Scott E Denmark

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Research Output

2001

Tandem double intramolecular [4 + 2]/[3 + 2] cycloadditions of nitroalkenes

Denmark, S. E., Baiazitov, R. Y. & Nguyen, S. T., 2001, In : Organic Letters. 3, 18, p. 2907-2910 4 p.

Research output: Contribution to journalArticle

The first catalytic, diastereoselective, and enantioselective crossed-aldol reactions of aldehydes

Denmark, S. E. & Ghosh, S. K., Dec 17 2001, In : Angewandte Chemie - International Edition. 40, 24, p. 4759-4762 4 p.

Research output: Contribution to journalArticle

2002

Catalytic, enantioselective aldol additions to ketones

Denmark, S. E. & Fan, Y., Apr 24 2002, In : Journal of the American Chemical Society. 124, 16, p. 4233-4235 3 p.

Research output: Contribution to journalArticle

Catalytic enantioselective addition of dialkylzincs to aldehydes using (2S)-(-)-3-exo-(dimethylamino)isoborneol [(2S)-daib]: (S)-1-phenyl-1-propanol: [Benzenemethanol, α-ethyl-, (S)-]

Kitamura, M., Oka, H., Suga, S., Noyori, R., Kaelin, D. E., Martin, S. F., Beutner, G. L. & Denmark, S. E., Jan 1 2002, In : Organic Syntheses. 79, 1 p.

Research output: Contribution to journalArticle

Chiral fluoro ketones for catalytic asymmetric epoxidation of alkenes with oxone

Denmark, S. E. & Matsuhashi, H., May 17 2002, In : Journal of Organic Chemistry. 67, 10, p. 3479-3486 8 p.

Research output: Contribution to journalArticle

Cross-coupling reactions of alkenylsilanols with fluoroalkylsulfonates

Denmark, S. E. & Sweis, R. F., Oct 17 2002, In : Organic Letters. 4, 21, p. 3771-3774 4 p.

Research output: Contribution to journalArticle

Cross-coupling reactions of organosilicon compounds: New concepts and recent advances

Denmark, S. E. & Sweis, R. F., Dec 1 2002, In : Chemical and Pharmaceutical Bulletin. 50, 12, p. 1531-1541 11 p.

Research output: Contribution to journalReview article

Design and implementation of new, silicon-based, cross-coupling reactions: Importance of silicon-oxygen bonds

Denmark, S. E. & Sweis, R. F., Oct 1 2002, In : Accounts of chemical research. 35, 10, p. 835-846 12 p.

Research output: Contribution to journalArticle

Diastereoselective aldol additions of chiral β-hydroxy ethyl ketone enolates catalyzed by Lewis bases

Denmark, S. E. & Fujimori, S., Oct 3 2002, In : Organic Letters. 4, 20, p. 3473-3476 4 p.

Research output: Contribution to journalArticle

Efficient and stereoselective cross-coupling with highly substituted alkenylsilanols

Denmark, S. E. & Pan, W., Jul 1 2002, In : Journal of Organometallic Chemistry. 653, 1-2, p. 98-104 7 p.

Research output: Contribution to journalArticle

Formation of γ-keto esters from β-keto esters: Methyl 5,5-dimethyl-4-oxohexanoate: [Hexanoic acid, 5,5-dimethyl-4-oxo-, methyl ester]

Ronsheim, M. D., Hilgenkamp, R. K., Zercher, C. K., Denmark, S. E. & Beutner, G. L., Jan 1 2002, In : Organic Syntheses. 79, 1 p.

Research output: Contribution to journalArticle

Inter- and intramolecular [4+2] cycloaddition of nitroalkenes with allenylsilanes. A case of unexpected regioselectivity

Denmark, S. E. & Gomez, L., Nov 22 2002, In : Heterocycles. 58, p. 129-136 8 p.

Research output: Contribution to journalArticle

Intramolecular silicon-assisted cross-coupling: Total synthesis of (+)-brasilenyne

Denmark, S. E. & Yang, S. M., Dec 25 2002, In : Journal of the American Chemical Society. 124, 51, p. 15196-15197 2 p.

Research output: Contribution to journalArticle

Lewis base activation of Lewis acids. Addition of silyl ketene acetals to aldehydes

Denmark, S. E., Wynn, T. & Beutner, G. L., Nov 13 2002, In : Journal of the American Chemical Society. 124, 45, p. 13405-13407 3 p.

Research output: Contribution to journalArticle

Preparation of n-butyl 4-chlorophenyl sulfide

McWilliams, J. C., Fleitz, F. J., Zheng, N., Armstrong, J. D., Denmark, S. E. & Sweis, R. F., Jan 1 2002, In : Organic Syntheses. 79, 1 p.

Research output: Contribution to journalArticle

Stereospecific cleavage of carbon-phosphorus bonds: Stereochemical course of the phosphinoyl curtius (harger) reaction

Denmark, S. E. & Dorow, R. L., Feb 11 2002, In : Chirality. 14, 2-3, p. 241-257 17 p.

Research output: Contribution to journalArticle

Synthesis of (+)-(1S,2R)- AND (í)-(1R,2S)-trans-2-phenylcyclohexanol via sharpless asymmetric dihydroxylation (AD): [Cyclohexanol, 2-phenyl-, (1s-trans)- and cyclohexanol, 2-phenyl-, (1r-trans)-]

Gonzalez, J., Aurigemma, C., Truesdale, L., Denmark, S. E., Tymonko, S. A., Cottell, J. J. & Gomez, L., 2002, In : Organic Syntheses. 79, 1 p.

Research output: Contribution to journalArticle

Synthesis of cis,cis,cis,cis-[5.5.5.5]-1-Azafenestrane

Denmark, S. E., Kramps, L. A. & Montgomery, J. I., Nov 4 2002, In : Angewandte Chemie - International Edition. 41, 21, p. 4122-4125 4 p.

Research output: Contribution to journalArticle

Tandem inter [4+2]/intra [3+2] cycloadditions of nitroalkenes. Application to the synthesis of aminocarbasugars

Denmark, S. E. & Juhl, M., Jan 1 2002, In : Helvetica Chimica Acta. 85, 11, p. 3712-3736 25 p.

Research output: Contribution to journalArticle

The effects of a remote stereogenic center in the Lewis base catalyzed aldol additions of chiral trichlorosilyl enolates

Denmark, S. E. & Fujimori, S., Oct 3 2002, In : Organic Letters. 4, 20, p. 3477-3480 4 p.

Research output: Contribution to journalArticle

2003

2-Silyloxy-1,2-oxazines, a New Type of Acetals of Conjugated Nitroso Alkenes

Tishkov, A. A., Lesiv, A. V., Khomutova, Y. A., Strelenko, Y. A., Nesterov, I. D., Antipin, M. Y., Ioffe, S. L. & Denmark, S. E., Nov 28 2003, In : Journal of Organic Chemistry. 68, 24, p. 9477-9480 4 p.

Research output: Contribution to journalArticle

Catalytic enantioselective addition of allylic organometallic reagents to aldehydes and ketones

Denmark, S. E. & Fu, J., Aug 1 2003, In : Chemical reviews. 103, 8, p. 2763-2793 31 p.

Research output: Contribution to journalArticle

Catalytic enantioselective allylation with chiral Lewis bases

Denmark, S. E. & Fu, J., Jan 1 2003, In : Chemical Communications. 2, p. 167-170 4 p.

Research output: Contribution to journalArticle

Cross-Coupling of Alkynylsilanols with Aryl Halides Promoted by Potassium Trimethylsilanolate

Denmark, S. E. & Tymonko, S. A., Nov 14 2003, In : Journal of Organic Chemistry. 68, 23, p. 9151-9154 4 p.

Research output: Contribution to journalArticle

Cross-coupling reactions of arylsilanols with substituted aryl halides

Denmark, S. E. & Ober, M. H., Apr 17 2003, In : Organic Letters. 5, 8, p. 1357-1360 4 p.

Research output: Contribution to journalArticle

Generation and [2+2] cycloadditions of thio-substituted ketenes: trans-1-(4-methoxyphenyl)-4-phenyl-3-(phenylthio)azetidin-2-one [(2-azetidinone, 1-(4-methoxyphenyl)-4-phenyl-3-(phenylthio)-, trans-)]

Danheiser, R. L., Okamoto, I., Lawlor, M. D., Lee, T. W., Denmark, S. E. & Ober, M. H., Jan 1 2003, In : Organic Syntheses. 80, p. 160-171 12 p.

Research output: Contribution to journalArticle

Lewis base activation of lewis acids. Catalytic enantioselective addition of silyl enol ethers of achiral methyl ketones to aldehydes

Denmark, S. E. & Heemstra, J. R., Jun 26 2003, In : Organic Letters. 5, 13, p. 2303-2306 4 p.

Research output: Contribution to journalArticle

Lewis base activation of Lewis acids. Vinylogous aldol reactions

Denmark, S. E. & Beutner, G. L., Jul 2 2003, In : Journal of the American Chemical Society. 125, 26, p. 7800-7801 2 p.

Research output: Contribution to journalArticle

Organosilicon Reagents: Synthesis and Application to Palladium-Catalyzed Cross-Coupling Reactions

Denmark, S. E. & Ober, M. H., Dec 1 2003, In : Aldrichimica Acta. 36, 3, p. 75-85 11 p.

Research output: Contribution to journalReview article

Palladium-catalyzed conjugate addition of organosiloxanes to α,β-unsaturated carbonyl compounds and nitroalkenes

Denmark, S. E. & Amishiro, N., Sep 5 2003, In : Journal of Organic Chemistry. 68, 18, p. 6997-7003 7 p.

Research output: Contribution to journalArticle

Palladium-Catalyzed Silylation of Aryl Bromides Leading to Functionalized Aryldimethylsilanols

Denmark, S. E. & Kallemeyn, J. M., Sep 18 2003, In : Organic Letters. 5, 19, p. 3483-3486 4 p.

Research output: Contribution to journalArticle

Preparation of 2-chloro-1,3 bis(dimethylamino) trimethinium hexafluorophosphate [[methanaminium, N-[2-chloro-3-(dimethylamino)-2-propenylidene]-N-methyl-, hexafluorophosphate(1-)]]

Davies, I. W., Marcoux, J. F., Taylor, J., Fan, Y. & Denmark, S. E., Jan 1 2003, In : Organic Syntheses. 80, p. 200-206 7 p.

Research output: Contribution to journalArticle

Stereoselective aldol additions of achiral ethyl ketone-derived trichlorosilyl enolates

Denmark, S. E. & Pham, S. M., Jun 27 2003, In : Journal of Organic Chemistry. 68, 13, p. 5045-5055 11 p.

Research output: Contribution to journalArticle

Tandem double intramolecular [4+2]/[3+2] cycloadditions of nitroalkenes. The fused/bridged mode

Denmark, S. E. & Gomez, L., Oct 17 2003, In : Journal of Organic Chemistry. 68, 21, p. 8015-8024 10 p.

Research output: Contribution to journalArticle

Topics in stereochemistry. Vol. 23

Denmark, S. E., 2003, Hoboken: Wiley-Interscience.

Research output: Book/Report/Conference proceedingBook

Transformation of primary amines to N-monoalkylhydroxylamines: N-hydroxy-(S)-1-phenylethylamine oxalate: [(Benzenemethanamine, N-hydroxy--methyl-, (S)-, ethanedioate)]

Tokuyama, H., Kuboyama, T., Fukuyama, T., Denmark, S. E. & Cottell, J. J., Jan 1 2003, In : Organic Syntheses. 80, p. 207-218 12 p.

Research output: Contribution to journalArticle

2004

Fluoride-Promoted Cross-Coupling Reactions of Alkenylsilanols. Elucidation of the Mechanism through Spectroscopic and Kinetic Analysis

Denmark, S. E., Sweis, R. F. & Wehrli, D., Apr 21 2004, In : Journal of the American Chemical Society. 126, 15, p. 4865-4875 11 p.

Research output: Contribution to journalArticle

Lewis base activation of Lewis acids: Vinylogous aldol additions of silyl dienol ethers to aldehydes

Denmark, S. E. & Heemstra, J. R., Nov 3 2004, In : Synlett. 13, p. 2411-2416 6 p.

Research output: Contribution to journalArticle

Palladium-catalyzed cross-coupling reactions of 2-indolyldimethylsilanols with substituted aryl halides

Denmark, S. E. & Baird, J. D., Sep 30 2004, In : Organic Letters. 6, 20, p. 3649-3652 4 p.

Research output: Contribution to journalArticle

Palladium-catalyzed cross-coupling reactions of substituted aryl(dimethyl)silanols

Denmark, S. E. & Ober, M. H., Dec 1 2004, In : Advanced Synthesis and Catalysis. 346, 13-15, p. 1703-1714 12 p.

Research output: Contribution to journalArticle