Scott E Denmark

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Research Output

2008

(S)-5-Pyrrolidin-2-yl-1H-tetrazole

Aureggi, V., Franckeviius, V., Kitching, M. O., Ley, S. V., Longbottom, D. A., Oelke, A. J., Sedelmeier, G., Denmark, S. E. & Smith, R. C., Jan 1 2008, Organic Syntheses. Wiley Blackwell, p. 72-87 16 p. (Organic Syntheses; vol. 85).

Research output: Chapter in Book/Report/Conference proceedingChapter

Asymmetric synthesis of the ABCD ring system of daphnilactone B via a tandem, double intramolecular, [4+2]/[3+2] cycloaddition strategy

Denmark, S. E., Nguyen, S. T. & Baiazitov, R. Y., 2008, In : Heterocycles. 76, 1, p. 143-154 12 p.

Research output: Contribution to journalArticle

Asymmetrie catalysis with Chiral Lewis bases: A new frontier in main group chemistry

Denmark, S. E., Mar 24 2008, In : Chimia. 62, 1-2, p. 37-40 4 p.

Research output: Contribution to journalArticle

Benzyl isopropoxymethyl carbamate - An aminomethylating reagent for mannich reactions of titanium enolates

Meyer, H., Beck, A. K., Sebesta, R., Seebach, D., Denmark, S. E. & Wilson, T. W., Jan 1 2008, Organic Syntheses. Wiley-Blackwell, p. 287-294 8 p. (Organic Syntheses; vol. 85).

Research output: Chapter in Book/Report/Conference proceedingChapter

Chapter 1 Total synthesis of RK-397

Denmark, S. E. & Fujimori, S., Dec 1 2008, In : Strategies and Tactics in Organic Synthesis. 7, C, p. 1-34 34 p.

Research output: Contribution to journalArticle

Cross-coupling of aromatic bromides with allylic silanolate salts

Denmark, S. E. & Werner, N. S., Dec 3 2008, In : Journal of the American Chemical Society. 130, 48, p. 16382-16393 12 p.

Research output: Contribution to journalArticle

Investigations into transition-state geometry in the Mukaiyama directed aldol reaction

Denmark, S. E. & Lee, W., Feb 1 2008, In : Chemistry - An Asian Journal. 3, 2, p. 327-341 15 p.

Research output: Contribution to journalArticle

Lewis base activation of Lewis acids: Catalytic enantioselective glycolate aldol reactions

Denmark, S. E. & Chung, W. J., Feb 22 2008, In : Angewandte Chemie - International Edition. 47, 10, p. 1890-1892 3 p.

Research output: Contribution to journalArticle

Lewis base catalysis in organic synthesis

Denmark, S. E. & Beutner, G. L., Feb 15 2008, In : Angewandte Chemie - International Edition. 47, 9, p. 1560-1638 79 p.

Research output: Contribution to journalReview article

Organic syntheses. Volume 85, 2008

Denmark, S. E., 2008, Hoboken, N, J: Wiley.

Research output: Book/Report/Conference proceedingBook

Palladium-catalyzed cross-coupling of five-membered heterocyclic silanolates

Denmark, S. E., Baird, J. D. & Regens, C. S., Feb 15 2008, In : Journal of Organic Chemistry. 73, 4, p. 1440-1455 16 p.

Research output: Contribution to journalArticle

Palladium-catalyzed cross-coupling reactions of organosilanols and their salts: Practical alternatives to boron- and tin-based methods

Denmark, S. E. & Regens, C. S., Nov 1 2008, In : Accounts of chemical research. 41, 11, p. 1486-1499 14 p.

Research output: Contribution to journalReview article

Studies on the bisoxazoline- and (-)-sparteine-mediated enantioselective addition of organolithium reagents to imines

Denmark, S. E., Nakajima, N., Stiff, C. M., Nicaise, O. J. C. & Kranz, M., May 5 2008, In : Advanced Synthesis and Catalysis. 350, 7-8, p. 1023-1045 23 p.

Research output: Contribution to journalArticle

Synthesis and resolution of racemic trans-2-(N-benzyl)amino-1-cyclohexanol: Enantiomer separation by sequential use of (R)- and (S)-Mandelic acid: [cyclohexanol, 2-(N-benzyl)amino, (1S,2S)- and (1R,2R)-]

Schiffers, I., Bolm, C., Denmark, S. E., Woerly, E., Toussaint, A. & Pfaltz, A., Jan 1 2008, Organic Syntheses. Wiley Blackwell, p. 106-117 12 p. (Organic Syntheses; vol. 85).

Research output: Chapter in Book/Report/Conference proceedingChapter

Synthesis of 2-substituted biaryls via Cu/Pd-catalyzed decarboxylative cross-coupling of 2-substituted potassium benzoates: 4-Methyl-2'-nitrobiphenyl and 2-acetyl-4'-methylbiphenyl: [Biphenyl, 4-Methyl-2’-nitro-] [Biphenyl, 4-Methyl-2’-acetyl-]

Gooßen, L. J., Rodríguez, N., Linder, C., Zimmermann, B., Knauber, T., Denmark, S. E. & Werner, N. S., Jan 1 2008, Organic Syntheses. Wiley Blackwell, p. 196-208 13 p. (Organic Syntheses; vol. 85).

Research output: Chapter in Book/Report/Conference proceedingChapter

Total synthesis of papulacandin D

Kobayashi, T., Regens, C. S. & Denmark, S. E., Jun 2008, In : Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry. 66, 6, p. 616-628 13 p.

Research output: Contribution to journalArticle

Vinylation of aromatic halides using inexpensive organosilicon reagents. Illustration of design of experiment protocols

Denmark, S. E. & Butler, C. R., Mar 19 2008, In : Journal of the American Chemical Society. 130, 11, p. 3690-3704 15 p.

Research output: Contribution to journalArticle

2007

1-(4-acetylphenyl)-2-phenylethane from potassium 2-phenethyltrifluoroborate and 4-bromoacetophenone

Molander, G. A., Petrillo, D. E., Denmark, S. E. & Eggertswyler, C., Jan 1 2007, Organic Syntheses. Wiley Blackwell, p. 317-324 8 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

Carbonylative ring opening of terminal epoxides at atmospheric pressure

Denmark, S. E. & Ahmad, M., Dec 7 2007, In : Journal of Organic Chemistry. 72, 25, p. 9630-9634 5 p.

Research output: Contribution to journalArticle

Enantioselective construction of quaternary stereogenic carbons by the Lewis base catalyzed additions of silyl ketene imines to aldehydes

Denmark, S. E., Wilson, T. W., Burk, M. T. & Heemstra, J. R., Dec 5 2007, In : Journal of the American Chemical Society. 129, 48, p. 14864-14865 2 p.

Research output: Contribution to journalArticle

Enantioselective ring opening of epoxides with silicon tetrachloride in the presence of a chiral lewis base: Mechanism studies

Denmark, S. E., Barsanti, P. A., Beutner, G. L. & Wilson, T. W., Mar 2007, In : Advanced Synthesis and Catalysis. 349, 4-5, p. 567-582 16 p.

Research output: Contribution to journalArticle

Generation of ynolate and Z-selective olefination of acylsilanes: (Z)-2-methyl-3-trimethylsilyl-2-butenoic acid: ((Z)-2-butenoic acid, 2-methyl-3-trimethylsilyl-)

Shindo, M., Matsumoto, K., Shishido, K., Denmark, S. E. & Eklov, B. M., Jan 1 2007, Organic Syntheses. Wiley Blackwell, p. 11-21 11 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

Introduction to the series

Denmark, S. E., Feb 27 2007, Topics in Stereochemistry. Wiley, p. vii

Research output: Chapter in Book/Report/Conference proceedingForeword/postscript

Introduction to the series

Denmark, S. E., Feb 27 2007, Topics in Stereochemistry. Wiley, p. vii

Research output: Chapter in Book/Report/Conference proceedingForeword/postscript

Lewis acid-promoted conjugate addition of dienol silyl ethers to nitroalkenes: Synthesis of 3-substituted azepanes

Denmark, S. E. & Xie, M., Aug 31 2007, In : Journal of Organic Chemistry. 72, 18, p. 7050-7053 4 p.

Research output: Contribution to journalArticle

Lewis base activation of lewis acids: Development of a lewis base catalyzed selenolactonization

Denmark, S. E. & Collins, W. R., Sep 13 2007, In : Organic Letters. 9, 19, p. 3801-3804 4 p.

Research output: Contribution to journalArticle

Lewis base activation of Lewis acids: Catalytic, enantioselective vinylogous aldol addition reactions

Denmark, S. E. & Heemstra, J. R., Jul 20 2007, In : Journal of Organic Chemistry. 72, 15, p. 5668-5688 21 p.

Research output: Contribution to journalArticle

One-flask synthesis of methyl arylvinyldiazoacetates and their application in enantioselective C–H functionalization: synthesis of (E)-methyl 2-diazo-4-phenylbut-3-enoate and (S,E)methyl 2-((R)-4-methyl-1,2-dihydronaphthalen-2-YL)-4-phenylbut-3-enoate

Manning, J. R., Davies, H. M. L., Denmark, S. E. & Collins, W. R., Jan 1 2007, Organic Syntheses. Wiley Blackwell, p. 334-346 13 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

Phosphine oxides as stabilizing ligands for the palladium-catalyzed cross-coupling of potassium aryldimethylsilanolates

Denmark, S. E., Smith, R. C. & Tymonko, S. A., Jun 25 2007, In : Tetrahedron. 63, 26, p. 5730-5738 9 p.

Research output: Contribution to journalArticle

Preface

Denmark, S. E., Feb 27 2007, Topics in Stereochemistry. Wiley, p. xi-xii

Research output: Chapter in Book/Report/Conference proceedingForeword/postscript

Preface

Denmark, S. E., Feb 27 2007, Topics in Stereochemistry. Wiley, p. xi-xii

Research output: Chapter in Book/Report/Conference proceedingForeword/postscript

Preparation of a carbazole-based macrocycle via precipitation-driven alkyne metathesis

Zhang, W., Cho, H. M., Moore, J. S., Denmark, S. E. & Butler, C. R., Jan 1 2007, Organic Syntheses. Wiley-Blackwell, p. 177-191 15 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

Sequential silylcarbocyclization/silicon-based cross-coupling reactions

Denmark, S. E. & Liu, J. H. C., Mar 28 2007, In : Journal of the American Chemical Society. 129, 12, p. 3737-3744 8 p.

Research output: Contribution to journalArticle

Synthesis of acylsilanes from morpholine amides. Synthesis of 1-(dimethyl(phenyl)silyl)propan-1-one [dimethyl(1-oxopropyl)phenylsilane]

Lettan, R. B., Milgram, B. C., Scheidt, K. A., Denmark, S. E. & Baiazitov, R. Y., Jan 1 2007, Organic Syntheses. Wiley-Blackwell, p. 22-31 10 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

Synthesis of electron-deficient secondary phosphine oxides and secondary phosphines: Bis[3,5bis(trifluoromethyl)phenyl]phosphine oxide and bis[3,5-bis(trifluoromethyl)phenyl]phosphine

Busacca, C. A., Lorenz, J. C., Sabila, P., Haddad, N., Senandyake, C. H., Denmark, S. E. & Regens, C. S., 2007, Organic Syntheses. Wiley-Blackwell, p. 242-261 20 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

Synthesis of terminal 1,3-diynes via sonogashira coupling of vinylidene chloride followed by elimination. preparation of 1,3-decadiyne

Kohnen, A. L., Danheiser, R. L., Denmark, S. E. & Liu, X., Jan 1 2007, Organic Syntheses. Wiley-Blackwell, p. 77-87 11 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

Synthesis of ynamides by N-alkynylation of amine derivatives. Preparation of N-allyl-N-(methoxycarbonyl)-1,3-decadiynylamine

Kohnen, A. L., Dunetz, J. R., Danheiser, R. L., Denmark, S. E. & Liu, X., Jan 1 2007, Organic Syntheses. Wiley-Blackwell, p. 88-101 14 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

Topics in Stereochemistry

Denmark, S. E., Feb 27 2007, Wiley. 314 p.

Research output: Book/Report/Conference proceedingBook

Total synthesis of papulacandin D

Denmark, S. E., Regens, C. S. & Kobayashi, T., Mar 14 2007, In : Journal of the American Chemical Society. 129, 10, p. 2774-2776 3 p.

Research output: Contribution to journalArticle

Unexpected ambidoselectivity in crossed-aldol reactions of α-oxy aldehyde trichlorosilyl enolates

Denmark, S. E. & Ghosh, S. K., Aug 27 2007, In : Tetrahedron. 63, 35, p. 8636-8644 9 p.

Research output: Contribution to journalArticle

2006

(R,R)-2,2'-bispyrrolidine and (S,S)-2,2'-bispyrrolidine: Useful ligands for asymmetric synthesis

Denmark, S. E., Fu, J., Lawler, M. J., Lee, S., Huntsman, E. & Grabowski, E. J. J., Jan 1 2006, In : Organic Syntheses. 83, p. 121-130 10 p.

Research output: Contribution to journalArticle

A general synthesis of N-vinyl nitrones

Denmark, S. E. & Montgomery, J. I., Aug 1 2006, In : Journal of Organic Chemistry. 71, 16, p. 6211-6220 10 p.

Research output: Contribution to journalArticle

A qualitative examination of the effects of silicon substituents on the efficiency of cross-coupling reactions

Denmark, S. E., Neuville, L., Christy, M. E. L. & Tymonko, S. A., Oct 27 2006, In : Journal of Organic Chemistry. 71, 22, p. 8500-8509 10 p.

Research output: Contribution to journalArticle

A tandem, nitroalkene conjugate addition/[3+2] cycloaddition approach to the synthesis of the pentacyclic core of (±)-scandine

Denmark, S. E. & Cottell, J. J., Nov 1 2006, In : Advanced Synthesis and Catalysis. 348, 16-17, p. 2397-2402 6 p.

Research output: Contribution to journalArticle

Chiral phosphoramide-catalyzed aldol additions of ketone trichlorosilyl enolates. Mechanistic aspects

Denmark, S. E., Pham, S. M., Stavenger, R. A., Su, X., Wong, K. T. & Nishigaichi, Y., May 12 2006, In : Journal of Organic Chemistry. 71, 10, p. 3904-3922 19 p.

Research output: Contribution to journalArticle

Chiral phosphoramide-catalyzed enantioselective addition of allylic trichlorosilanes to aldehydes. Preparative and mechanistic studies with monodentate phosphorus-based amides

Denmark, S. E., Fu, J., Coe, D. M., Su, X., Pratt, N. E. & Griedel, B. D., Feb 17 2006, In : Journal of Organic Chemistry. 71, 4, p. 1513-1522 10 p.

Research output: Contribution to journalArticle