 p.

Research output: Contribution to journal › Article › peer-review

Synthesis of α- and β-branched ethers from alcohols by reaction of acetals with Grignard reagents: Synthesis of isopropyl and isobutyl ethers of (1S,2RS,4R)-6-methylenebicyclo[2.2.2]octan-2-ol

Willson, T. M., Amburgey, J. & Denmark, S. E., 1991, In: Journal of the Chemical Society, Perkin Transactions 1. 12, p. 2899-2906 8 p.

Research output: Contribution to journal › Article › peer-review

Tandem Inter [4 + 2]/Intra [3 + 2] Cycloadditions. 3. The Stereochemical Influence of the Lewis Acid

Denmark, S. E. & Schnute, M. E., Nov 1 1991, In: Journal of Organic Chemistry. 56, 24, p. 6738-6739 2 p.

Research output: Contribution to journal › Article › peer-review

1990

Auxiliary-Based, Asymmetric SN2' Reactions: A Case of 1,7-Relative Stereogenesis

Denmark, S. E. & Marble, L. K., 1990, In: Journal of Organic Chemistry. 55, 7, p. 1984-1986 3 p.

Research output: Contribution to journal › Article › peer-review

Intramolecular [4+2]-cycloadditions of nitroalkenes with olefins. 2

Denmark, S. E., Moon, Y. C., Cramer, C. J., Dappen, M. S. & Senanayake, C. B. W., 1990, In: Tetrahedron. 46, 21, p. 7373-7392 20 p.

Research output: Contribution to journal › Article › peer-review

Lithium/Ammonia Cleavage of the N-N Bond in N-(MethoxycarbonyI)- and N-Acetylhydrazines

Denmark, S. E., Nicaise, O. & Edwards, J. P., Dec 1990, In: Journal of Organic Chemistry. 55, 25, p. 6219-6223 5 p.

Research output: Contribution to journal › Article › peer-review

Silicon-directed Nazarov cyclizations. 8. Stereoelectronic control of torquoselectivity

Denmark, S. E., Wallace, M. A. & Walker, C. B., 1990, In: Journal of Organic Chemistry. 55, 21, p. 5543-5545 3 p.

Research output: Contribution to journal › Article › peer-review

Solution and Solid-State Structure of a Phosphorus-Stabilized Carbanion

Denmark, S. E. & Dorow, R. L., Jan 1 1990, In: Journal of the American Chemical Society. 112, 2, p. 864-866 3 p.

Research output: Contribution to journal › Article › peer-review

Stereoselective Alkylations of Chiral, Phosphorus-Stabilized Benzylic Carbanions

Denmark, S. E. & Dorow, R. L., Nov 1990, In: Journal of Organic Chemistry. 55, 24, p. 5926-5928 3 p.

Research output: Contribution to journal › Article › peer-review

Synthesis, structure, and reactivity of an organogermanium lewis acid

Denmark, S. E., Jacobs, R. T., Dai-Ho, G. & Wilson, S., 1990, In: Organometallics. 9, 12, p. 3015-3019 5 p.

Research output: Contribution to journal › Article › peer-review

Tandem [4 + 2]/[3 + 2] Cycloadditions: Facile and Stereoselective Construction of Polycyclic Frameworks

Denmark, S. E., Moon, Y. C. & Senanayake, C. B. W., 1990, In: Journal of the American Chemical Society. 112, 1, p. 311-315 5 p.

Research output: Contribution to journal › Article › peer-review

Tandem [4+2]/[3+2]-cycloadditions. 2. Asymmetric induction with a chiral vinyl ether

Denmark, S. E., Senanayake, C. B. W. & Ginny-Dai, H., 1990, In: Tetrahedron. 46, 13-14, p. 4857-4876 20 p.

Research output: Contribution to journal › Article › peer-review

The Theoretical Structures of Neutral, Anionic, and Lithiated P-Allylphosphonic Diamide

Denmark, S. E. & Cramer, C. J., 1990, In: Journal of Organic Chemistry. 55, 6, p. 1806-1813 8 p.

Research output: Contribution to journal › Article › peer-review

The Vinylogous Anomeric Effect in 3-Alkyl-2-chlorocyclohexanone Oximes and Oxime Ethers

Denmark, S. E., Dappen, M. S., Sear, N. L. & Jacobs, R. T., Jan 1990, In: Journal of the American Chemical Society. 112, 9, p. 3466-3474 9 p.

Research output: Contribution to journal › Article › peer-review

1989

Carbanion-Accelerated Claisen Rearrangements. 6. Preparative and Stereochemical Studies with Sulfonyl-Stabilized Anions

Denmark, S. E., White, K. S. & Harmata, M. A., Nov 1 1989, In: Journal of the American Chemical Society. 111, 24, p. 8878-8891 14 p.

Research output: Contribution to journal › Article › peer-review

Carbanion-accelerated Claisen rearrangements 5. Studies on stereocontrol with phosphorus-stabilized anions

Denmark, S. E., Rajendra, G. & Marlin, J. E., 1989, In: Tetrahedron Letters. 30, 19, p. 2469-2472 4 p.

Research output: Contribution to journal › Article › peer-review

Investigations on Transition-State Geometry in the Aldol Condensation

Denmark, S. E. & Henke, B. R., Sep 1 1989, In: Journal of the American Chemical Society. 111, 20, p. 8032-8034 3 p.

Research output: Contribution to journal › Article › peer-review

Mechanistic and Stereochemical Divergence in the Allylsilane-Acetal Addition Reaction

Denmark, S. E. & Willson, T. M., Apr 1989, In: Journal of the American Chemical Society. 111, 9, p. 3475-3476 2 p.

Research output: Contribution to journal › Article › peer-review

Modified proline auxiliaries for selective addition of organocerium reagents to hydrazones

Weber, T., Edwards, J. P. & Denmark, S. E., Sep 1989, In: Synlett. 1989, 1, p. 20-22 3 p.

Research output: Contribution to journal › Article › peer-review

Stereochemical and spectroscopic studies on the reaction of allylstannanes with aldehydes

Denmark, S. E., Weber, E. J., Wilson, T. M. & Willson, T. M., 1989, In: Tetrahedron. 45, 4, p. 1053-1065 13 p.

Research output: Contribution to journal › Article › peer-review

The Origin of Stereoselective Opening of Chiral Dioxane and Dioxolane Acetals: Solution Structure of Their Lewis Acid Complexes⁺

Denmark, S. E., Willson, T. M. & Almstead, N. G., Dec 1989, In: Journal of the American Chemical Society. 111, 26, p. 9258-9260 3 p.

Research output: Contribution to journal › Article › peer-review

1988

On the lewis acid induced addition of allylstannanes to aldehydes: A spectroscopic investigation

Denmark, S. E., Wilson, T. & Willson, T. M., Feb 1988, In: Journal of the American Chemical Society. 110, 3, p. 984-986 3 p.

Research output: Contribution to journal › Article › peer-review

Silicon‐Directed Nazarov Cyclizations. Part V. Substituent and heteroatom effects on the reaction

Denmark, S. E., Habermas, K. L. & Hite, G. A., Feb 3 1988, In: Helvetica Chimica Acta. 71, 1, p. 168-194 27 p.

Research output: Contribution to journal › Article › peer-review

Silicon‐Directed Nazarov Cyclizations. Part VI. The anomalous cyclization of vinyl dienyl ketones

Denmark, S. E. & Hite, G. A., Feb 3 1988, In: Helvetica Chimica Acta. 71, 1, p. 195-208 14 p.

Research output: Contribution to journal › Article › peer-review

Silicon-directed nazarov cyclizations VII. Linearly-fused tricyclics

Denmark, S. E. & Klix, R. C., 1988, In: Tetrahedron. 44, 13, p. 4043-4060 18 p.

Research output: Contribution to journal › Article › peer-review

Stereoselective alkylation of chiral α-nitro keto imine dianions. Observations on the role of amide bases

Denmark, S. E. & Ares, J. J., Jun 1988, In: Journal of the American Chemical Society. 110, 13, p. 4432-4434 3 p.

Research output: Contribution to journal › Article › peer-review

α-Nitro Keto Hydrazone and Keto Imine Dianions. Synthetic Equivalents for the Nitroalkene d³ Synthon

Denmark, S. E., Sternberg, J. A. & Lueoend, R., Mar 1 1988, In: Journal of Organic Chemistry. 53, 6, p. 1251-1263 13 p.

Research output: Contribution to journal › Article › peer-review

1987

An AB initio study of the [1,2] proton transfer from phosphine oxide to phosphinic acid

Cramer, C. J., Dykstra, C. E. & Denmark, S. E., Apr 24 1987, In: Chemical Physics Letters. 136, 1, p. 17-21 5 p.

Research output: Contribution to journal › Article › peer-review

Diphenylmethylsilyl Ether (DPMS): A Protecting Group for Alcohols

Denmark, S. E., Hammer, R. P., Weber, E. J. & Habermas, K. L., Jan 1 1987, In: Journal of Organic Chemistry. 52, 1, p. 165-168 4 p.

Research output: Contribution to journal › Article › peer-review

Intramolecular [4 + 2]-Cycloadditions of Vinylnitrosonium Cations with Olefins

Denmark, S. E., Cramer, C. J. & Dappen, M. S., Mar 1 1987, In: Journal of Organic Chemistry. 52, 5, p. 877-887 11 p.

Research output: Contribution to journal › Article › peer-review

Organocerium Additions to SAMP-Hydrazones: General Synthesis of Chiral Amines

Denmark, S. E., Weber, T. & Piotrowski, D. W., Apr 1 1987, In: Journal of the American Chemical Society. 109, 7, p. 2224-2225 2 p.

Research output: Contribution to journal › Article › peer-review

SnCl₄(4-t-BuC₆H₄CHO)₂. X-ray Crystal Structure, Solution NMR, and Implications for Reactions at Complexed Carbonyls^1a

Denmark, S. E., Henke, B. R. & Weber, E., Apr 1 1987, In: Journal of the American Chemical Society. 109, 8, p. 2512-2514 3 p.

Research output: Contribution to journal › Article › peer-review

Studies on the Addition of Allyl Oxides to Sulfonylallenes. Preparation of Highly Substituted Allyl Vinyl Ethers for Carbanionic Claisen Rearrangements.

Denmark, S. E., Harmata, M. A. & White, K. S., Sep 1 1987, In: Journal of Organic Chemistry. 52, 18, p. 4031-4042 12 p.

Research output: Contribution to journal › Article › peer-review

1986

Intermolecular [4 + 2]‐Cycloadditions of Nitroalkenes with Cyclic Olefins. Transformations of Cyclic Nitronates

Denmark, S. E., Cramer, C. J. & Sternberg, J. A., Dec 10 1986, In: Helvetica Chimica Acta. 69, 8, p. 1971-1989 19 p.

Research output: Contribution to journal › Article › peer-review

Intramolecular [4 + 2] Cycloadditions of (Z)-α,β-Unsaturated Aldehydes with Vinyl Sulfides and Ketene Dithioacetals

Denmark, S. E. & Sternberg, J. A., 1986, In: Journal of the American Chemical Society. 108, 26, p. 8277-8279 3 p.

Research output: Contribution to journal › Article › peer-review

Intramolecular [4 + 2] Cycloadditions of Nitroalkenes with Olefins

Denmark, S. E., Dappen, M. S. & Cramer, C. J., 1986, In: Journal of the American Chemical Society. 108, 6, p. 1306-1307 2 p.

Research output: Contribution to journal › Article › peer-review

Silicon-directed nazarov cyclizations-IV. Further studies in stereochemical control

Denmark, S. E., Habermas, K. L., Hite, G. A. & Jones, T. K., 1986, In: Tetrahedron. 42, 11, p. 2821-2829 9 p.

Research output: Contribution to journal › Article › peer-review

The stereostructures of [1,1′-bicyclohexyl]-2,2′-diones: A reassignment

Denmark, S. E., Cramer, C. J. & Sternberg, J. A., 1986, In: Tetrahedron Letters. 27, 32, p. 3693-3696 4 p.

Research output: Contribution to journal › Article › peer-review

1985

A General Method for the Preparation of 7-Substituted Cyclohexenals and Cycloheptenals

Jones, T. K. & Denmark, S. E., Oct 1985, In: Journal of Organic Chemistry. 50, 21, p. 4037-4045 9 p.

Research output: Contribution to journal › Article › peer-review

1984

A vinylsilane route to trans-7a-methylhydrind-4-en-1,6-dione

Denmark, S. E. & Germanas, J. P., 1984, In: Tetrahedron Letters. 25, 12, p. 1231-1234 4 p.

Research output: Contribution to journal › Article › peer-review

Carbanion-accelerated Claisen rearrangements 3. Vicinal quaternary centers

Denmark, S. E. & Harmata, M. A., 1984, In: Tetrahedron Letters. 25, 15, p. 1543-1546 4 p.

Research output: Contribution to journal › Article › peer-review

Intramolecular [4 + 2] Cycloadditions of Nitrosoalkenes with Olefins

Denmark, S. E., Dappen, M. S. & Sternberg, J. A., Jun 1984, In: Journal of Organic Chemistry. 49, 24, p. 4741-4743 3 p.

Research output: Contribution to journal › Article › peer-review

Stereochemistry of Allylmetal-Aldehyde Condensations. 2. Allylstannanes

Denmark, S. E. & Weber, E. J., Dec 1 1984, In: Journal of the American Chemical Society. 106, 25, p. 7970-7971 2 p.

Research output: Contribution to journal › Article › peer-review

α-chloro ketoximes as precursors of nitrosoalkenes: Preparation, stereochemistry and conformation

Denmark, S. E. & Dappen, M. S., Dec 1984, In: Journal of Organic Chemistry. 49, 5, p. 798-806 9 p.

Research output: Contribution to journal › Article › peer-review

Scott E Denmark

Research output

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