Scott E Denmark

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Research Output

Enantioselective, lewis base-catalyzed, intermolecular sulfenoamination of alkenes

Roth, A. & Denmark, S. E., Sep 4 2019, In : Journal of the American Chemical Society. 141, 35, p. 13767-13771 5 p.

Research output: Contribution to journalArticle

Enantio- and Diastereoselective, Lewis Base Catalyzed, Cascade Sulfenoacetalization of Alkenyl Aldehydes

Matviitsuk, A. & Denmark, S. E., Jan 1 2019, In : Angewandte Chemie - International Edition. 58, 36, p. 12486-12490 5 p.

Research output: Contribution to journalArticle

Elucidating the Role of the Boronic Esters in the Suzuki-Miyaura Reaction: Structural, Kinetic, and Computational Investigations

Thomas, A. A., Zahrt, A. F., Delaney, C. P. & Denmark, S. E., Mar 28 2018, In : Journal of the American Chemical Society. 140, 12, p. 4401-4416 16 p.

Research output: Contribution to journalArticle

Efficient and stereoselective cross-coupling with highly substituted alkenylsilanols

Denmark, S. E. & Pan, W., Jul 1 2002, In : Journal of Organometallic Chemistry. 653, 1-2, p. 98-104 7 p.

Research output: Contribution to journalArticle

Effects of charge separation, effective concentration, and aggregate formation on the phase transfer catalyzed alkylation of phenol

Denmark, S. E., Weintraub, R. C. & Gould, N. D., Aug 15 2012, In : Journal of the American Chemical Society. 134, 32, p. 13415-13429 15 p.

Research output: Contribution to journalArticle

Effect of ligand structure in the bisoxazoline mediated asymmetric addition of methyllithium to imines

Denmark, S. E. & Stiff, G. M., Sep 8 2000, In : Journal of Organic Chemistry. 65, 18, p. 5875-5878 4 p.

Research output: Contribution to journalComment/debate

Dynamically Chiral Helical Polymers: A New Frontier in Asymmetric Catalysis?

Denmark, S. E., Jul 24 2019, In : ACS Central Science. 5, 7, p. 1117-1119 3 p.

Research output: Contribution to journalArticle

Open Access

Diphenylmethylsilyl Ether (DPMS): A Protecting Group for Alcohols

Denmark, S. E., Hammer, R. P., Weber, E. J. & Habermas, K. L., Jan 1 1987, In : Journal of Organic Chemistry. 52, 1, p. 165-168 4 p.

Research output: Contribution to journalArticle

Diastereoselective aldol additions of chiral β-hydroxy ethyl ketone enolates catalyzed by Lewis bases

Denmark, S. E. & Fujimori, S., Oct 3 2002, In : Organic Letters. 4, 20, p. 3473-3476 4 p.

Research output: Contribution to journalArticle

Diastereoselective aldol addition reactions of a chiral methyl ketone trichlorosilyl enolate under lewis base catalysis

Denmark, S. E. & Fujimori, S., 2001, In : Synlett. SPEC. ISS, p. 1024-1029 6 p.

Research output: Contribution to journalArticle

Open Access

Development of chiral bis-hydrazone ligands for the enantioselective cross-coupling reactions of aryldimethylsilanolates

Denmark, S. E., Chang, W. T. T., Houk, K. N. & Liu, P., Jan 1 2015, In : Journal of Organic Chemistry. 80, 1, p. 313-366 54 p.

Research output: Contribution to journalArticle

Development of a Phase-Transfer-Catalyzed, [2,3]-Wittig Rearrangement

Denmark, S. E. & Cullen, L. R., Oct 2 2015, In : Journal of Organic Chemistry. 80, 23, p. 11818-11848 31 p.

Research output: Contribution to journalArticle

Development of a Computer-Guided Workflow for Catalyst Optimization. Descriptor Validation, Subset Selection, and Training Set Analysis

Henle, J. J., Zahrt, A. F., Rose, B. T., Darrow, W. T., Wang, Y. & Denmark, S. E., 2020, (Accepted/In press) In : Journal of the American Chemical Society.

Research output: Contribution to journalArticle

Development and mechanistic investigation of the palladium-catalyzed α-arylation of aldehydes and N-arylation of ammonia

Vo, G. D., White, M. C., Hartwig, J. F., Denmark, S. E. & Girolami, G. S., 2011, Urbana, Il: University of Illinois.

Research output: Book/Report/Conference proceedingBook

Design and implementation of new, silicon-based, cross-coupling reactions: Importance of silicon-oxygen bonds

Denmark, S. E. & Sweis, R. F., Oct 2002, In : Accounts of chemical research. 35, 10, p. 835-846 12 p.

Research output: Contribution to journalArticle

Design, validation, and implementation of a rapid-injection NMR system

Denmark, S. E., Williams, B. J., Eklov, B. M., Pham, S. M. & Beutner, G. L., Aug 20 2010, In : Journal of Organic Chemistry. 75, 16, p. 5558-5572 15 p.

Research output: Contribution to journalArticle

Demystifying the asymmetry-amplifying, autocatalytic behaviour of the Soai reaction through structural, mechanistic and computational studies

Athavale, S. V., Simon, A., Houk, K. N. & Denmark, S. E., Apr 1 2020, In : Nature Chemistry. 12, 4, p. 412-423 12 p.

Research output: Contribution to journalArticle

Deconstructing quinine. Part 1. Toward an understanding of the remarkable performance of cinchona alkaloids in asymmetric phase transfer catalysis

Denmark, S. E. & Weintraub, R. C., Feb 28 2010, In : Heterocycles. 82, 2, p. 1527-1540 14 p.

Research output: Contribution to journalArticle

Cyclopropanation with Diazomethane and Bis(oxazoline)palladium(II) Complexes

Denmark, S. E., Stavenger, R. A., Faucher, A. M. & Edwards, J. P., 1997, In : Journal of Organic Chemistry. 62, 10, p. 3370-3374 5 p.

Research output: Contribution to journalArticle

Cross-coupling with organosilicon compounds

Chang, W. T. T., Smith, R. C., Regens, C. S., Bailey, A. D., Werner, N. S. & Denmark, S. E., Dec 1 2011, In : Organic Reactions. 75, 1, p. 213-745 533 p.

Research output: Contribution to journalArticle

Cross-coupling reactions of organosilicon compounds: New concepts and recent advances

Denmark, S. E. & Sweis, R. F., Dec 1 2002, In : Chemical and Pharmaceutical Bulletin. 50, 12, p. 1531-1541 11 p.

Research output: Contribution to journalReview article

Cross-coupling reactions of arylsilanols with substituted aryl halides

Denmark, S. E. & Ober, M. H., Apr 17 2003, In : Organic Letters. 5, 8, p. 1357-1360 4 p.

Research output: Contribution to journalArticle

Cross-coupling reactions of aromatic and heteroaromatic silanolates with aromatic and heteroaromatic halides

Denmark, S. E., Smith, R. C., Chang, W. T. T. & Muhuhi, J. M., Mar 4 2009, In : Journal of the American Chemical Society. 131, 8, p. 3104-3118 15 p.

Research output: Contribution to journalArticle

Cross-coupling reactions of alkenylsilanols with fluoroalkylsulfonates

Denmark, S. E. & Sweis, R. F., Oct 17 2002, In : Organic Letters. 4, 21, p. 3771-3774 4 p.

Research output: Contribution to journalArticle

Cross-coupling of vinylpolysiloxanes with aryl iodides

Denmark, S. E. & Wang, Z., Apr 1 2001, In : Journal of Organometallic Chemistry. 624, 1-2, p. 372-375 4 p.

Research output: Contribution to journalArticle

Cross-coupling of aromatic bromides with allylic silanolate salts

Denmark, S. E. & Werner, N. S., Dec 3 2008, In : Journal of the American Chemical Society. 130, 48, p. 16382-16393 12 p.

Research output: Contribution to journalArticle

Cross-Coupling of Alkynylsilanols with Aryl Halides Promoted by Potassium Trimethylsilanolate

Denmark, S. E. & Tymonko, S. A., Nov 14 2003, In : Journal of Organic Chemistry. 68, 23, p. 9151-9154 4 p.

Research output: Contribution to journalArticle

Convergence of mechanistic pathways in the palladium(0)-catalyzed cross-coupling of alkenylsilacyclobutanes and alkenylsilanols

Denmark, S. E., Wehrli, D. & Choi, J. Y., Aug 10 2000, In : Organic Letters. 2, 16, p. 2491-2494 4 p.

Research output: Contribution to journalArticle

Configuration, Conformation, and Colligative Properties of a Phosphorus-Stabilized Anion

Denmark, S. E., Miller, P. C. & Wilson, S. R., Jan 1 1991, In : Journal of the American Chemical Society. 113, 4, p. 1468-1470 3 p.

Research output: Contribution to journalArticle

Chiral phosphoramide-catalyzed enantioselective addition of allylic trichlorosilanes to aldehydes. Preparative and mechanistic studies with monodentate phosphorus-based amides

Denmark, S. E., Fu, J., Coe, D. M., Su, X., Pratt, N. E. & Griedel, B. D., Feb 17 2006, In : Journal of Organic Chemistry. 71, 4, p. 1513-1522 10 p.

Research output: Contribution to journalArticle

Chiral phosphoramide-catalyzed aldol additions of ketone trichlorosilyl enolates. Mechanistic aspects

Denmark, S. E., Pham, S. M., Stavenger, R. A., Su, X., Wong, K. T. & Nishigaichi, Y., May 12 2006, In : Journal of Organic Chemistry. 71, 10, p. 3904-3922 19 p.

Research output: Contribution to journalArticle

Chiral phosphoramide-catalyzed aldol additions of ketone enolates. Preparative aspects

Denmark, S. E., Stavenger, R. A., Wong, K. T. & Su, X., Jun 2 1999, In : Journal of the American Chemical Society. 121, 21, p. 4982-4991 10 p.

Research output: Contribution to journalArticle

Chiral fluoro ketones for catalytic asymmetric epoxidation of alkenes with oxone

Denmark, S. E. & Matsuhashi, H., May 17 2002, In : Journal of Organic Chemistry. 67, 10, p. 3479-3486 8 p.

Research output: Contribution to journalArticle

Chiral Amino Alcohol Modified Halomethylzinc Reagents

Denmark, S. E. & Edwards, J. P., Jan 1 1992, In : Synlett. 1992, 3, p. 229-230 2 p.

Research output: Contribution to journalArticle

Chemistry of trichlorosilyl enolates. 1. New reagents for catalytic, asymmetric aldol additions

Denmark, S. E., Winter, S. B. D., Su, X. & Wong, K. T., Aug 7 1996, In : Journal of the American Chemical Society. 118, 31, p. 7404-7405 2 p.

Research output: Contribution to journalArticle

Chemistry of Enoxysilacyclobutanes. 3. Uncatalyzed, Syn-Selective, Asymmetric Aldol Additions

Denmark, S. E. & Griedel, B. D., Sep 1 1994, In : Journal of Organic Chemistry. 59, 18, p. 5136-5138 3 p.

Research output: Contribution to journalArticle

Chemistry of Enoxysilacyclobutanes: Highly Selective Uncatalyzed Aldol Additions

Denmark, S. E., Griedel, B. D., Coe, D. M. & Schnute, M. E., Aug 1 1994, In : Journal of the American Chemical Society. 116, 16, p. 7026-7043 18 p.

Research output: Contribution to journalArticle

Chapter 1 Total synthesis of RK-397

Denmark, S. E. & Fujimori, S., Dec 1 2008, In : Strategies and Tactics in Organic Synthesis. 7, C, p. 1-34 34 p.

Research output: Contribution to journalArticle

Catalytic Nucleophilic Allylation Driven by the Water-Gas Shift Reaction

Denmark, S. E., Matesich, Z. D., Nguyen, S. T. & Milicevic Sephton, S., Jan 5 2018, In : Journal of Organic Chemistry. 83, 1, p. 23-48 26 p.

Research output: Contribution to journalArticle