Scott E Denmark

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Research Output

Article

New vistas in organoelement chemistry

Denmark, S. E., Christenson, B. L., O'Connor, S. P. & Murase, N., Jan 1996, In : Pure and Applied Chemistry. 68, 1, p. 23-27 5 p.

Research output: Contribution to journalArticle

Nitroalkene Inter [4 + 2]/Intra [3 + 2] Tandem Cycloadditions. 7. Application of (R)-(-)-2,2-Diphenylcyclopentanol as the Chiral Auxiliary

Denmark, S. E., Schnute, M. E., Marcin, L. R. & Thorarensen, A., May 1 1995, In : Journal of Organic Chemistry. 60, 10, p. 3205-3220 16 p.

Research output: Contribution to journalArticle

N-silyl oxyketene imines are underused yet highly versatile reagents for catalytic asymmetric synthesis

Denmark, S. E. & Wilson, T. W., Nov 1 2010, In : Nature Chemistry. 2, 11, p. 937-943 7 p.

Research output: Contribution to journalArticle

Observation of direct sulfenium and selenenium group transfer from thiiranium and seleniranium ions to alkenes

Denmark, S. E., Collins, W. R. & Cullen, M. D., Mar 18 2009, In : Journal of the American Chemical Society. 131, 10, p. 3490-3492 3 p.

Research output: Contribution to journalArticle

On the absolute configurational stability of bromonium and chloronium ions

Denmark, S. E., Burk, M. T. & Hoover, A. J., Feb 3 2010, In : Journal of the American Chemical Society. 132, 4, p. 1232-1233 2 p.

Research output: Contribution to journalArticle

On the Generation and Configurational Stability of (2S,3S)-1,2,3-TriphenyIborirane

Denmark, S. E., Nishide, K. & Faucher, A. M., Aug 1 1991, In : Journal of the American Chemical Society. 113, 17, p. 6675-6676 2 p.

Research output: Contribution to journalArticle

On the lewis acid induced addition of allylstannanes to aldehydes: A spectroscopic investigation

Denmark, S. E., Wilson, T. & Willson, T. M., Feb 1988, In : Journal of the American Chemical Society. 110, 3, p. 984-986 3 p.

Research output: Contribution to journalArticle

On the mechanism of Lewis base catalyzed aldol addition reactions: Kinetic and spectroscopic investigations using rapid-injection NMR

Denmark, S. E., Eklov, B. M., Yao, P. J. & Eastgate, M. D., Aug 26 2009, In : Journal of the American Chemical Society. 131, 33, p. 11770-11787 18 p.

Research output: Contribution to journalArticle

On the mechanism of the selenolactonization reaction with selenenyl halides

Denmark, S. E. & Edwards, M. G., Sep 15 2006, In : Journal of Organic Chemistry. 71, 19, p. 7293-7306 14 p.

Research output: Contribution to journalArticle

On the mechanism of the Skraup-Doebner-Von Miller quinoline synthesis

Denmark, S. E. & Venkatraman, S., Feb 17 2006, In : Journal of Organic Chemistry. 71, 4, p. 1668-1676 9 p.

Research output: Contribution to journalArticle

On the stereochemical course of palladium-catalyzed cross-coupling of allylic silanolate salts with aromatic bromides

Denmark, S. E. & Werner, N. S., Mar 17 2010, In : Journal of the American Chemical Society. 132, 10, p. 3612-3620 9 p.

Research output: Contribution to journalArticle

On the stereochemical course of the addition of allylsilanes to aldehydes

Denmark, S. E., Weber, E. J., Almstead, N. G. & Wolf, L. M., Sep 16 2012, In : Tetrahedron. 68, 37, p. 7701-7718 18 p.

Research output: Contribution to journalArticle

On the stereochemistry of allylmetal‐aldehyde condensations. Preliminary communication

Denmark, S. E. & Weber, E. J., Sep 21 1983, In : Helvetica Chimica Acta. 66, 6, p. 1655-1660 6 p.

Research output: Contribution to journalArticle

On the Stereoselective Opening of Achiral Dioxane Acetals

Denmark, S. E. & Almstead, N. G., Oct 1 1991, In : Journal of Organic Chemistry. 56, 22, p. 6458-6467 10 p.

Research output: Contribution to journalArticle

On the Stereoselective Opening of Chiral Dioxane Acetals. Nucleophile Dependence

Denmark, S. E. & Almstead, N. G., Nov 1 1991, In : Journal of Organic Chemistry. 56, 23, p. 6485-6487 3 p.

Research output: Contribution to journalArticle

Organic Synthesis: Wherefrom and Whither? (Some Very Personal Reflections)

Denmark, S. E., Feb 2018, In : Israel Journal of Chemistry. 58, 1, p. 61-72 12 p.

Research output: Contribution to journalArticle

Organocerium additions to chiral α,α-dialkoxy hydrazones: Asymmetric synthesis of JV-protected a-amino acetals and α-amino aldehydes

Denmark, S. E. & Nicaise, O., May 1993, In : Synlett. 1993, 5, p. 359-361 3 p.

Research output: Contribution to journalArticle

Organocerium Additions to Hydrazones: Effects of Reagent Stoichiometry on Efficiency and Selectivity

Denmark, S. E., Edwards, J. P. & Nicaise, O., Jan 1 1993, In : Journal of Organic Chemistry. 58, 3, p. 569-578 10 p.

Research output: Contribution to journalArticle

Organocerium additions to proline-derived hydrazones: Synthesis of enantiomerically enriched amines

Denmark, S. E., Edwards, J. P., Weber, T. & Piotrowski, D. W., May 17 2010, In : Tetrahedron Asymmetry. 21, 9-10, p. 1278-1302 25 p.

Research output: Contribution to journalArticle

Organocerium Additions to SAMP-Hydrazones: General Synthesis of Chiral Amines

Denmark, S. E., Weber, T. & Piotrowski, D. W., Apr 1 1987, In : Journal of the American Chemical Society. 109, 7, p. 2224-2225 2 p.

Research output: Contribution to journalArticle

Organoselenium-catalyzed enantioselective syn-dichlorination of unbiased alkenes

Gilbert, B. B., Eey, S. T. C., Ryabchuk, P., Garry, O. & Denmark, S. E., Aug 2 2019, In : Tetrahedron. 75, 31, p. 4086-4098 13 p.

Research output: Contribution to journalArticle

Palladium-catalyzed conjugate addition of organosiloxanes to α,β-unsaturated carbonyl compounds and nitroalkenes

Denmark, S. E. & Amishiro, N., Sep 5 2003, In : Journal of Organic Chemistry. 68, 18, p. 6997-7003 7 p.

Research output: Contribution to journalArticle

Palladium catalyzed cross-coupling of (Z)-1-heptenyldimethylsilanol with 4-iodoanisole: (Z)-1-Heptenyl-4-methoxybenzene: [Benzene,1-(1Z)-1-heptenyl-4-methoxy-]

Denmark, S. E., Wang, Z., Campbell, M. & Curran, D. P., Jan 1 2005, In : Organic Syntheses. 81, p. 42-53 12 p.

Research output: Contribution to journalArticle

Palladium-catalyzed cross-coupling of five-membered heterocyclic silanolates

Denmark, S. E., Baird, J. D. & Regens, C. S., Feb 15 2008, In : Journal of Organic Chemistry. 73, 4, p. 1440-1455 16 p.

Research output: Contribution to journalArticle

Palladium-catalyzed cross-coupling reactions of 2-indolyldimethylsilanols with substituted aryl halides

Denmark, S. E. & Baird, J. D., Sep 30 2004, In : Organic Letters. 6, 20, p. 3649-3652 4 p.

Research output: Contribution to journalArticle

Palladium-catalyzed cross-coupling reactions of heterocyclic silanolates with substituted aryl iodides and bromides

Denmark, S. E. & Baird, J. D., Feb 16 2006, In : Organic Letters. 8, 4, p. 793-795 3 p.

Research output: Contribution to journalArticle

Palladium-catalyzed cross-coupling reactions of silanolates: A paradigm shift in silicon-based cross-coupling reactions

Denmark, S. E. & Baird, J. D., Jun 23 2006, In : Chemistry - A European Journal. 12, 19, p. 4954-4963 10 p.

Research output: Contribution to journalArticle

Palladium-catalyzed cross-coupling reactions of substituted aryl(dimethyl)silanols

Denmark, S. E. & Ober, M. H., Dec 1 2004, In : Advanced Synthesis and Catalysis. 346, 13-15, p. 1703-1714 12 p.

Research output: Contribution to journalArticle

Palladium-Catalyzed Silylation of Aryl Bromides Leading to Functionalized Aryldimethylsilanols

Denmark, S. E. & Kallemeyn, J. M., Sep 18 2003, In : Organic Letters. 5, 19, p. 3483-3486 4 p.

Research output: Contribution to journalArticle

Palladium-Promoted Intramolecular Addition of an Aryl Iodide to a Nitroalkene

Denmark, S. E. & Schnute, M. E., Feb 1 1995, In : Journal of Organic Chemistry. 60, 4, p. 1013-1019 7 p.

Research output: Contribution to journalArticle

Phosphine oxides as stabilizing ligands for the palladium-catalyzed cross-coupling of potassium aryldimethylsilanolates

Denmark, S. E., Smith, R. C. & Tymonko, S. A., Jun 25 2007, In : Tetrahedron. 63, 26, p. 5730-5738 9 p.

Research output: Contribution to journalArticle

Potassium Trimethylsilanolate Enables Rapid, Homogeneous Suzuki-Miyaura Cross-Coupling of Boronic Esters

Delaney, C. P., Kassel, V. M. & Denmark, S. E., Jan 1 2019, (Accepted/In press) In : ACS Catalysis. p. 73-80 8 p.

Research output: Contribution to journalArticle

Prediction of higher-selectivity catalysts by computer-driven workflow and machine learning

Zahrt, A. F., Henle, J. J., Rose, B. T., Wang, Y., Darrow, W. T. & Denmark, S. E., Jan 18 2019, In : Science. 363, 6424, eaau5631.

Research output: Contribution to journalArticle

Preparation of 2,3-disubstituted indoles by sequential Larock heteroannulation and silicon-based cross-coupling reactions

Denmark, S. E. & Baird, J. D., Apr 18 2009, In : Tetrahedron. 65, 16, p. 3120-3129 10 p.

Research output: Contribution to journalArticle

Preparation of 2-chloro-1,3 bis(dimethylamino) trimethinium hexafluorophosphate [[methanaminium, N-[2-chloro-3-(dimethylamino)-2-propenylidene]-N-methyl-, hexafluorophosphate(1-)]]

Davies, I. W., Marcoux, J. F., Taylor, J., Fan, Y. & Denmark, S. E., Jan 1 2003, In : Organic Syntheses. 80, p. 200-206 7 p.

Research output: Contribution to journalArticle

Preparation of a diisopropylselenophosphoramide catalyst and its use in enantioselective sulfenoetherification

Denmark, S. E., Ryabchuk, P., Chi, H. M. & Matviitsuk, A., Jan 1 2019, In : Organic Syntheses. 96, p. 400-417 18 p.

Research output: Contribution to journalArticle

Open Access

Preparation of chiral bipyridine bis-N-oxides by oxidative dimerization of chiral pyridine N-oxides

Denmark, S. E. & Fan, Y., Feb 20 2006, In : Tetrahedron Asymmetry. 17, 4, p. 687-707 21 p.

Research output: Contribution to journalArticle

Preparation of Chiral Bisoxazolines: Observations on the Effect of Substituents

Denmark, S. E., Nakajima, N., Nicaise, O. J. C., Faucher, A. M. & Edwards, J. P., Jul 1 1995, In : Journal of Organic Chemistry. 60, 15, p. 4884-4892 9 p.

Research output: Contribution to journalArticle

Preparation of chlorosilyl enolates

Denmark, S. E., Stavenger, R. A., Winter, S. B. D., Wong, K. T. & Barsanti, P. A., Dec 11 1998, In : Journal of Organic Chemistry. 63, 25, p. 9517-9523 7 p.

Research output: Contribution to journalArticle

Preparation of enantiomerically enriched (1S)-1-phenylpropan-1-amine hydrochloride by a catalytic addition of diorganozinc reagents to imines :[Benzenemethanamine, -ethyl-, hydrochloride, (S)-]

Desrosiers, J. N., Côté, A., Boezio, A. A., Charette, A. B., Denmark, S. E. & Montgomery, J. I., Jan 1 2006, In : Organic Syntheses. 83, p. 5-17 13 p.

Research output: Contribution to journalArticle

Preparation of enantiomerically pure (R,R)-BozPHOS: [(2R,5R)-1-{2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl}-2,5-dimethylphospholane 1-oxide]

Côté, A., Desrosiers, J. N., Boezio, A. A., Charette, A. B., Denmark, S. E. & Montgomery, J. I., Jan 1 2006, In : Organic Syntheses. 83, p. 1-4 4 p.

Research output: Contribution to journalArticle

Preparation of hexakis(4-Bromophenyl)benzene (HBB) [1,1':2',1''-Terphenyl, 4,4''-dibromo-3',4',5',6'-tetrakis(4-Bromophenyl)-]

Rathore, R., Burns, C. L., Denmark, S. E. & Fujimori, S., Jan 1 2005, In : Organic Syntheses. 82, p. 30-33 4 p.

Research output: Contribution to journalArticle

Preparation of n-butyl 4-chlorophenyl sulfide

McWilliams, J. C., Fleitz, F. J., Zheng, N., Armstrong, J. D., Denmark, S. E. & Sweis, R. F., Jan 1 2002, In : Organic Syntheses. 79, 1 p.

Research output: Contribution to journalArticle

Preparative and mechanistic studies toward the rational development of catalytic, enantioselective selenoetherification reactions

Denmark, S. E., Kalyani, D. & Collins, W. R., Nov 10 2010, In : Journal of the American Chemical Society. 132, 44, p. 15752-15765 14 p.

Research output: Contribution to journalArticle

Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link

Thomas, A. A. & Denmark, S. E., Apr 15 2016, In : Science. 352, 6283, p. 329-332 4 p.

Research output: Contribution to journalArticle