Scott E Denmark

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Research Output

Article

Cross-coupling reactions of arylsilanols with substituted aryl halides

Denmark, S. E. & Ober, M. H., Apr 17 2003, In : Organic Letters. 5, 8, p. 1357-1360 4 p.

Research output: Contribution to journalArticle

Cross-coupling with organosilicon compounds

Chang, W. T. T., Smith, R. C., Regens, C. S., Bailey, A. D., Werner, N. S. & Denmark, S. E., Dec 1 2011, In : Organic Reactions. 75, 1, p. 213-745 533 p.

Research output: Contribution to journalArticle

Cyclopropanation with Diazomethane and Bis(oxazoline)palladium(II) Complexes

Denmark, S. E., Stavenger, R. A., Faucher, A. M. & Edwards, J. P., 1997, In : Journal of Organic Chemistry. 62, 10, p. 3370-3374 5 p.

Research output: Contribution to journalArticle

Deconstructing quinine. Part 1. Toward an understanding of the remarkable performance of cinchona alkaloids in asymmetric phase transfer catalysis

Denmark, S. E. & Weintraub, R. C., Feb 28 2010, In : Heterocycles. 82, 2, p. 1527-1540 14 p.

Research output: Contribution to journalArticle

Demystifying the asymmetry-amplifying, autocatalytic behaviour of the Soai reaction through structural, mechanistic and computational studies

Athavale, S. V., Simon, A., Houk, K. N. & Denmark, S. E., Apr 1 2020, In : Nature Chemistry. 12, 4, p. 412-423 12 p.

Research output: Contribution to journalArticle

Design, validation, and implementation of a rapid-injection NMR system

Denmark, S. E., Williams, B. J., Eklov, B. M., Pham, S. M. & Beutner, G. L., Aug 20 2010, In : Journal of Organic Chemistry. 75, 16, p. 5558-5572 15 p.

Research output: Contribution to journalArticle

Design and implementation of new, silicon-based, cross-coupling reactions: Importance of silicon-oxygen bonds

Denmark, S. E. & Sweis, R. F., Oct 2002, In : Accounts of chemical research. 35, 10, p. 835-846 12 p.

Research output: Contribution to journalArticle

Development of a Computer-Guided Workflow for Catalyst Optimization. Descriptor Validation, Subset Selection, and Training Set Analysis

Henle, J. J., Zahrt, A. F., Rose, B. T., Darrow, W. T., Wang, Y. & Denmark, S. E., Jul 1 2020, In : Journal of the American Chemical Society. 142, 26, p. 11578-11592 15 p.

Research output: Contribution to journalArticle

Development of a Phase-Transfer-Catalyzed, [2,3]-Wittig Rearrangement

Denmark, S. E. & Cullen, L. R., Oct 2 2015, In : Journal of Organic Chemistry. 80, 23, p. 11818-11848 31 p.

Research output: Contribution to journalArticle

Development of chiral bis-hydrazone ligands for the enantioselective cross-coupling reactions of aryldimethylsilanolates

Denmark, S. E., Chang, W. T. T., Houk, K. N. & Liu, P., Jan 1 2015, In : Journal of Organic Chemistry. 80, 1, p. 313-366 54 p.

Research output: Contribution to journalArticle

Diastereoselective aldol addition reactions of a chiral methyl ketone trichlorosilyl enolate under lewis base catalysis

Denmark, S. E. & Fujimori, S., 2001, In : Synlett. SPEC. ISS, p. 1024-1029 6 p.

Research output: Contribution to journalArticle

Open Access

Diastereoselective aldol additions of chiral β-hydroxy ethyl ketone enolates catalyzed by Lewis bases

Denmark, S. E. & Fujimori, S., Oct 3 2002, In : Organic Letters. 4, 20, p. 3473-3476 4 p.

Research output: Contribution to journalArticle

Diphenylmethylsilyl Ether (DPMS): A Protecting Group for Alcohols

Denmark, S. E., Hammer, R. P., Weber, E. J. & Habermas, K. L., Jan 1 1987, In : Journal of Organic Chemistry. 52, 1, p. 165-168 4 p.

Research output: Contribution to journalArticle

Dynamically Chiral Helical Polymers: A New Frontier in Asymmetric Catalysis?

Denmark, S. E., Jul 24 2019, In : ACS Central Science. 5, 7, p. 1117-1119 3 p.

Research output: Contribution to journalArticle

Open Access

Effects of charge separation, effective concentration, and aggregate formation on the phase transfer catalyzed alkylation of phenol

Denmark, S. E., Weintraub, R. C. & Gould, N. D., Aug 15 2012, In : Journal of the American Chemical Society. 134, 32, p. 13415-13429 15 p.

Research output: Contribution to journalArticle

Efficient and stereoselective cross-coupling with highly substituted alkenylsilanols

Denmark, S. E. & Pan, W., Jul 1 2002, In : Journal of Organometallic Chemistry. 653, 1-2, p. 98-104 7 p.

Research output: Contribution to journalArticle

Elucidating the Role of the Boronic Esters in the Suzuki-Miyaura Reaction: Structural, Kinetic, and Computational Investigations

Thomas, A. A., Zahrt, A. F., Delaney, C. P. & Denmark, S. E., Mar 28 2018, In : Journal of the American Chemical Society. 140, 12, p. 4401-4416 16 p.

Research output: Contribution to journalArticle

Enantio- and Diastereoselective, Lewis Base Catalyzed, Cascade Sulfenoacetalization of Alkenyl Aldehydes

Matviitsuk, A. & Denmark, S. E., Jan 1 2019, In : Angewandte Chemie - International Edition. 58, 36, p. 12486-12490 5 p.

Research output: Contribution to journalArticle

Enantioselective, lewis base-catalyzed, intermolecular sulfenoamination of alkenes

Roth, A. & Denmark, S. E., Sep 4 2019, In : Journal of the American Chemical Society. 141, 35, p. 13767-13771 5 p.

Research output: Contribution to journalArticle

Enantioselective, Lewis Base-Catalyzed Carbosulfenylation of Alkenylboronates by 1,2-Boronate Migration

Tao, Z., Robb, K. A., Panger, J. L. & Denmark, S. E., Nov 21 2018, In : Journal of the American Chemical Society. 140, 46, p. 15621-15625 5 p.

Research output: Contribution to journalArticle

Enantioselective, Lewis Base-Catalyzed Sulfenocyclization of Polyenes

Tao, Z., Robb, K. A., Zhao, K. & Denmark, S. E., Mar 14 2018, In : Journal of the American Chemical Society. 140, 10, p. 3569-3573 5 p.

Research output: Contribution to journalArticle

Enantioselective bromocycloetherification by Lewis base/chiral Brønsted acid cooperative catalysis

Denmark, S. E. & Burk, M. T., Jan 6 2012, In : Organic Letters. 14, 1, p. 256-259 4 p.

Research output: Contribution to journalArticle

Enantioselective construction of quaternary stereogenic carbon atoms by the lewis base catalyzed additions of silyl ketene imines to aldehydes

Denmark, S. E., Wilson, T. W. & Burk, M. T., Jul 21 2014, In : Chemistry - A European Journal. 20, 30, p. 9268-9279 12 p.

Research output: Contribution to journalArticle

Enantioselective construction of quaternary stereogenic carbons by the Lewis base catalyzed additions of silyl ketene imines to aldehydes

Denmark, S. E., Wilson, T. W., Burk, M. T. & Heemstra, J. R., Dec 5 2007, In : Journal of the American Chemical Society. 129, 48, p. 14864-14865 2 p.

Research output: Contribution to journalArticle

Enantioselective Cyclopropanation of Allylic Alcohols. The Effect of Zinc Iodide

Denmark, S. E. & O'Connor, S. P., 1997, In : Journal of Organic Chemistry. 62, 10, p. 3375-3389 15 p.

Research output: Contribution to journalArticle

Enantioselective ring opening of epoxides with silicon tetrachloride in the presence of a chiral lewis base: Mechanism studies

Denmark, S. E., Barsanti, P. A., Beutner, G. L. & Wilson, T. W., Mar 2007, In : Advanced Synthesis and Catalysis. 349, 4-5, p. 567-582 16 p.

Research output: Contribution to journalArticle

Enantioselective Ring Opening of Epoxides with Silicon Tetrachloride in the Presence of a Chiral Lewis Base

Denmark, S. E., Barsanti, P. A., Wong, K. T. & Stavenger, R. A., Apr 17 1998, In : Journal of Organic Chemistry. 63, 8, p. 2428-2429 2 p.

Research output: Contribution to journalArticle

Enantioselective synthesis of alkylidene cyclohexanes by an asymmetric olefination/cross‐coupling sequence

Denmark, S. E. & Chen, CT. T., Jan 1 1995, In : Heteroatom Chemistry. 6, 2, p. 133-144 12 p.

Research output: Contribution to journalArticle

Enantioselective Synthesis of γ-Lactams by Lewis Base Catalyzed Sulfenoamidation of Alkenes

Panger, J. L. & Denmark, S. E., Apr 3 2020, In : Organic Letters. 22, 7, p. 2501-2505 5 p.

Research output: Contribution to journalArticle

Enantioselective total syntheses of (+)-castanospermine, (+)-6- epicastanospermine, (+)-australine, and (+)-3-epiaustraline

Denmark, S. E. & Martinborough, E. A., Apr 7 1999, In : Journal of the American Chemical Society. 121, 13, p. 3046-3056 11 p.

Research output: Contribution to journalArticle

Evaluating continuous chirality measure as a 3D descriptor in chemoinformatics applied to asymmetric catalysis

Zahrt, A. F. & Denmark, S. E., Mar 29 2019, In : Tetrahedron. 75, 13, p. 1841-1851 11 p.

Research output: Contribution to journalArticle

ExCage

Dale, E. J., Vermeulen, N. A., Thomas, A. A., Barnes, J. C., Juríček, M., Blackburn, A. K., Strutt, N. L., Sarjeant, A. A., Stern, C. L., Denmark, S. E. & Stoddart, J. F., Jul 30 2014, In : Journal of the American Chemical Society. 136, 30, p. 10669-10682 14 p.

Research output: Contribution to journalArticle

Facile Oxetane Formation in a Rigid Bicyclo[2.2.2]octane System

Denmark, S. E., Jul 1981, In : Journal of Organic Chemistry. 46, 15, p. 3144-3147 4 p.

Research output: Contribution to journalArticle

Fluoride-Promoted Cross-Coupling Reactions of Alkenylsilanols. Elucidation of the Mechanism through Spectroscopic and Kinetic Analysis

Denmark, S. E., Sweis, R. F. & Wehrli, D., Apr 21 2004, In : Journal of the American Chemical Society. 126, 15, p. 4865-4875 11 p.

Research output: Contribution to journalArticle

Formation of γ-keto esters from β-keto esters: Methyl 5,5-dimethyl-4-oxohexanoate: [Hexanoic acid, 5,5-dimethyl-4-oxo-, methyl ester]

Ronsheim, M. D., Hilgenkamp, R. K., Zercher, C. K., Denmark, S. E. & Beutner, G. L., Jan 1 2002, In : Organic Syntheses. 79, 1 p.

Research output: Contribution to journalArticle

Generation and [2+2] cycloadditions of thio-substituted ketenes: trans-1-(4-methoxyphenyl)-4-phenyl-3-(phenylthio)azetidin-2-one [(2-azetidinone, 1-(4-methoxyphenyl)-4-phenyl-3-(phenylthio)-, trans-)]

Danheiser, R. L., Okamoto, I., Lawlor, M. D., Lee, T. W., Denmark, S. E. & Ober, M. H., Jan 1 2003, In : Organic Syntheses. 80, p. 160-171 12 p.

Research output: Contribution to journalArticle

Generation and cyclization of 5-hexenyllithium: 2-cyclopentylacetophenone: (ethanone, 2-cyclopentyl-1-phenyl-)

Bailey, W. F., Luderer, M. R., Mealy, M. J., Punzalan, E. R., Denmark, S. E. & Macneil, S. L., Jan 1 2005, In : Organic Syntheses. 81, p. 121-133 13 p.

Research output: Contribution to journalArticle

Highly 1,4-syn diastereoselective, phosphoramide-catalyzed aldol additions of chiral methyl ketone enolates

Denmark, S. E. & Stavenger, R. A., Dec 11 1998, In : Journal of Organic Chemistry. 63, 25, p. 9524-9527 4 p.

Research output: Contribution to journalArticle

Highly diastereoselective aldol additions of a chiral ethyl ketone enolate under Lewis base catalysis

Denmark, S. E. & Pham, S. M., Jul 12 2001, In : Organic Letters. 3, 14, p. 2201-2204 4 p.

Research output: Contribution to journalArticle

Highly stereoselective hydrocarbation of terminal alkynes via Pt-Catalyzed Hydrosilylation/Pd-Catalyzed cross-coupling reactions

Denmark, S. E. & Wang, Z., Apr 5 2001, In : Organic Letters. 3, 7, p. 1073-1076 4 p.

Research output: Contribution to journalArticle

Highly stereospecific, cross-coupling reactions of alkenylsilacyclobutanes

Denmark, S. E. & Choi, J. Y., Jun 23 1999, In : Journal of the American Chemical Society. 121, 24, p. 5821-5822 2 p.

Research output: Contribution to journalArticle

Highly stereospecific, palladium-catalyzed cross-coupling of alkenylsilanols

Denmark, S. E. & Wehrli, D., Feb 24 2000, In : Organic Letters. 2, 4, p. 565-568 4 p.

Research output: Contribution to journalArticle

Inter- and intramolecular [4+2] cycloaddition of nitroalkenes with allenylsilanes. A case of unexpected regioselectivity

Denmark, S. E. & Gomez, L., Nov 22 2002, In : Heterocycles. 58, p. 129-136 8 p.

Research output: Contribution to journalArticle

Inter-and Intramolecular [4 + 2] Cycloadditions of Nitroalkenes with Olefins. 2-Nitrostyrenes

Denmark, S. E., Kesler, B. S. & Moon, Y. C., Aug 1 1992, In : Journal of Organic Chemistry. 57, 18, p. 4912-4924 13 p.

Research output: Contribution to journalArticle

Intermolecular [4 + 2]‐Cycloadditions of Nitroalkenes with Cyclic Olefins. Transformations of Cyclic Nitronates

Denmark, S. E., Cramer, C. J. & Sternberg, J. A., Dec 10 1986, In : Helvetica Chimica Acta. 69, 8, p. 1971-1989 19 p.

Research output: Contribution to journalArticle

Intramolecular [4 + 2] cycloaddition of nitroalkenes for construction of vicinal quaternary stereocenters

Denmark, S. E. & Baiazitov, R. Y., Dec 8 2005, In : Organic Letters. 7, 25, p. 5617-5620 4 p.

Research output: Contribution to journalArticle