Scott E Denmark

1975 …2019
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Research Output 1975 2019

2006

On the mechanism of the Skraup-Doebner-Von Miller quinoline synthesis

Denmark, S. E. & Venkatraman, S., Feb 17 2006, In : Journal of Organic Chemistry. 71, 4, p. 1668-1676 9 p.

Research output: Contribution to journalArticle

Ketones
Labels
Aniline Compounds
Quinolines
Imines

Organic chemistry: Catalysts break symmetry

Denmark, S. E., Sep 7 2006, In : Nature. 443, 7107, p. 40-41 2 p.

Research output: Contribution to journalShort survey

Organic Chemistry
Synthetic Chemistry Techniques

Palladium-catalyzed cross-coupling reactions of heterocyclic silanolates with substituted aryl iodides and bromides

Denmark, S. E. & Baird, J. D., Feb 16 2006, In : Organic Letters. 8, 4, p. 793-795 3 p.

Research output: Contribution to journalArticle

cross coupling
Cross Reactions
Palladium
Iodides
Bromides

Palladium-catalyzed cross-coupling reactions of silanolates: A paradigm shift in silicon-based cross-coupling reactions

Denmark, S. E. & Baird, J. D., Jun 23 2006, In : Chemistry - A European Journal. 12, 19, p. 4954-4963 10 p.

Research output: Contribution to journalArticle

Palladium
Silicon
Patents and inventions
Fluorides
Chemical activation

Preparation of chiral bipyridine bis-N-oxides by oxidative dimerization of chiral pyridine N-oxides

Denmark, S. E. & Fan, Y., Feb 20 2006, In : Tetrahedron Asymmetry. 17, 4, p. 687-707 21 p.

Research output: Contribution to journalArticle

Dimerization
dimerization
Pyridine
Oxides
pyridines

Preparation of enantiomerically enriched (1S)-1-phenylpropan-1-amine hydrochloride by a catalytic addition of diorganozinc reagents to imines :[Benzenemethanamine, -ethyl-, hydrochloride, (S)-]

Desrosiers, J. N., Côté, A., Boezio, A. A., Charette, A. B., Denmark, S. E. & Montgomery, J. I., Jan 1 2006, In : Organic Syntheses. 83, p. 5-17 13 p.

Research output: Contribution to journalArticle

Preparation of enantiomerically pure (R,R)-BozPHOS: [(2R,5R)-1-{2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl}-2,5-dimethylphospholane 1-oxide]

Côté, A., Desrosiers, J. N., Boezio, A. A., Charette, A. B., Denmark, S. E. & Montgomery, J. I., Jan 1 2006, In : Organic Syntheses. 83, p. 1-4 4 p.

Research output: Contribution to journalArticle

Reduction of allylpalladium(II)chloride dimer by formation of allyloxysilanes

Denmark, S. E. & Smith, R. C., Nov 3 2006, In : Synlett. 18, p. 2921-2928 8 p.

Research output: Contribution to journalArticle

Dimers
Chlorides
Alkali Metals
Chelation
Ligands

Stereospecific palladium-catalyzed cross-coupling of (E)- and (Z)-alkenylsilanolates with aryl chlorides

Denmark, S. E. & Kallemeyn, J. M., Dec 20 2006, In : Journal of the American Chemical Society. 128, 50, p. 15958-15959 2 p.

Research output: Contribution to journalArticle

palladium
Palladium
Ketones
Functional groups
Catalysis

Synthesis, x-ray crystallography, and computational analysis of 1-azafenestranes

Denmark, S. E., Montgomery, J. I. & Kramps, L. A., Sep 6 2006, In : Journal of the American Chemical Society. 128, 35, p. 11620-11630 11 p.

Research output: Contribution to journalArticle

crystallography
Crystallography
Cycloaddition Reaction
Cycloaddition
X-Rays
Cycloaddition
Functional groups
Acetals
Biological Products
Alkaloids

Topics in Stereochemistry: Introduction to the series

Denmark, S. E. & Siegel, J. S., Jul 13 2006, In : Topics in Stereochemistry. 25, p. v

Research output: Contribution to journalEditorial

Stereochemistry

Topics in Stereochemistry

Denmark, S. E. & Siegel, J. S., May 5 2006, Wiley Blackwell. 403 p.

Research output: Book/ReportBook

Stereochemistry
Crystals
Hydrogen bonds
Pyrimidinones
Stilbenes

Topics in stereochemistry. Vol. 25

Siegel, J. S. & Denmark, S. E., 2006, Hoboken, N, J: John Wiley & Sons.

Research output: Book/ReportBook

Trifluoromethylation at the -position of ,-unsaturated ketones: 4-Phenyl-3-(trifluoromethyl)butan-2-one

Sato, K., Omote, M., Ando, A., Kumadaki, I., Denmark, S. E. & Chung, W. J., Jan 1 2006, In : Organic Syntheses. 83, p. 177-183 7 p.

Research output: Contribution to journalArticle

ketones

Vinylation of aryl bromides using an inexpensive vinylpolysiloxane

Denmark, S. E. & Butler, C. R., Jan 5 2006, In : Organic Letters. 8, 1, p. 63-66 4 p.

Research output: Contribution to journalArticle

Styrenes
Palladium
Bromides
styrenes
fluorides
2005

Catalytic, enantioselective, vinylogous aldol reactions

Denmark, S. E., Heemstra, J. R. & Beutner, G. L., Jul 25 2005, In : Angewandte Chemie - International Edition. 44, 30, p. 4682-4698 17 p.

Research output: Contribution to journalReview article

Functional groups
Carbon
Carbonyl compounds
Ethers
Enantioselectivity

Catalytic, enantioselective α-additions of isocyanides: Lewis base catalyzed Passerini-type reactions

Denmark, S. E. & Fan, Y., Nov 25 2005, In : Journal of Organic Chemistry. 70, 24, p. 9667-9676 10 p.

Research output: Contribution to journalArticle

Lewis Bases
Cyanides
Enantioselectivity
Aldehydes
Amides
Silicon
brasilenyne

Generation and cyclization of 5-hexenyllithium: 2-cyclopentylacetophenone: (ethanone, 2-cyclopentyl-1-phenyl-)

Bailey, W. F., Luderer, M. R., Mealy, M. J., Punzalan, E. R., Denmark, S. E. & Macneil, S. L., Jan 1 2005, In : Organic Syntheses. 81, p. 121-133 13 p.

Research output: Contribution to journalArticle

Intramolecular [4 + 2] cycloaddition of nitroalkenes for construction of vicinal quaternary stereocenters

Denmark, S. E. & Baiazitov, R. Y., Dec 8 2005, In : Organic Letters. 7, 25, p. 5617-5620 4 p.

Research output: Contribution to journalArticle

Cycloaddition
Cycloaddition Reaction
cycloaddition
dienes
alkenes

Lewis base activation of Lewis acids: Catalytic, enantioselective addition of silyl ketene acetals to aldehydes

Denmark, S. E., Beutner, G. L., Wynn, T. & Eastgate, M. D., Mar 23 2005, In : Journal of the American Chemical Society. 127, 11, p. 3774-3789 16 p.

Research output: Contribution to journalArticle

Lewis Bases
Lewis Acids
Acetals
aldehyde
Aldehydes

Lewis base catalyzed, enantioselective aldol addition of methyl trichlorosilyl ketene acetal to ketones

Denmark, S. E., Fan, Y. & Eastgate, M. D., Jun 24 2005, In : Journal of Organic Chemistry. 70, 13, p. 5235-5248 14 p.

Research output: Contribution to journalArticle

Lewis Bases
Acetals
Ketones
Enantioselectivity
Bearings (structural)

Lewis base catalyzed aldol additions of chiral trichlorosilyl enolates and silyl enol ethers

Denmark, S. E., Fujimori, S. & Pham, S. M., Dec 23 2005, In : Journal of Organic Chemistry. 70, 26, p. 10823-10840 18 p.

Research output: Contribution to journalArticle

Lewis Bases
Ethers
3-Hydroxybutyric Acid
Phosphoramides
Catalysts

Lewis base catalyzed enantioselective aldol addition of acetaldehyde-derived silyl enol ether to aldehydes

Denmark, S. E. & Bui, T., Nov 25 2005, In : Journal of Organic Chemistry. 70, 24, p. 10190-10193 4 p.

Research output: Contribution to journalArticle

Lewis Bases
Acetaldehyde
Aldehydes
Ether
Chlorohydrins

Mechanistic insights into the chiral phosphoramide-catalyzed, enantioselective crossed-aldol reactions of aldehydes

Denmark, S. E. & Bui, T., Dec 9 2005, In : Journal of Organic Chemistry. 70, 25, p. 10393-10399 7 p.

Research output: Contribution to journalArticle

Aldehydes
Chemical activation
Isotopes
Addition reactions
Kinetics

Palladium catalyzed cross-coupling of (Z)-1-heptenyldimethylsilanol with 4-iodoanisole: (Z)-1-Heptenyl-4-methoxybenzene: [Benzene,1-(1Z)-1-heptenyl-4-methoxy-]

Denmark, S. E., Wang, Z., Campbell, M. & Curran, D. P., Jan 1 2005, In : Organic Syntheses. 81, p. 42-53 12 p.

Research output: Contribution to journalArticle

Preparation of hexakis(4-Bromophenyl)benzene (HBB) [1,1':2',1''-Terphenyl, 4,4''-dibromo-3',4',5',6'-tetrakis(4-Bromophenyl)-]

Rathore, R., Burns, C. L., Denmark, S. E. & Fujimori, S., Jan 1 2005, In : Organic Syntheses. 82, p. 30-33 4 p.

Research output: Contribution to journalArticle

Benzene

Sequential cross-coupling of 1,4-bissilylbutadienes: Synthesis of unsymmetrical 1,4-disubstituted 1,3-butadienes

Denmark, S. E. & Tymonko, S. A., Jun 8 2005, In : Journal of the American Chemical Society. 127, 22, p. 8004-8005 2 p.

Research output: Contribution to journalArticle

Butadiene
electron
Electrons
halide
1,3-butadiene

Synthesis of 3,4,5-trisubstituted isoxazoles via sequential [3 + 2] cycloaddition/silicon-based cross-coupling reactions

Denmark, S. E. & Kallemeyn, J. M., Apr 1 2005, In : Journal of Organic Chemistry. 70, 7, p. 2839-2842 4 p.

Research output: Contribution to journalArticle

Isoxazoles
Cycloaddition
Silicon
Nitriles
Ethers

Synthesis of 3-pyridylboronic acid and its pinacol ester. Application of 3-pyridylboronic acid in suzuki coupling to prepare 3-pyridin-3-ylquinoline [quinoline, 3-(3-pyridinyl)-]

Li, W., Nelson, D. P., Jensen, M. S., Scott Hoerrner, R., Cai, D., Larsen, R. D., Denmark, S. E., Halvorsen, G. T. & Kallemeyn, J. M., Jan 1 2005, In : Organic Syntheses. 81, p. 89-97 9 p.

Research output: Contribution to journalArticle

Esters
Acids
quinoline

Synthesis of cis,cis,cis,cis-[5.5.5.4]-1-azafenestrane with discovery of an unexpected dyotropic rearrangement

Denmark, S. E. & Montgomery, J. I., Jun 13 2005, In : Angewandte Chemie - International Edition. 44, 24, p. 3732-3736 5 p.

Research output: Contribution to journalArticle

Cycloaddition
Carbon
Derivatives
X rays
Atoms

Total synthesis of RK-397

Denmark, S. E. & Fujimori, S., Jun 29 2005, In : Journal of the American Chemical Society. 127, 25, p. 8971-8973 3 p.

Research output: Contribution to journalArticle

palladium
carbon
Polyenes
Polyols
Macrolides
2004
Cross Reactions
Aldehydes
Electrons
phosphoramide
3-hydroxybutanal
Cross Reactions
palladium
Palladium
kinetics
Kinetics

Fluoride-Promoted Cross-Coupling Reactions of Alkenylsilanols. Elucidation of the Mechanism through Spectroscopic and Kinetic Analysis

Denmark, S. E., Sweis, R. F. & Wehrli, D., Apr 21 2004, In : Journal of the American Chemical Society. 126, 15, p. 4865-4875 11 p.

Research output: Contribution to journalArticle

Cross Reactions
Fluorides
fluoride
Palladium
palladium

Lewis base activation of Lewis acids: Vinylogous aldol additions of silyl dienol ethers to aldehydes

Denmark, S. E. & Heemstra, J. R., Nov 3 2004, In : Synlett. 13, p. 2411-2416 6 p.

Research output: Contribution to journalArticle

Lewis Bases
Lewis Acids
Ethers
Aldehydes
Chemical activation

Palladium-catalyzed cross-coupling reactions of 2-indolyldimethylsilanols with substituted aryl halides

Denmark, S. E. & Baird, J. D., Sep 30 2004, In : Organic Letters. 6, 20, p. 3649-3652 4 p.

Research output: Contribution to journalArticle

cross coupling
Cross Reactions
Palladium
Iodides
iodides

Palladium-catalyzed cross-coupling reactions of substituted aryl(dimethyl)silanols

Denmark, S. E. & Ober, M. H., Dec 1 2004, In : Advanced Synthesis and Catalysis. 346, 13-15, p. 1703-1714 12 p.

Research output: Contribution to journalArticle

Palladium
Cesium
Electrons
Iodides
Bromides
Siloxanes
Ethers
Cross Reactions
Styrenes
Bearings (structural)

Total synthesis of (+)-brasilenyne. Application of an intramolecular silicon-assisted cross-coupling reaction

Denmark, S. E. & Yang, S. M., Oct 6 2004, In : Journal of the American Chemical Society. 126, 39, p. 12432-12440 9 p.

Research output: Contribution to journalArticle

Cross Reactions
Silicon
silicon
Acids
acid
2003

2-Silyloxy-1,2-oxazines, a New Type of Acetals of Conjugated Nitroso Alkenes

Tishkov, A. A., Lesiv, A. V., Khomutova, Y. A., Strelenko, Y. A., Nesterov, I. D., Antipin, M. Y., Ioffe, S. L. & Denmark, S. E., Nov 28 2003, In : Journal of Organic Chemistry. 68, 24, p. 9477-9480 4 p.

Research output: Contribution to journalArticle

Oxazines
Acetals
Alkenes
Oxides
Oximes

Catalytic enantioselective addition of allylic organometallic reagents to aldehydes and ketones

Denmark, S. E. & Fu, J., Aug 1 2003, In : Chemical reviews. 103, 8, p. 2763-2793 31 p.

Research output: Contribution to journalArticle

Allylation
Organometallics
Ketones
Aldehydes
Lewis Acids

Catalytic enantioselective allylation with chiral Lewis bases

Denmark, S. E. & Fu, J., Feb 4 2003, In : Chemical Communications. 9, 2, p. 167-170 4 p.

Research output: Contribution to journalArticle

Lewis Bases
Allylation
Aldehydes
Alcohols
Catalysts

Cross-Coupling of Alkynylsilanols with Aryl Halides Promoted by Potassium Trimethylsilanolate

Denmark, S. E. & Tymonko, S. A., Nov 14 2003, In : Journal of Organic Chemistry. 68, 23, p. 9151-9154 4 p.

Research output: Contribution to journalArticle

Iodides
Fluorides
Alkynes
Palladium
Silicon

Cross-coupling reactions of arylsilanols with substituted aryl halides

Denmark, S. E. & Ober, M. H., Apr 17 2003, In : Organic Letters. 5, 8, p. 1357-1360 4 p.

Research output: Contribution to journalArticle

cross coupling
Cross Reactions
Palladium
Iodides
Bromides

Generation and [2+2] cycloadditions of thio-substituted ketenes: trans-1-(4-methoxyphenyl)-4-phenyl-3-(phenylthio)azetidin-2-one [(2-azetidinone, 1-(4-methoxyphenyl)-4-phenyl-3-(phenylthio)-, trans-)]

Danheiser, R. L., Okamoto, I., Lawlor, M. D., Lee, T. W., Denmark, S. E. & Ober, M. H., Jan 1 2003, In : Organic Syntheses. 80, p. 160-171 12 p.

Research output: Contribution to journalArticle

ketenes
Cycloaddition
cycloaddition
2-azetidinone