Scott E Denmark

1975 …2019
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Research Output 1975 2019

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2016

Bifunctional and Synergistic Catalysis: Lewis Acid Catalysis and Lewis Base-Assisted Bond Polarization (n → σ*)

Chung, W. J. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1213-1258 46 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Lewis Acids
Catalysis
Polarization
Chemical activation

Bifunctional Lewis Base Catalysis With Dual Activation of X3Si Nu and C=O(n → σ*)

Fu, J., Fujimori, S. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 1. p. 281-338 58 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Catalysis
Chemical activation
Phosphoramides
Catalysts

Lewis Base Catalysis: A Platform for Enantioselective Addition to Alkenes Using Group 16 and 17 Lewis Acids (n → σ*)

Kalyani, D., Kornfilt, D. J. P., Burk, M. T. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1153-1211 59 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Lewis Acids
Alkenes
Catalysis
Nucleophiles

Lewis Base-Catalyzed, Lewis Acid-Mediated Reactions (n → σ*)

Rossi, S. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1039-1076 38 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Lewis Acids
Silicon
Phosphoramides
Methyl Ethers

Principles, Definitions, Terminology, and Orbital Analysis of Lewis Base-Lewis Acid Interactions Leading to Catalysis

Denmark, S. E. & Beutner, G. L., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 1. p. 33-54 22 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Lewis Acids
Terminology
Catalysis
Quantum theory

Reactions of epoxides (n → σ*)

Wilson, T. W. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1113-1151 39 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Epoxy Compounds
Lewis Acids
Lewis Bases
Chemical activation
Reaction kinetics

Summation

Vedejs, E. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1351-1353 3 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Speech synthesis
2014

Tandem [4+2]/[3+2] Cycloadditions

Baiazitov, R. Y. & Denmark, S. E., Feb 10 2014, Methods and Applications of Cycloaddition Reactions in Organic Syntheses. Wiley Blackwell, Vol. 9781118299883. p. 471-550 80 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Cycloaddition
Biological Products
Molecules
2013

Organosilicon Compounds in Cross-Coupling Reactions

Denmark, S. E. & Sweis, R. F., Nov 30 2013, Metal Catalyzed Cross-Coupling Reactions and More. Wiley-VCH Verlag, Vol. 3. p. 475-532 58 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Fluorine compounds
Silicon compounds

The interplay of invention, observation, and discovery in the development of lewis base activation of lewis acids for catalytic enantioselective synthesis

Beutner, G. L. & Denmark, S. E., Jan 1 2013, Inventing Reactions. Goossen, L. (ed.). p. 55-89 35 p. (Topics in Organometallic Chemistry; vol. 44).

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Lewis Acids
Patents and inventions
Esters
Nucleophiles
2012

Total synthesis of papulacandin D

Kobayashi, T., Regens, C. S. & Denmark, S. E., 2012, Strategies and Tactics in Organic Synthesis. Academic Press Inc., p. 79-126 48 p. (Strategies and Tactics in Organic Synthesis; vol. 8).

Research output: Chapter in Book/Report/Conference proceedingChapter

Palladium
Biological Products
papulacandins
2008

(R)-2,2’-Binaphthoyl-(S,S)-di(1-phenylethyl) aminophosphine. Scalable protocols for the syntheses of phosphoramidite (feringa) ligands

Smith, C. R., Mans, D. J., RajanBabu, T. V., Denmark, S. E. & Nguyen, T., Jan 1 2008, Organic Syntheses. Wiley Blackwell, p. 238-247 10 p. (Organic Syntheses; vol. 85).

Research output: Chapter in Book/Report/Conference proceedingChapter

ligands
synthesis

(R)-2-(benzyloxycarbonylamino-methyl)-3-phenylpropanoic acid (Z-2hPHE-OH): Preparation of A 2-amino acid with the auxiliary dioz

Müller-Hartwieg, J. C. D., Vecchia, L. L., Meyer, H., Beck, A. K., Seebach, D., Denmark, S. E., Duncan-Gould, N. & Hoover, A., Jan 1 2008, Organic Syntheses. Wiley Blackwell, p. 295-306 12 p. (Organic Syntheses; vol. 85).

Research output: Chapter in Book/Report/Conference proceedingChapter

Amino Acids
3-phenylpropionic acid

(S)-5-Pyrrolidin-2-yl-1H-tetrazole

Aureggi, V., Franckeviius, V., Kitching, M. O., Ley, S. V., Longbottom, D. A., Oelke, A. J., Sedelmeier, G., Denmark, S. E. & Smith, R. C., Jan 1 2008, Organic Syntheses. Wiley Blackwell, p. 72-87 16 p. (Organic Syntheses; vol. 85).

Research output: Chapter in Book/Report/Conference proceedingChapter

tetrazoles

Benzyl isopropoxymethyl carbamate - An aminomethylating reagent for mannich reactions of titanium enolates

Meyer, H., Beck, A. K., Sebesta, R., Seebach, D., Denmark, S. E. & Wilson, T. W., Jan 1 2008, Organic Syntheses. Wiley Blackwell, p. 287-294 8 p. (Organic Syntheses; vol. 85).

Research output: Chapter in Book/Report/Conference proceedingChapter

reagents
titanium

Synthesis and resolution of racemic trans-2-(N-benzyl)amino-1-cyclohexanol: Enantiomer separation by sequential use of (R)- and (S)-Mandelic acid: [cyclohexanol, 2-(N-benzyl)amino, (1S,2S)- and (1R,2R)-]

Schiffers, I., Bolm, C., Denmark, S. E., Woerly, E., Toussaint, A. & Pfaltz, A., Jan 1 2008, Organic Syntheses. Wiley Blackwell, p. 106-117 12 p. (Organic Syntheses; vol. 85).

Research output: Chapter in Book/Report/Conference proceedingChapter

enantiomers
acids
synthesis

Synthesis of 2-substituted biaryls via Cu/Pd-catalyzed decarboxylative cross-coupling of 2-substituted potassium benzoates: 4-Methyl-2'-nitrobiphenyl and 2-acetyl-4'-methylbiphenyl: [Biphenyl, 4-Methyl-2’-nitro-] [Biphenyl, 4-Methyl-2’-acetyl-]

Gooßen, L. J., Rodríguez, N., Linder, C., Zimmermann, B., Knauber, T., Denmark, S. E. & Werner, N. S., Jan 1 2008, Organic Syntheses. Wiley Blackwell, p. 196-208 13 p. (Organic Syntheses; vol. 85).

Research output: Chapter in Book/Report/Conference proceedingChapter

cross coupling
potassium
synthesis
2007

1-(4-acetylphenyl)-2-phenylethane from potassium 2-phenethyltrifluoroborate and 4-bromoacetophenone

Molander, G. A., Petrillo, D. E., Denmark, S. E. & Eggertswyler, C., Jan 1 2007, Organic Syntheses. Wiley Blackwell, p. 317-324 8 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

potassium
Potassium
4-bromoacetophenone

Generation of ynolate and Z-selective olefination of acylsilanes: (Z)-2-methyl-3-trimethylsilyl-2-butenoic acid: ((Z)-2-butenoic acid, 2-methyl-3-trimethylsilyl-)

Shindo, M., Matsumoto, K., Shishido, K., Denmark, S. E. & Eklov, B. M., Jan 1 2007, Organic Syntheses. Wiley Blackwell, p. 11-21 11 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

One-flask synthesis of methyl arylvinyldiazoacetates and their application in enantioselective C–H functionalization: synthesis of (E)-methyl 2-diazo-4-phenylbut-3-enoate and (S,E)methyl 2-((R)-4-methyl-1,2-dihydronaphthalen-2-YL)-4-phenylbut-3-enoate

Manning, J. R., Davies, H. M. L., Denmark, S. E. & Collins, W. R., 2007, Organic Syntheses. Wiley Blackwell, Vol. 84. p. 334-346 13 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

flasks
synthesis
diazo-4

Preparation of a carbazole-based macrocycle via precipitation-driven alkyne metathesis

Zhang, W., Cho, H. M., Moore, J. S., Denmark, S. E. & Butler, C. R., Jan 1 2007, Organic Syntheses. Wiley Blackwell, p. 177-191 15 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

carbazoles
metathesis
alkynes
preparation

Synthesis of acylsilanes from morpholine amides. Synthesis of 1-(dimethyl(phenyl)silyl)propan-1-one [dimethyl(1-oxopropyl)phenylsilane]

Lettan, R. B., Milgram, B. C., Scheidt, K. A., Denmark, S. E. & Baiazitov, R. Y., Jan 1 2007, Organic Syntheses. Wiley Blackwell, p. 22-31 10 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

Amides
morpholine

Synthesis of electron-deficient secondary phosphine oxides and secondary phosphines: Bis[3,5bis(trifluoromethyl)phenyl]phosphine oxide and bis[3,5-bis(trifluoromethyl)phenyl]phosphine

Busacca, C. A., Lorenz, J. C., Sabila, P., Haddad, N., Senandyake, C. H., Denmark, S. E. & Regens, C. S., Jan 1 2007, Organic Syntheses. Wiley Blackwell, p. 242-261 20 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

phosphine
Phosphines
phosphines
Oxides
oxides

Synthesis of terminal 1,3-diynes via sonogashira coupling of vinylidene chloride followed by elimination. preparation of 1,3-decadiyne

Kohnen, A. L., Danheiser, R. L., Denmark, S. E. & Liu, X., Jan 1 2007, Organic Syntheses. Wiley Blackwell, p. 77-87 11 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

vinylidene
elimination
chlorides
preparation
synthesis

Synthesis of ynamides by N-alkynylation of amine derivatives. Preparation of N-allyl-N-(methoxycarbonyl)-1,3-decadiynylamine

Kohnen, A. L., Dunetz, J. R., Danheiser, R. L., Denmark, S. E. & Liu, X., Jan 1 2007, Organic Syntheses. Wiley Blackwell, p. 88-101 14 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

amines
preparation
synthesis