Scott E Denmark

1975 …2019
If you made any changes in Pure, your changes will be visible here soon.

Research Output 1975 2019

2016

Reactions of epoxides (n → σ*)

Wilson, T. W. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1113-1151 39 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Epoxy Compounds
Lewis Acids
Lewis Bases
Chemical activation
Reaction kinetics

Summation

Vedejs, E. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1351-1353 3 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Speech synthesis

Toward Catalytic, Enantioselective Chlorolactonization of 1,2-Disubstituted Styrenyl Carboxylic Acids

Denmark, S. E., Ryabchuk, P., Burk, M. T. & Gilbert, B. B., Nov 4 2016, In : Journal of Organic Chemistry. 81, 21, p. 10411-10423 13 p.

Research output: Contribution to journalArticle

Lewis Bases
Carboxylic Acids
Catalysis
Ions
Enantioselectivity
2015

Catalytic, Stereoselective Dihalogenation of Alkenes: Challenges and Opportunities

Cresswell, A. J., Eey, S. T. C. & Denmark, S. E., Dec 21 2015, In : Angewandte Chemie - International Edition. 54, 52, p. 15642-15682 41 p.

Research output: Contribution to journalReview article

Alkenes
Olefins
Bearings (structural)
Arsenals
Halogens

Catalytic, stereospecific syn-dichlorination of alkenes

Cresswell, A. J., Eey, S. T. C. & Denmark, S. E., Feb 2015, In : Nature Chemistry. 7, 2, p. 146-152 7 p.

Research output: Contribution to journalArticle

Alkenes
Olefins
Chlorides
Organic Chemicals
Bromine

Development of a Phase-Transfer-Catalyzed, [2,3]-Wittig Rearrangement

Denmark, S. E. & Cullen, L. R., Oct 2 2015, In : Journal of Organic Chemistry. 80, 23, p. 11818-11848 31 p.

Research output: Contribution to journalArticle

Catalysis
Carbonyl compounds
Catalysts
Enantioselectivity
Substrates

Development of chiral bis-hydrazone ligands for the enantioselective cross-coupling reactions of aryldimethylsilanolates

Denmark, S. E., Chang, W. T. T., Houk, K. N. & Liu, P., Jan 1 2015, In : Journal of Organic Chemistry. 80, 1, p. 313-366 54 p.

Research output: Contribution to journalArticle

Hydrazones
Enantioselectivity
Ligands
Glyoxal
Stereoselectivity

Mechanistic significance of the Si-O-Pd bond in the palladium-catalyzed cross-coupling reactions of alkenylsilanolates

Tymonko, S. A., Smith, R. C., Ambrosi, A. & Denmark, S. E., May 20 2015, In : Journal of the American Chemical Society. 137, 19, p. 6192-6199 8 p.

Research output: Contribution to journalArticle

Open Access
phosphine
cesium
Cross Reactions
palladium
Palladium

Mechanistic significance of the Si-O-Pd bond in the palladium-catalyzed cross-coupling reactions of arylsilanolates

Tymonko, S. A., Smith, R. C., Ambrosi, A., Ober, M. H., Wang, H. & Denmark, S. E., May 20 2015, In : Journal of the American Chemical Society. 137, 19, p. 6200-6218 19 p.

Research output: Contribution to journalArticle

Open Access
Cross Reactions
palladium
Palladium
phosphine
Hot Temperature

Preface to volume 86

Denmark, S. E., Jan 1 2015, In : Organic Reactions. 86, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 87

Denmark, S. E., Jan 1 2015, In : Organic Reactions. 87, 1, p. vii-ix

Research output: Contribution to journalEditorial

Preface to volume 88

Denmark, S. E., Jan 1 2015, In : Organic Reactions. 88, 1, p. vii-viii

Research output: Contribution to journalEditorial

Redefining q: Quaternary ammonium cross sectional area (XSA) as a general descriptor for transport-limiting PTC rate approximations

Denmark, S. E. & Henle, J. J., Apr 1 2015, In : Chemical Science. 6, 4, p. 2211-2218 8 p.

Research output: Contribution to journalArticle

Ammonium Compounds
Catalysis
Ions
Alkylation
Catalysts

Reinvestigation of a Catalytic, Enantioselective Alkene Dibromination and Chlorohydroxylation

Denmark, S. E. & Carson, N., Nov 13 2015, In : Organic Letters. 17, 23, p. 5728-5731 4 p.

Research output: Contribution to journalArticle

Enantioselectivity
Alkenes
Nuclear magnetic resonance spectroscopy
alkenes
High Pressure Liquid Chromatography

Why You Really Should Consider Using Palladium-Catalyzed Cross-Coupling of Silanols and Silanolates

Denmark, S. E. & Ambrosi, A., Jul 30 2015, In : Organic Process Research and Development. 19, 8, p. 982-994 13 p.

Research output: Contribution to journalArticle

cross coupling
Palladium
Silicon
palladium
Fluorides
2014

Asymmetric construction of quaternary stereogenic centers via auxiliary-based SN2′ reactions: A case of 1,7-relative stereogenesis

Denmark, S. E. & Marble, L. K., Jan 1 2014, In : Heterocycles. 88, 1, p. 559-590 32 p.

Research output: Contribution to journalArticle

Carbamates
Enantioselectivity
Alkenes
Substitution reactions
Substrates
Lewis Bases
Alkenes
catalysis
Catalysis
Olefins

Catalytic, enantioselective, intramolecular carbosulfenylation of olefins. preparative and stereochemical aspects

Denmark, S. E. & Jaunet, A., Jan 3 2014, In : Journal of Organic Chemistry. 79, 1, p. 140-171 32 p.

Research output: Contribution to journalArticle

Alkenes
Enantioselectivity
Nucleophiles
Electrons
Acids

Catalytic, Enantioselective Sulfenylation of Ketone-Derived Enoxysilanes

Denmark, S. E., Rossi, S., Webster, M. P. & Wang, H., Sep 5 2014, In : Journal of the American Chemical Society. 136, 37, p. 13016-13028 13 p.

Research output: Contribution to journalArticle

Lewis Bases
Enantioselectivity
ketone
Ketones
ether
Allylation
Water gas shift
Aldehydes
Acetates
Carbon

Catalytic conjugate addition of acyl anion equivalents promoted by fluorodesilylation

Denmark, S. E. & Cullen, L. R., Jan 3 2014, In : Organic Letters. 16, 1, p. 70-73 4 p.

Research output: Contribution to journalArticle

Anions
anions
Ketones
reaction time
ketones
Lewis Bases
Chirality
Catalysis
Catalysts
Kinetics

Enantioselective construction of quaternary stereogenic carbon atoms by the lewis base catalyzed additions of silyl ketene imines to aldehydes

Denmark, S. E., Wilson, T. W. & Burk, M. T., Jul 21 2014, In : Chemistry - A European Journal. 20, 30, p. 9268-9279 12 p.

Research output: Contribution to journalArticle

Lewis Bases
Imines
Aldehydes
Carbon
Enantioselectivity

ExCage

Dale, E. J., Vermeulen, N. A., Thomas, A. A., Barnes, J. C., Juríček, M., Blackburn, A. K., Strutt, N. L., Sarjeant, A. A., Stern, C. L., Denmark, S. E. & Stoddart, J. F., Jul 30 2014, In : Journal of the American Chemical Society. 136, 30, p. 10669-10682 14 p.

Research output: Contribution to journalArticle

Polycyclic Aromatic Hydrocarbons
Polycyclic aromatic hydrocarbons
PAH
Pyrene
Complexation

Lewis base catalyzed, enantioselective, intramolecular sulfenoamination of olefins

Denmark, S. E. & Chi, H. M., Jun 25 2014, In : Journal of the American Chemical Society. 136, 25, p. 8915-8918 4 p.

Research output: Contribution to journalArticle

Lewis Bases
alkene
Alkenes
Olefins
Pyrrolidines

Mechanistic, crystallographic, and computational studies on the catalytic, enantioselective sulfenofunctionalization of alkenes

Denmark, S. E., Hartmann, E., Kornfilt, D. J. P. & Wang, H., Dec 2014, In : Nature Chemistry. 6, 12, p. 1056-1064 9 p.

Research output: Contribution to journalArticle

Alkenes
Olefins
Carbon
Sulfur
Nitrogen

Preface to volume 83

Denmark, S. E., 2014, In : Organic Reactions. 83, 1, p. Vii-Viii

Research output: Contribution to journalEditorial

Preface to volume 84

Denmark, S. E., Jan 1 2014, In : Organic Reactions. 84, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 85

Denmark, S. E., Jan 1 2014, In : Organic Reactions. 85, 1, p. vii-viii

Research output: Contribution to journalEditorial

Tandem [4+2]/[3+2] Cycloadditions

Baiazitov, R. Y. & Denmark, S. E., Feb 10 2014, Methods and Applications of Cycloaddition Reactions in Organic Syntheses. Wiley Blackwell, Vol. 9781118299883. p. 471-550 80 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Cycloaddition
Biological Products
Molecules
2013
Acetaldehyde
acetaldehyde
Static Electricity
Chemical activation
Electrostatics

Carbanion-accelerated claisen rearrangements: Asymmetric induction with chiral phosphorus-stabilized anions

Denmark, S. E., Marlin, J. E. & Rajendra, G., Jan 4 2013, In : Journal of Organic Chemistry. 78, 1, p. 66-82 17 p.

Research output: Contribution to journalArticle

Phosphorus
Anions
Oxides
Metals
Temperature

Catalytic, enantioselective, intramolecular carbosulfenylation of olefins

Denmark, S. E. & Jaunet, A., May 1 2013, In : Journal of the American Chemical Society. 135, 17, p. 6419-6422 4 p.

Research output: Contribution to journalArticle

alkene
Alkenes
Olefins
Tetrahydronaphthalenes
Nucleophiles

Iron-catalyzed cross-coupling of unactivated secondary alkyl thio ethers and sulfones with aryl grignard reagents

Denmark, S. E. & Cresswell, A. J., Dec 20 2013, In : Journal of Organic Chemistry. 78, 24, p. 12593-12628 36 p.

Research output: Contribution to journalArticle

Sulfones
Ethers
Iron
Sulfur Compounds
Nucleophiles

Lewis base activation of Lewis acids: Group 13. in situ generation and reaction of borenium ions

Denmark, S. E. & Ueki, Y., Nov 25 2013, In : Organometallics. 32, 22, p. 6631-6634 4 p.

Research output: Contribution to journalArticle

Lewis Bases
Lewis Acids
Lewis base
Chemical activation
activation

Lewis base catalysis of the Mukaiyama directed aldol reaction: 40years of inspiration and advances

Beutner, G. L. & Denmark, S. E., Aug 26 2013, In : Angewandte Chemie - International Edition. 52, 35, p. 9086-9096 11 p.

Research output: Contribution to journalReview article

Lewis Bases
Addition reactions
Catalysis
Catalyst selectivity
Enantioselectivity

Organosilicon Compounds in Cross-Coupling Reactions

Denmark, S. E. & Sweis, R. F., Nov 30 2013, Metal Catalyzed Cross-Coupling Reactions and More. Wiley-VCH Verlag, Vol. 3. p. 475-532 58 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Fluorine compounds
Silicon compounds

Preface to volume 82

Denmark, S. E., 2013, In : Organic Reactions. 82, 1, p. Vii-Viii

Research output: Contribution to journalEditorial

The interplay of invention, observation, and discovery in the development of lewis base activation of lewis acids for catalytic enantioselective synthesis

Beutner, G. L. & Denmark, S. E., Jan 1 2013, Inventing Reactions. Goossen, L. (ed.). p. 55-89 35 p. (Topics in Organometallic Chemistry; vol. 44).

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Lewis Acids
Patents and inventions
Esters
Nucleophiles
2012

Catalytic, asymmetric halofunctionalization of alkenes-a critical perspective

Denmark, S. E., Kuester, W. E. & Burk, M. T., Oct 29 2012, In : Angewandte Chemie - International Edition. 51, 44, p. 10938-10953 16 p.

Research output: Contribution to journalReview article

Alkenes
Catalysis
Olefins
Halogenation
Halogens

Effects of charge separation, effective concentration, and aggregate formation on the phase transfer catalyzed alkylation of phenol

Denmark, S. E., Weintraub, R. C. & Gould, N. D., Aug 15 2012, In : Journal of the American Chemical Society. 134, 32, p. 13415-13429 15 p.

Research output: Contribution to journalArticle

Alkylation
catalysis
Phenol
Catalysis
Phenols

Enantioselective bromocycloetherification by Lewis base/chiral Brønsted acid cooperative catalysis

Denmark, S. E. & Burk, M. T., Jan 6 2012, In : Organic Letters. 14, 1, p. 256-259 4 p.

Research output: Contribution to journalArticle

Lewis Bases
Lewis base
Enantioselectivity
Cyclization
Catalysis

Lewis base catalyzed enantioselective additions of an N-silyl vinylketene imine

Denmark, S. E. & Wilson, T. W., Mar 26 2012, In : Angewandte Chemie - International Edition. 51, 13, p. 3236-3239 4 p.

Research output: Contribution to journalArticle

Lewis Bases
Stereoselectivity
Nitriles
Nucleophiles
Imines

On the stereochemical course of the addition of allylsilanes to aldehydes

Denmark, S. E., Weber, E. J., Almstead, N. G. & Wolf, L. M., Sep 16 2012, In : Tetrahedron. 68, 37, p. 7701-7718 18 p.

Research output: Contribution to journalArticle

Cyclization
Aldehydes
Lewis Acids
allylsilane

Organic reactions. Volume 76

Denmark, S. E., 2012, Hoboken, N, J: Wiley.

Research output: Book/ReportBook

Organic reactions. Volume 77

Denmark, S. E., 2012, Hoboken, N, J: Wiley-Blackwell.

Research output: Book/ReportBook

Organic reactions. Volume 78

Denmark, S. E., 2012, Hoboken, N, J: Wiley.

Research output: Book/ReportBook

Silyl ketene imines: Highly versatile nucleophiles for catalytic, asymmetric synthesis

Denmark, S. E. & Wilson, T. W., Oct 1 2012, In : Angewandte Chemie - International Edition. 51, 40, p. 9980-9992 13 p.

Research output: Contribution to journalReview article

Nucleophiles
Imines
Carbon
Benzoin
ketene

Total synthesis of papulacandin D

Kobayashi, T., Regens, C. S. & Denmark, S. E., 2012, Strategies and Tactics in Organic Synthesis. Academic Press Inc., p. 79-126 48 p. (Strategies and Tactics in Organic Synthesis; vol. 8).

Research output: Chapter in Book/Report/Conference proceedingChapter

Palladium
Biological Products
papulacandins
2011
Catalyst selectivity
Ammonium Compounds
Catalyst activity
Ions
Catalysts