Scott E Denmark

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Research Output

1994

Stereochemical Studies on the Addition of Allylstannanes to Aldehydes. The SE′Component

Denmark, S. E. & Hosoi, S., Sep 1 1994, In : Journal of Organic Chemistry. 59, 18, p. 5133-5135 3 p.

Research output: Contribution to journalArticle

Structure and Dynamics of Phosphorus(V)-Stabilized Carbanions: A Comparison of Theoretical, Crystallographic, and Solution Structures

Cramer, C. J., Denmark, S. E., Miller, P. C., Dorow, R. L., Swiss, K. A. & Wilson, S. R., Mar 1 1994, In : Journal of the American Chemical Society. 116, 6, p. 2437-2447 11 p.

Research output: Contribution to journalArticle

The tandem cycloaddition chemistry of nitroalkenes

Denmark, S. E., Schnute, M. E., Thorarensen, A., Middleton, D. S. & Stolle, A., Jan 1 1994, In : Pure and Applied Chemistry. 66, 10-11, p. 2041-2044 4 p.

Research output: Contribution to journalArticle

The Tandem Cycloaddition Chemistry of Nitroalkenes. A Novel Synthesis of (−)-Hastanecine

Denmark, S. E. & Thorarensen, A., Sep 1 1994, In : Journal of Organic Chemistry. 59, 19, p. 5672-5680 9 p.

Research output: Contribution to journalArticle

Triarylcarbenium ions as catalysts in the Mukaiyama Aldol addition: A mechanistic investigation

Denmark, S. E. & Chen, C. T., Jun 20 1994, In : Tetrahedron Letters. 35, 25, p. 4327-4330 4 p.

Research output: Contribution to journalArticle

1995

A General Strategy for the Synthesis of Cis-Substituted Pyrrolizidine Bases. The Synthesis of (-)-Rosmarinecine

Denmark, S. E., Thorarensen, A. & Middleton, D. S., Jun 1 1995, In : Journal of Organic Chemistry. 60, 12, p. 3574-3575 2 p.

Research output: Contribution to journalArticle

Alkylations of Chiral, Phosphoryl- and Thiophosphoryl-Stabilized Carbanions

Denmark, S. E. & Chen, C. T., Jan 1 1995, In : Journal of the American Chemical Society. 117, 48, p. 11879-11897 19 p.

Research output: Contribution to journalArticle

Asymmetric [2,3]-Wittig rearrangements with chiral, phosphorus anion-stabilizing groups

Denmark, S. E. & Miller, P. C., Jan 1 1995, In : Tetrahedron Letters. 36, 37, p. 6631-6634 4 p.

Research output: Contribution to journalArticle

Asymmetric Michael Addition Reaction of Phosphorus-Stabilized Allyl Anions with Cyclic Enones

Denmark, S. E. & Kim, J. H., Nov 1 1995, In : Journal of Organic Chemistry. 60, 23, p. 7535-7547 13 p.

Research output: Contribution to journalArticle

Asymmetric Nitroalkene [4 + 2] Cycloadditions: Enantioselective Synthesis of 3-Substituted and 3,4-Disubstituted Pyrrolidines

Denmark, S. E. & Marcin, L. R., May 1 1995, In : Journal of Organic Chemistry. 60, 10, p. 3221-3235 15 p.

Research output: Contribution to journalArticle

Catalytic enantioselective cyclopropanation with bis(halomethyl)zinc reagents. I. Optimization of reaction protocol

Denmark, S. E., Christenson, B. L., Coe, D. M. & O'Connor, S. P., Mar 27 1995, In : Tetrahedron Letters. 36, 13, p. 2215-2218 4 p.

Research output: Contribution to journalArticle

Catalytic enantioselective cyclopropanation with bis(halomethyl)zinc reagents. II. The effect of promoter structure on selectivity

Denmark, S. E., Christenson, B. L. & O'Connor, S. P., Mar 27 1995, In : Tetrahedron Letters. 36, 13, p. 2219-2222 4 p.

Research output: Contribution to journalArticle

Catalytic Epoxidation of Alkenes with Oxone

Denmark, S. E., Forbes, D. C., Hays, D. S., DePue, J. S. & Wilde, R. G., Mar 1 1995, In : Journal of Organic Chemistry. 60, 5, p. 1391-1407 17 p.

Research output: Contribution to journalArticle

Enantioselective synthesis of alkylidene cyclohexanes by an asymmetric olefination/cross‐coupling sequence

Denmark, S. E. & Chen, CT. T., Jan 1 1995, In : Heteroatom Chemistry. 6, 2, p. 133-144 12 p.

Research output: Contribution to journalArticle

Nitroalkene Inter [4 + 2]/Intra [3 + 2] Tandem Cycloadditions. 7. Application of (R)-(-)-2,2-Diphenylcyclopentanol as the Chiral Auxiliary

Denmark, S. E., Schnute, M. E., Marcin, L. R. & Thorarensen, A., May 1 1995, In : Journal of Organic Chemistry. 60, 10, p. 3205-3220 16 p.

Research output: Contribution to journalArticle

Palladium-Promoted Intramolecular Addition of an Aryl Iodide to a Nitroalkene

Denmark, S. E. & Schnute, M. E., Feb 1 1995, In : Journal of Organic Chemistry. 60, 4, p. 1013-1019 7 p.

Research output: Contribution to journalArticle

Preparation of Chiral Bisoxazolines: Observations on the Effect of Substituents

Denmark, S. E., Nakajima, N., Nicaise, O. J. C., Faucher, A. M. & Edwards, J. P., Jul 1 1995, In : Journal of Organic Chemistry. 60, 15, p. 4884-4892 9 p.

Research output: Contribution to journalArticle

Tandem Inter [4 + 2]/Intra [3 + 2] Cycloadditions. 6. The Bridged Model

Denmark, S. E., Stolle, A., Dixon, J. A. & Guagnano, V., Jan 1 1995, In : Journal of the American Chemical Society. 117, 7, p. 2100-2101 2 p.

Research output: Contribution to journalArticle

An ab initio study of the P-C bond rotation in phosphoryl- and thiophosphoryl-stabilized carbanions: Five- and six-membered heterocycles

Kranz, M., Denmark, S. E., Swiss, K. A. & Wilson, S. R., Nov 29 1996, In : Journal of Organic Chemistry. 61, 24, p. 8551-8563 13 p.

Research output: Contribution to journalArticle

Chemistry of trichlorosilyl enolates. 1. New reagents for catalytic, asymmetric aldol additions

Denmark, S. E., Winter, S. B. D., Su, X. & Wong, K. T., Aug 7 1996, In : Journal of the American Chemical Society. 118, 31, p. 7404-7405 2 p.

Research output: Contribution to journalArticle

Ligand-mediated addition of organometallic reagents to azomethine functions

Denmark, S. E. & Nicaise, O. J. C., Jan 1 1996, In : Chemical Communications. 9, p. 999-1004 6 p.

Research output: Contribution to journalArticle

New vistas in organoelement chemistry

Denmark, S. E., Christenson, B. L., O'Connor, S. P. & Murase, N., Jan 1996, In : Pure and Applied Chemistry. 68, 1, p. 23-27 5 p.

Research output: Contribution to journalArticle

Solution and solid-state structure of a lithiated phosphane oxide

Denmark, S. E., Swiss, K. A. & Wilson, S. R., Jan 1 1996, In : Angewandte Chemie (International Edition in English). 35, 21, p. 2515-2517 3 p.

Research output: Contribution to journalArticle

Tandem [4+2]/[3+2] cycloadditions of nitroalkenes

Denmark, S. E. & Thorarensen, A., 1996, In : Chemical reviews. 96, 1, p. 137-165 29 p.

Research output: Contribution to journalArticle

Tandem [4 + 2]/[3 + 2] cycloadditions of nitroalkenes. 10. Trans-2-(1-methyl-1-phenylethyl)cyclohexanol as a new auxiliary

Denmark, S. E. & Thorarensen, A., Sep 20 1996, In : Journal of Organic Chemistry. 61, 19, p. 6727-6729 3 p.

Research output: Contribution to journalArticle

Tandem [4+2]/[3+2] cycloadditions of nitroalkenes. 9. Synthesis of (-)-rosmarinecine

Denmark, S. E., Thorarensen, A. & Middleton, D. S., Sep 4 1996, In : Journal of the American Chemical Society. 118, 35, p. 8266-8277 12 p.

Research output: Contribution to journalArticle

Tandem inter [4+2]/intra [3+2] cycloadditions. 8. Cycloadditions with unactivated dipolarophiles

Denmark, S. E. & Senanayake, C. B. W., Aug 26 1996, In : Tetrahedron. 52, 35, p. 11579-11600 22 p.

Research output: Contribution to journalArticle

1997

(R)-(-)-2,2-diphenylcyclopentanol

Denmark, S. E., Marcin, L. R., Schnute, M. E. & Thorarensen, A., Jan 1 1997, In : Organic Syntheses. 74, 1 p.

Research output: Contribution to journalArticle

Catalytic, Enantioselective Cyclopropanation of Allylic Alcohols. Substrate Generality

Denmark, S. E. & O'Connor, S. P., Jan 1 1997, In : Journal of Organic Chemistry. 62, 3, p. 584-594 11 p.

Research output: Contribution to journalArticle

Catalytic Epoxidation of Alkenes with Oxone. 2. Flupro Ketones

Denmark, S. E., Wu, Z., Crudden, C. M. & Matsuhashi, H., 1997, In : Journal of Organic Chemistry. 62, 24, p. 8288-8289 2 p.

Research output: Contribution to journalArticle

Cyclopropanation with Diazomethane and Bis(oxazoline)palladium(II) Complexes

Denmark, S. E., Stavenger, R. A., Faucher, A. M. & Edwards, J. P., 1997, In : Journal of Organic Chemistry. 62, 10, p. 3370-3374 5 p.

Research output: Contribution to journalArticle

Enantioselective Cyclopropanation of Allylic Alcohols. The Effect of Zinc Iodide

Denmark, S. E. & O'Connor, S. P., 1997, In : Journal of Organic Chemistry. 62, 10, p. 3375-3389 15 p.

Research output: Contribution to journalArticle

Tandem [4 + 2]/[3 + 2] cycloadditions of nitroalkenes. 11. The synthesis of (+)-crotanecine

Denmark, S. E. & Thorarensen, A., Jan 8 1997, In : Journal of the American Chemical Society. 119, 1, p. 125-137 13 p.

Research output: Contribution to journalArticle

Tandem [4 + 2]/[3 + 2] cycloadditions of nitroalkenes. 12. Synthesis of (-)-platynecine

Denmark, S. E., Parker, J. & Dixon, J. A., Jan 1 1997, In : Journal of Organic Chemistry. 62, 2, p. 435-436 2 p.

Research output: Contribution to journalArticle

Tandem [4 + 2]/[3 + 2] cycloadditions of nitroalkenes. 13. The synthesis of (-)-detoxinine

Denmark, S. E., Hurd, A. R. & Sacha, H. J., Jan 1 1997, In : Journal of Organic Chemistry. 62, 6, p. 1668-1674 7 p.

Research output: Contribution to journalArticle

Tandem Inter [4 + 2]/Intra [3 + 2] Cycloadditions of Nitroalkenes. 15. The Bridged Mode (α-Tether)

Denmark, S. E., Guagnano, V., Dixon, J. A. & Stolle, A., Jan 1 1997, In : Journal of Organic Chemistry. 62, 14, p. 4610-4628 19 p.

Research output: Contribution to journalArticle

The Chemistry of Chlorosilyl Enolates 3. Variation of the Silyl Group and the Effect on Rate and Enantiomeric Excess of Acetate Aldol Additions

Denmark, S. E. & Winter, S. B. D., Jan 1 1997, In : Synlett. 1997, 9, p. 1087-1089 3 p.

Research output: Contribution to journalArticle

The chemistry of trichlorosilyl enolates. 2. Highly-selective asymmetric aldol additions of ketone enolates

Denmark, S. E., Wong, K. T. & Stavenger, R. A., Jan 1 1997, In : Journal of the American Chemical Society. 119, 9, p. 2333-2334 2 p.

Research output: Contribution to journalArticle

1998

Asymmetric aldol additions catalyzed by chiral phosphoramides: Electronic effects of the aldehyde component

Denmark, S. E., Stavenger, R. A. & Wong, K. T., Aug 27 1998, In : Tetrahedron. 54, 35, p. 10389-10402 14 p.

Research output: Contribution to journalArticle

Asymmetric catalysis with chiral Lewis bases

Denmark, S. E., Stavenger, R. A., Su, X., Wong, K. T. & Nishigaichi, Y., Aug 1998, In : Pure and Applied Chemistry. 70, 8, p. 1469-1476 8 p.

Research output: Contribution to journalArticle

Enantioselective Ring Opening of Epoxides with Silicon Tetrachloride in the Presence of a Chiral Lewis Base

Denmark, S. E., Barsanti, P. A., Wong, K. T. & Stavenger, R. A., Apr 17 1998, In : Journal of Organic Chemistry. 63, 8, p. 2428-2429 2 p.

Research output: Contribution to journalArticle

Highly 1,4-syn diastereoselective, phosphoramide-catalyzed aldol additions of chiral methyl ketone enolates

Denmark, S. E. & Stavenger, R. A., Dec 11 1998, In : Journal of Organic Chemistry. 63, 25, p. 9524-9527 4 p.

Research output: Contribution to journalArticle

Lewis Base-Catalyzed, Asymmetric Aldol Additions of Methyl Ketone Enolates

Denmark, S. E., Stavenger, R. A. & Wong, K. T., Feb 20 1998, In : Journal of Organic Chemistry. 63, 4, p. 918-919 2 p.

Research output: Contribution to journalArticle

Preparation of chlorosilyl enolates

Denmark, S. E., Stavenger, R. A., Winter, S. B. D., Wong, K. T. & Barsanti, P. A., Dec 11 1998, In : Journal of Organic Chemistry. 63, 25, p. 9517-9523 7 p.

Research output: Contribution to journalArticle