Scott E Denmark

1975 …2019
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Research Output 1975 2019

2003
Hydrosilylation
cross coupling
Cross Reactions
Iodides
Silicon

Lewis base activation of lewis acids. Catalytic enantioselective addition of silyl enol ethers of achiral methyl ketones to aldehydes

Denmark, S. E. & Heemstra, J. R., Jun 26 2003, In : Organic Letters. 5, 13, p. 2303-2306 4 p.

Research output: Contribution to journalArticle

Lewis Bases
Methyl Ethers
Lewis Acids
Lewis base
Ethers

Lewis base activation of Lewis acids. Vinylogous aldol reactions

Denmark, S. E. & Beutner, G. L., Jul 2 2003, In : Journal of the American Chemical Society. 125, 26, p. 7800-7801 2 p.

Research output: Contribution to journalArticle

Lewis Bases
Lewis Acids
Ethers
ether
Chemical activation

Organosilicon Reagents: Synthesis and Application to Palladium-Catalyzed Cross-Coupling Reactions

Denmark, S. E. & Ober, M. H., Dec 1 2003, In : Aldrichimica Acta. 36, 3, p. 75-85 11 p.

Research output: Contribution to journalReview article

Palladium

Palladium-catalyzed conjugate addition of organosiloxanes to α,β-unsaturated carbonyl compounds and nitroalkenes

Denmark, S. E. & Amishiro, N., Sep 5 2003, In : Journal of Organic Chemistry. 68, 18, p. 6997-7003 7 p.

Research output: Contribution to journalArticle

Silicon Compounds
Carbonyl compounds
Palladium
Ketones
Aldehydes

Palladium-Catalyzed Silylation of Aryl Bromides Leading to Functionalized Aryldimethylsilanols

Denmark, S. E. & Kallemeyn, J. M., Sep 18 2003, In : Organic Letters. 5, 19, p. 3483-3486 4 p.

Research output: Contribution to journalArticle

Ethers
Palladium
Bromides
palladium
bromides

Preparation of 2-chloro-1,3 bis(dimethylamino) trimethinium hexafluorophosphate [[methanaminium, N-[2-chloro-3-(dimethylamino)-2-propenylidene]-N-methyl-, hexafluorophosphate(1-)]]

Davies, I. W., Marcoux, J. F., Taylor, J., Fan, Y. & Denmark, S. E., Jan 1 2003, In : Organic Syntheses. 80, p. 200-206 7 p.

Research output: Contribution to journalArticle

preparation

Stereoselective aldol additions of achiral ethyl ketone-derived trichlorosilyl enolates

Denmark, S. E. & Pham, S. M., Jun 27 2003, In : Journal of Organic Chemistry. 68, 13, p. 5045-5055 11 p.

Research output: Contribution to journalArticle

Ketones
Aldehydes
Phosphoramides
Stereoselectivity
Enantioselectivity

Tandem double intramolecular [4+2]/[3+2] cycloadditions of nitroalkenes. The fused/bridged mode

Denmark, S. E. & Gomez, L., Oct 17 2003, In : Journal of Organic Chemistry. 68, 21, p. 8015-8024 10 p.

Research output: Contribution to journalArticle

Cycloaddition
Bearings (structural)
Polyenes
Ethers
Silicon
Aldehydes
Palladium
Copper
Lewis Bases
Cyanides
aldehyde
Aldehydes
Enantioselectivity

Topics in stereochemistry. Vol. 23

Denmark, S. E., 2003, Hoboken: Wiley-Interscience.

Research output: Book/ReportBook

Transformation of primary amines to N-monoalkylhydroxylamines: N-hydroxy-(S)-1-phenylethylamine oxalate: [(Benzenemethanamine, N-hydroxy--methyl-, (S)-, ethanedioate)]

Tokuyama, H., Kuboyama, T., Fukuyama, T., Denmark, S. E. & Cottell, J. J., Jan 1 2003, In : Organic Syntheses. 80, p. 207-218 12 p.

Research output: Contribution to journalArticle

Phenethylamines
Oxalates
Amines
2002
LY 426965
Allylation
serotonin
Serotonin Antagonists
Enantioselectivity

Catalytic, enantioselective aldol additions to ketones

Denmark, S. E. & Fan, Y., Apr 24 2002, In : Journal of the American Chemical Society. 124, 16, p. 4233-4235 3 p.

Research output: Contribution to journalArticle

ketone
Ketones
oxide
Stereoselectivity
Acetals

Catalytic enantioselective addition of dialkylzincs to aldehydes using (2S)-(-)-3-exo-(dimethylamino)isoborneol [(2S)-daib]: (S)-1-phenyl-1-propanol: [Benzenemethanol, α-ethyl-, (S)-]

Kitamura, M., Oka, H., Suga, S., Noyori, R., Kaelin, D. E., Martin, S. F., Beutner, G. L. & Denmark, S. E., Jan 1 2002, In : Organic Syntheses. 79, 1 p.

Research output: Contribution to journalArticle

Benzyl Alcohol
Aldehydes
alpha-ethylbenzyl alcohol
isoborneol

Chiral fluoro ketones for catalytic asymmetric epoxidation of alkenes with oxone

Denmark, S. E. & Matsuhashi, H., May 17 2002, In : Journal of Organic Chemistry. 67, 10, p. 3479-3486 8 p.

Research output: Contribution to journalArticle

Epoxidation
Alkenes
Ketones
Enantioselectivity
Catalysts

Cross-coupling reactions of alkenylsilanols with fluoroalkylsulfonates

Denmark, S. E. & Sweis, R. F., Oct 17 2002, In : Organic Letters. 4, 21, p. 3771-3774 4 p.

Research output: Contribution to journalArticle

cross coupling
Cross Reactions
Fluorides
fluorides
reactivity

Cross-coupling reactions of organosilicon compounds: New concepts and recent advances

Denmark, S. E. & Sweis, R. F., Dec 1 2002, In : Chemical and Pharmaceutical Bulletin. 50, 12, p. 1531-1541 11 p.

Research output: Contribution to journalReview article

Organosilicon Compounds
Cross Reactions
Silicon
Siloxanes
Ethers

Design and implementation of new, silicon-based, cross-coupling reactions: Importance of silicon-oxygen bonds

Denmark, S. E. & Sweis, R. F., Oct 1 2002, In : Accounts of chemical research. 35, 10, p. 835-846 12 p.

Research output: Contribution to journalArticle

Silicon
Oxygen
Palladium
Fluorides
Chemical activation

Diastereoselective aldol additions of chiral β-hydroxy ethyl ketone enolates catalyzed by Lewis bases

Denmark, S. E. & Fujimori, S., Oct 3 2002, In : Organic Letters. 4, 20, p. 3473-3476 4 p.

Research output: Contribution to journalArticle

Lewis Bases
Lewis base
Ketones
aldehydes
ketones

Efficient and stereoselective cross-coupling with highly substituted alkenylsilanols

Denmark, S. E. & Pan, W., Jul 1 2002, In : Journal of Organometallic Chemistry. 653, 1-2, p. 98-104 7 p.

Research output: Contribution to journalArticle

cross coupling
Palladium
Functional groups
halides
fluorides

Formation of γ-keto esters from β-keto esters: Methyl 5,5-dimethyl-4-oxohexanoate: [Hexanoic acid, 5,5-dimethyl-4-oxo-, methyl ester]

Ronsheim, M. D., Hilgenkamp, R. K., Zercher, C. K., Denmark, S. E. & Beutner, G. L., Jan 1 2002, In : Organic Syntheses. 79, 1 p.

Research output: Contribution to journalArticle

esters
Esters
acids
hexanoic acid

Inter- and intramolecular [4+2] cycloaddition of nitroalkenes with allenylsilanes. A case of unexpected regioselectivity

Denmark, S. E. & Gomez, L., Nov 22 2002, In : Heterocycles. 58, p. 129-136 8 p.

Research output: Contribution to journalArticle

Regioselectivity
Acetals
Cycloaddition
Cycloaddition Reaction
Carbon
Hydrosilylation
cross coupling
Silicon
alcohols
Alcohols

Intramolecular silicon-assisted cross-coupling: Total synthesis of (+)-brasilenyne

Denmark, S. E. & Yang, S. M., Dec 25 2002, In : Journal of the American Chemical Society. 124, 51, p. 15196-15197 2 p.

Research output: Contribution to journalArticle

Acetylene
Cross Reactions
acetylene
Silicon
silicon
Bearings (structural)
Siloxanes
Cross Reactions
Silicon
silicon

Lewis base activation of Lewis acids. Addition of silyl ketene acetals to aldehydes

Denmark, S. E., Wynn, T. & Beutner, G. L., Nov 13 2002, In : Journal of the American Chemical Society. 124, 45, p. 13405-13407 3 p.

Research output: Contribution to journalArticle

Lewis Bases
Lewis Acids
Acetals
aldehyde
Aldehydes

Preparation of n-butyl 4-chlorophenyl sulfide

McWilliams, J. C., Fleitz, F. J., Zheng, N., Armstrong, J. D., Denmark, S. E. & Sweis, R. F., Jan 1 2002, In : Organic Syntheses. 79, 1 p.

Research output: Contribution to journalArticle

Sulfides

Stereospecific cleavage of carbon-phosphorus bonds: Stereochemical course of the phosphinoyl curtius (harger) reaction

Denmark, S. E. & Dorow, R. L., Feb 11 2002, In : Chirality. 14, 2-3, p. 241-257 17 p.

Research output: Contribution to journalArticle

Azides
Phosphorus
Phenethylamines
Carbon
Hydrolysis

Synthesis of (+)-(1S,2R)- AND (í)-(1R,2S)-trans-2-phenylcyclohexanol via sharpless asymmetric dihydroxylation (AD): [Cyclohexanol, 2-phenyl-, (1s-trans)- and cyclohexanol, 2-phenyl-, (1r-trans)-]

Gonzalez, J., Aurigemma, C., Truesdale, L., Denmark, S. E., Tymonko, S. A., Cottell, J. J. & Gomez, L., Jan 1 2002, In : Organic Syntheses. 79, 1 p.

Research output: Contribution to journalArticle

Synthesis of cis,cis,cis,cis-[5.5.5.5]-1-Azafenestrane

Denmark, S. E., Kramps, L. A. & Montgomery, J. I., Nov 4 2002, In : Angewandte Chemie - International Edition. 41, 21, p. 4122-4125 4 p.

Research output: Contribution to journalArticle

X ray analysis
Atoms
Carbon
Boranes
Cycloaddition

Tandem inter [4+2]/intra [3+2] cycloadditions of nitroalkenes. Application to the synthesis of aminocarbasugars

Denmark, S. E. & Juhl, M., Jan 1 2002, In : Helvetica Chimica Acta. 85, 11, p. 3712-3736 25 p.

Research output: Contribution to journalArticle

Acetals
Cycloaddition
Cycloaddition Reaction
cycloaddition
Stereoselectivity

The effects of a remote stereogenic center in the Lewis base catalyzed aldol additions of chiral trichlorosilyl enolates

Denmark, S. E. & Fujimori, S., Oct 3 2002, In : Organic Letters. 4, 20, p. 3477-3480 4 p.

Research output: Contribution to journalArticle

Bearings (structural)
Lewis Bases
Lewis base
Ketones
Aldehydes
2001
Lewis Bases
Epoxy Compounds
Oxides
Recovery
Silicon

Cross-coupling of vinylpolysiloxanes with aryl iodides

Denmark, S. E. & Wang, Z., Apr 1 2001, In : Journal of Organometallic Chemistry. 624, 1-2, p. 372-375 4 p.

Research output: Contribution to journalArticle

Siloxanes
siloxanes
cross coupling
Cross Reactions
Iodides

Diastereoselective aldol addition reactions of a chiral methyl ketone trichlorosilyl enolate under lewis base catalysis

Denmark, S. E. & Fujimori, S., Jun 27 2001, In : Synlett. SPEC. ISS, p. 1024-1029 6 p.

Research output: Contribution to journalArticle

Bearings (structural)
Lewis Bases
Addition reactions
Ketones
Aldehydes

Fluoride-free cross-coupling of organosilanols

Denmark, S. E. & Sweis, R. F., Oct 9 2001, In : Journal of the American Chemical Society. 123, 26, p. 6439-6440 2 p.

Research output: Contribution to journalLetter

Fluorides

Highly diastereoselective aldol additions of a chiral ethyl ketone enolate under Lewis base catalysis

Denmark, S. E. & Pham, S. M., Jul 12 2001, In : Organic Letters. 3, 14, p. 2201-2204 4 p.

Research output: Contribution to journalArticle

Bearings (structural)
Hempa
Lewis Bases
Stereoselectivity
Lewis base

Highly stereoselective hydrocarbation of terminal alkynes via Pt-Catalyzed Hydrosilylation/Pd-Catalyzed cross-coupling reactions

Denmark, S. E. & Wang, Z., Apr 5 2001, In : Organic Letters. 3, 7, p. 1073-1076 4 p.

Research output: Contribution to journalArticle

Hydrosilylation
Alkynes
cross coupling
Cross Reactions
alkynes

Intramolecular hydrosilylation and silicon-assisted cross-coupling: An efficient route to trisubstituted homoallylic alcohols

Denmark, S. E. & Weitao, P., Jan 11 2001, In : Organic Letters. 3, 1, p. 61-64 4 p.

Research output: Contribution to journalArticle

Hydrosilylation
cross coupling
Silicon
alcohols
routes
Lewis Bases
Allylation
Lewis Acids
Aldehydes
Chemical activation
Styrenes
Bearings (structural)
Siloxanes
Ethers
metathesis

Studies on the reduction and hydrolysis of nitroso acetals

Denmark, S. E., Guagnano, V. & Vaugeois, J., Jan 1 2001, In : Canadian Journal of Chemistry. 79, 11, p. 1606-1616 11 p.

Research output: Contribution to journalArticle

Acetals
Hydrolysis
Samarium
Cycloaddition
Acids

Synthesis of (+)-1-epiaustraline

Denmark, S. E. & Cottell, J. J., Jun 15 2001, In : Journal of Organic Chemistry. 66, 12, p. 4276-4284 9 p.

Research output: Contribution to journalArticle

Acetals
Hydrogenolysis
Cycloaddition
Alkylation
Silicon

Tandem double intramolecular [4 + 2]/[3 + 2] cycloadditions of nitroalkenes

Denmark, S. E., Baiazitov, R. Y. & Nguyen, S. T., Jan 1 2001, In : Organic Letters. 3, 18, p. 2907-2910 4 p.

Research output: Contribution to journalArticle

Cycloaddition
Cycloaddition Reaction
cycloaddition
Bearings (structural)
Polyenes

The first catalytic, diastereoselective, and enantioselective crossed-aldol reactions of aldehydes

Denmark, S. E. & Ghosh, S. K., Dec 17 2001, In : Angewandte Chemie - International Edition. 40, 24, p. 4759-4762 4 p.

Research output: Contribution to journalArticle

Aldehydes
Enantioselectivity
Catalysis
Condensation
3-hydroxybutanal
2000
Palladium
Temperature
tetrabutylammonium