Scott E Denmark

1975 …2019
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Research Output 1975 2019

2011
Ammonium Compounds
Catalyst activity
Ions
Catalysts
Catalysis

Catalytic asymmetric thiofunctionalization of unactivated alkenes

Denmark, S. E., Kornfilt, D. J. P. & Vogler, T., Oct 5 2011, In : Journal of the American Chemical Society. 133, 39, p. 15308-15311 4 p.

Research output: Contribution to journalArticle

Styrenes
Furans
Nucleophiles
alkene
Alkenes
Cross Reactions
Palladium

Cross-coupling with organosilicon compounds

Chang, W. T. T., Smith, R. C., Regens, C. S., Bailey, A. D., Werner, N. S. & Denmark, S. E., Dec 1 2011, In : Organic Reactions. 75, 1, p. 213-745 533 p.

Research output: Contribution to journalArticle

cross coupling

Probing the electronic demands of transmetalation in the palladium-catalyzed cross-coupling of arylsilanolates

Denmark, S. E., Smith, R. C. & Chang, W. T. T., Jun 17 2011, In : Tetrahedron. 67, 24, p. 4391-4396 6 p.

Research output: Contribution to journalArticle

Palladium
Electrons
Nucleophiles
Cross Reactions
Silicon

Stereocontrolled total syntheses of isodomoic acids G and H via a unified strategy

Denmark, S. E., Liu, J. H. C. & Muhuhi, J. M., Jan 7 2011, In : Journal of Organic Chemistry. 76, 1, p. 201-215 15 p.

Research output: Contribution to journalArticle

Iodides
Silicon
Rhodium
Cyclization
Molecules
cross coupling
Bromides
adducts
bromides
Salts
2010
Lewis Bases
Imines
Ketones
Aldehydes
Carbon

Deconstructing quinine. Part 1. Toward an understanding of the remarkable performance of cinchona alkaloids in asymmetric phase transfer catalysis

Denmark, S. E. & Weintraub, R. C., Feb 28 2010, In : Heterocycles. 82, 2, p. 1527-1540 14 p.

Research output: Contribution to journalArticle

Cinchona Alkaloids
Quinine
Catalysis
Hydroxyl Radical
Catalysts

Design, validation, and implementation of a rapid-injection NMR system

Denmark, S. E., Williams, B. J., Eklov, B. M., Pham, S. M. & Beutner, G. L., Aug 20 2010, In : Journal of Organic Chemistry. 75, 16, p. 5558-5572 15 p.

Research output: Contribution to journalArticle

Nuclear magnetic resonance
Nuclear magnetic resonance spectroscopy
Chemical reactions
Temperature
Syringes
Cross Reactions
iodide
Iodides
Fluorides

Lewis base catalysis of bromo- and iodolactonization, and cycloetherification

Denmark, S. E. & Burk, M. T., Nov 30 2010, In : Proceedings of the National Academy of Sciences of the United States of America. 107, 48, p. 20655-20660 6 p.

Research output: Contribution to journalArticle

Lewis Bases
Cyclization
Catalysis
Ions
Fluorobenzenes
Cross Reactions
palladium
Palladium
Catalysis

N-silyl oxyketene imines are underused yet highly versatile reagents for catalytic asymmetric synthesis

Denmark, S. E. & Wilson, T. W., Nov 1 2010, In : Nature Chemistry. 2, 11, p. 937-943 7 p.

Research output: Contribution to journalArticle

Imines
Benzoin
Anions
Negative ions
glycolic acid

On the absolute configurational stability of bromonium and chloronium ions

Denmark, S. E., Burk, M. T. & Hoover, A. J., Feb 3 2010, In : Journal of the American Chemical Society. 132, 4, p. 1232-1233 2 p.

Research output: Contribution to journalArticle

Alkenes
Olefins
Ions
ion
alkene

On the stereochemical course of palladium-catalyzed cross-coupling of allylic silanolate salts with aromatic bromides

Denmark, S. E. & Werner, N. S., Mar 17 2010, In : Journal of the American Chemical Society. 132, 10, p. 3612-3620 9 p.

Research output: Contribution to journalArticle

palladium
Palladium
Bromides
bromide
Salts

Organocerium additions to proline-derived hydrazones: Synthesis of enantiomerically enriched amines

Denmark, S. E., Edwards, J. P., Weber, T. & Piotrowski, D. W., May 17 2010, In : Tetrahedron Asymmetry. 21, 9-10, p. 1278-1302 25 p.

Research output: Contribution to journalArticle

Bearings (structural)
Hydrazones
hydrazones
Proline
Amines

Palladium-catalyzed cross-coupling of five-membered heterocyclic silanolates

Denmark, S. E., Baird, J. & Regens, C., Mar 2010, In : Chemtracts. 23, 2, p. 41-46 6 p.

Research output: Contribution to journalReview article

Cross Reactions
Palladium
Alkali Metals
Iodides
Derivatives

Preface to special issue of heterocycles honoring the 85th birthday of prof. Dr. Albert eschenmoser

Denmark, S. E. & Sorensen, E. J., Dec 1 2010, In : Heterocycles. 82, 1, p. 5-10 6 p.

Research output: Contribution to journalReview article

Preparative and mechanistic studies toward the rational development of catalytic, enantioselective selenoetherification reactions

Denmark, S. E., Kalyani, D. & Collins, W. R., Nov 10 2010, In : Journal of the American Chemical Society. 132, 44, p. 15752-15765 14 p.

Research output: Contribution to journalArticle

Lewis Bases
Olefins
racemization
Alkenes
Selenium

Sequential processes in palladium-catalyzed silicon-based cross-coupling

Denmark, S. E. & Liu, J. H. C., Dec 1 2010, In : Israel Journal of Chemistry. 50, 5-6, p. 577-587 11 p.

Research output: Contribution to journalReview article

Palladium
Silicon
Substrates
Biological Products
Toxicity

Silicon-based cross-coupling reactions in the total synthesis of natural products

Denmark, S. E. & Liu, J. H. C., Apr 12 2010, In : Angewandte Chemie - International Edition. 49, 17, p. 2978-2986 9 p.

Research output: Contribution to journalReview article

Silicon
Biological Products
Carbon
Transition metals
Molecules

Total synthesis of (+)-papulacandin D

Denmark, S. E., Kobayashi, T. & Regens, C. S., Jun 26 2010, In : Tetrahedron. 66, 26, p. 4745-4759 15 p.

Research output: Contribution to journalArticle

Lewis Bases
Cross Reactions
Palladium
Iodides
Unsaturated Fatty Acids
2009

Catalytic, nucleophilic allylation of aldehydes with allyl acetate

Denmark, S. E. & Nguyen, S. T., Feb 5 2009, In : Organic Letters. 11, 3, p. 781-784 4 p.

Research output: Contribution to journalArticle

Allylation
aldehydes
Aldehydes
acetates
Carbon Monoxide

Cross-coupling reactions of aromatic and heteroaromatic silanolates with aromatic and heteroaromatic halides

Denmark, S. E., Smith, R. C., Chang, W. T. T. & Muhuhi, J. M., Mar 4 2009, In : Journal of the American Chemical Society. 131, 8, p. 3104-3118 15 p.

Research output: Contribution to journalArticle

Ethers
halide
Cross Reactions
ether
Chlorides

Low pressure carbonylation of epoxides to β-lactones

Kramer, J. W., Treitler, D. S., Coates, G. W., Denmark, S. E. & Hoover, A. J., Dec 1 2009, In : Organic Syntheses. 86, p. 287-297 11 p.

Research output: Contribution to journalArticle

epoxy compounds
low pressure

Observation of direct sulfenium and selenenium group transfer from thiiranium and seleniranium ions to alkenes

Denmark, S. E., Collins, W. R. & Cullen, M. D., Mar 18 2009, In : Journal of the American Chemical Society. 131, 10, p. 3490-3492 3 p.

Research output: Contribution to journalArticle

alkene
Alkenes
Olefins
Observation
Ions

On the mechanism of Lewis base catalyzed aldol addition reactions: Kinetic and spectroscopic investigations using rapid-injection NMR

Denmark, S. E., Eklov, B. M., Yao, P. J. & Eastgate, M. D., Aug 26 2009, In : Journal of the American Chemical Society. 131, 33, p. 11770-11787 18 p.

Research output: Contribution to journalArticle

Lewis Bases
Addition reactions
reaction kinetics
silicon
nuclear magnetic resonance

Organic reactions

Denmark, S. E., 2009, Oxford: Wiley-Blackwell.

Research output: Book/ReportBook

Organic reactions. Vol. 73

Denmark, S. E., 2009, Oxford: Wiley-Blackwell.

Research output: Book/ReportBook

Organic reactions. Volume 74

Denmark, S. E., 2009, Oxford: Wiley-Blackwell.

Research output: Book/ReportBook

Palladium- (and nickel-) catalyzed vinylation of aryl halides

Denmark, S. E. & Butler, C. R., Jan 1 2009, In : Chemical Communications. 1, p. 20-33 14 p.

Research output: Contribution to journalReview article

Styrenes
Palladium
Nickel
Styrene
Functional polymers

Preparation of 2,3-disubstituted indoles by sequential Larock heteroannulation and silicon-based cross-coupling reactions

Denmark, S. E. & Baird, J. D., Apr 18 2009, In : Tetrahedron. 65, 16, p. 3120-3129 10 p.

Research output: Contribution to journalArticle

Indoles
Cross Reactions
Silicon
Ether
Bromides

Protection of diols with 4-(tert-Butyldimethylsilyloxy)Benzylidene acetal and its deprotection: (4-((4R,5R)-4,5-diphenyl-1,3-dioxolan-2-yl)phenoxy) (tertbutyl)dimethylsilane

Osajima, H., Fujiwara, H., Okano, K., Tokuyama, H., Fukuyama, T., Denmark, S. E. & Chang, W. T. T., Dec 1 2009, In : Organic Syntheses. 86, p. 130-140 11 p.

Research output: Contribution to journalArticle

acetals

Stereochemical studies on the addition of allylsilanes to aldehydes. The SE' component

Denmark, S. E. & Almstead, N. G., Jul 1 2009, In : Journal of the Mexican Chemical Society. 53, 3, p. 174-192 19 p.

Research output: Contribution to journalArticle

Aldehydes
Cyclization
Lewis Acids
Deuterium
Silicon

Synthesis and reactivity of enantiomerically enriched thiiranium ions

Denmark, S. E. & Vogler, T., Nov 2 2009, In : Chemistry - A European Journal. 15, 43, p. 11737-11745 9 p.

Research output: Contribution to journalArticle

Ions
Lewis Bases
Nucleophiles
Alkenes
Sulfides

Synthesis of 2-arylindole-4-carboxylic amides: [2(4-Fluorophenyl)-1H-indol- 4-yl]-1-pyrrolidinylmethanone

Kuethe, J. T., Beutner, G. L., Denmark, S. E. & Muhuhi, J. M., Dec 1 2009, In : Organic Syntheses. 86, p. 92-104 13 p.

Research output: Contribution to journalArticle

Amides
amides
synthesis

Tandem double intramolecular [4+2]/[3+2] cycloadditions of nitroalkenes: construction of the pentacyclic core structure of daphnilactone B

Denmark, S. E., Baiazitov, R. Y. & Nguyen, S. T., Aug 15 2009, In : Tetrahedron. 65, 33, p. 6535-6548 14 p.

Research output: Contribution to journalArticle

Acetals
Cycloaddition
Cycloaddition Reaction
Hydrogenolysis
Hydrogenation

The interplay of invention, discovery, development, and application in organic synthetic methodology: A case study

Denmark, S. E., Apr 17 2009, In : Journal of Organic Chemistry. 74, 8, p. 2915-2927 13 p.

Research output: Contribution to journalReview article

Patents and inventions
Palladium
Silicon
Biological Products
Derivatives

Total syntheses of isodomoic acids G and H

Denmark, S. E., Liu, J. H. C. & Muhuhi, J. M., Oct 14 2009, In : Journal of the American Chemical Society. 131, 40, p. 14188-14189 2 p.

Research output: Contribution to journalArticle

Halogenation
Silicon
Rhodium
silicon
Acids

Vinylation with inexpensive silicon-based reagents: Preparation of 3-vinylquinoline and 4-vinylbenzophenone

Denmark, S. E., Butler, C. R., Pfaltz, A. & Woodmansee, D. H., Dec 1 2009, In : Organic Syntheses. 86, p. 274-286 13 p.

Research output: Contribution to journalArticle

reagents
preparation
silicon
2008

(R)-2,2’-Binaphthoyl-(S,S)-di(1-phenylethyl) aminophosphine. Scalable protocols for the syntheses of phosphoramidite (feringa) ligands

Smith, C. R., Mans, D. J., RajanBabu, T. V., Denmark, S. E. & Nguyen, T., Jan 1 2008, Organic Syntheses. Wiley Blackwell, p. 238-247 10 p. (Organic Syntheses; vol. 85).

Research output: Chapter in Book/Report/Conference proceedingChapter

ligands
synthesis

(R)-2-(benzyloxycarbonylamino-methyl)-3-phenylpropanoic acid (Z-2hPHE-OH): Preparation of A 2-amino acid with the auxiliary dioz

Müller-Hartwieg, J. C. D., Vecchia, L. L., Meyer, H., Beck, A. K., Seebach, D., Denmark, S. E., Duncan-Gould, N. & Hoover, A., Jan 1 2008, Organic Syntheses. Wiley Blackwell, p. 295-306 12 p. (Organic Syntheses; vol. 85).

Research output: Chapter in Book/Report/Conference proceedingChapter

Amino Acids
3-phenylpropionic acid

(S)-5-Pyrrolidin-2-yl-1H-tetrazole

Aureggi, V., Franckeviius, V., Kitching, M. O., Ley, S. V., Longbottom, D. A., Oelke, A. J., Sedelmeier, G., Denmark, S. E. & Smith, R. C., Jan 1 2008, Organic Syntheses. Wiley Blackwell, p. 72-87 16 p. (Organic Syntheses; vol. 85).

Research output: Chapter in Book/Report/Conference proceedingChapter

tetrazoles

Asymmetric synthesis of the ABCD ring system of daphnilactone B via a tandem, double intramolecular, [4+2]/[3+2] cycloaddition strategy

Denmark, S. E., Nguyen, S. T. & Baiazitov, R. Y., Dec 1 2008, In : Heterocycles. 76, 1, p. 143-154 12 p.

Research output: Contribution to journalArticle

Acetals
Cycloaddition
Cycloaddition Reaction
Hydrogenolysis
Hydrogenation

Asymmetrie catalysis with Chiral Lewis bases: A new frontier in main group chemistry

Denmark, S. E., Mar 24 2008, In : Chimia. 62, 1-2, p. 37-40 4 p.

Research output: Contribution to journalArticle

Lewis Bases
Catalysis
Chemical reactivity
Electrons
Chemical reactions

Benzyl isopropoxymethyl carbamate - An aminomethylating reagent for mannich reactions of titanium enolates

Meyer, H., Beck, A. K., Sebesta, R., Seebach, D., Denmark, S. E. & Wilson, T. W., Jan 1 2008, Organic Syntheses. Wiley Blackwell, p. 287-294 8 p. (Organic Syntheses; vol. 85).

Research output: Chapter in Book/Report/Conference proceedingChapter

reagents
titanium

Chapter 1 Total synthesis of RK-397

Denmark, S. E. & Fujimori, S., Dec 1 2008, In : Strategies and Tactics in Organic Synthesis. 7, C, p. 1-34 34 p.

Research output: Contribution to journalArticle

Lewis Bases
Polyenes
Acetals
Macrolides
Aldehydes