Scott E Denmark

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Research Output

Synthesis and resolution of racemic trans-2-(N-benzyl)amino-1-cyclohexanol: Enantiomer separation by sequential use of (R)- and (S)-Mandelic acid: [cyclohexanol, 2-(N-benzyl)amino, (1S,2S)- and (1R,2R)-]

Schiffers, I., Bolm, C., Denmark, S. E., Woerly, E., Toussaint, A. & Pfaltz, A., Jan 1 2008, Organic Syntheses. Wiley Blackwell, p. 106-117 12 p. (Organic Syntheses; vol. 85).

Research output: Chapter in Book/Report/Conference proceedingChapter

Synthesis and reactivity of enantiomerically enriched thiiranium ions

Denmark, S. E. & Vogler, T., Nov 2 2009, In : Chemistry - A European Journal. 15, 43, p. 11737-11745 9 p.

Research output: Contribution to journalArticle

Synthesis, x-ray crystallography, and computational analysis of 1-azafenestranes

Denmark, S. E., Montgomery, J. I. & Kramps, L. A., Sep 6 2006, In : Journal of the American Chemical Society. 128, 35, p. 11620-11630 11 p.

Research output: Contribution to journalArticle

Synthesis, structure, and reactivity of an organogermanium lewis acid

Denmark, S. E., Jacobs, R. T., Dai-Ho, G. & Wilson, S., Jan 1 1990, In : Organometallics. 9, 12, p. 3015-3019 5 p.

Research output: Contribution to journalArticle

Synthesis, Reactivity, Functionalization, and ADMET Properties of Silicon-Containing Nitrogen Heterocycles

Barraza, S. J. & Denmark, S. E., May 30 2018, In : Journal of the American Chemical Society. 140, 21, p. 6668-6684 17 p.

Research output: Contribution to journalArticle

Summation

Vedejs, E. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1351-1353 3 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Studies on the reduction and hydrolysis of nitroso acetals

Denmark, S. E., Guagnano, V. & Vaugeois, J., Jan 1 2001, In : Canadian Journal of Chemistry. 79, 11, p. 1606-1616 11 p.

Research output: Contribution to journalArticle

Studies on the Mechanism and Origin of Stereoselective Opening of Chiral Dioxane Acetals

Denmark, S. E. & Almstead, N. G., Oct 1 1991, In : Journal of the American Chemical Society. 113, 21, p. 8089-8110 22 p.

Research output: Contribution to journalArticle

Studies on the bisoxazoline- and (-)-sparteine-mediated enantioselective addition of organolithium reagents to imines

Denmark, S. E., Nakajima, N., Stiff, C. M., Nicaise, O. J. C. & Kranz, M., May 5 2008, In : Advanced Synthesis and Catalysis. 350, 7-8, p. 1023-1045 23 p.

Research output: Contribution to journalArticle

Structure and Dynamics of Phosphorus(V)-Stabilized Carbanions: A Comparison of Theoretical, Crystallographic, and Solution Structures

Cramer, C. J., Denmark, S. E., Miller, P. C., Dorow, R. L., Swiss, K. A. & Wilson, S. R., Mar 1 1994, In : Journal of the American Chemical Society. 116, 6, p. 2437-2447 11 p.

Research output: Contribution to journalArticle

Structural, Kinetic, and Computational Characterization of the Elusive Arylpalladium(II)boronate Complexes in the Suzuki-Miyaura Reaction

Thomas, A. A., Wang, H., Zahrt, A. F. & Denmark, S. E., Mar 15 2017, In : Journal of the American Chemical Society. 139, 10, p. 3805-3821 17 p.

Research output: Contribution to journalArticle

Stereospecific palladium-catalyzed cross-coupling of (E)- and (Z)-alkenylsilanolates with aryl chlorides

Denmark, S. E. & Kallemeyn, J. M., Dec 20 2006, In : Journal of the American Chemical Society. 128, 50, p. 15958-15959 2 p.

Research output: Contribution to journalArticle

Stereospecific cleavage of carbon-phosphorus bonds: Stereochemical course of the phosphinoyl curtius (harger) reaction

Denmark, S. E. & Dorow, R. L., Feb 11 2002, In : Chirality. 14, 2-3, p. 241-257 17 p.

Research output: Contribution to journalArticle

Stereoselective Alkylations of Chiral, Phosphorus-Stabilized Benzylic Carbanions

Denmark, S. E. & Dorow, R. L., Nov 1990, In : Journal of Organic Chemistry. 55, 24, p. 5926-5928 3 p.

Research output: Contribution to journalArticle

Stereoselective alkylation of chiral α-nitro keto imine dianions. Observations on the role of amide bases

Denmark, S. E. & Ares, J. J., Jun 1988, In : Journal of the American Chemical Society. 110, 13, p. 4432-4434 3 p.

Research output: Contribution to journalArticle

Stereoselective aldol additions of achiral ethyl ketone-derived trichlorosilyl enolates

Denmark, S. E. & Pham, S. M., Jun 27 2003, In : Journal of Organic Chemistry. 68, 13, p. 5045-5055 11 p.

Research output: Contribution to journalArticle

Stereocontrolled total syntheses of isodomoic acids G and H via a unified strategy

Denmark, S. E., Liu, J. H. C. & Muhuhi, J. M., Jan 7 2011, In : Journal of Organic Chemistry. 76, 1, p. 201-215 15 p.

Research output: Contribution to journalArticle

Stereochemistry of Allylmetal-Aldehyde Condensations. 2. Allylstannanes

Denmark, S. E. & Weber, E. J., Dec 1 1984, In : Journal of the American Chemical Society. 106, 25, p. 7970-7971 2 p.

Research output: Contribution to journalArticle

Stereochemical Studies on the Addition of Allylstannanes to Aldehydes. The SE′Component

Denmark, S. E. & Hosoi, S., Sep 1 1994, In : Journal of Organic Chemistry. 59, 18, p. 5133-5135 3 p.

Research output: Contribution to journalArticle

Stereochemical Studies on the Addition of Allylsilanes to Aldehydes. The SE′ Component

Denmark, S. E. & Almstead, N. G., Sep 1 1994, In : Journal of Organic Chemistry. 59, 18, p. 5130-5132 3 p.

Research output: Contribution to journalArticle

Stereochemical studies on the addition of allylsilanes to aldehydes. The SE' component

Denmark, S. E. & Almstead, N. G., Jul 1 2009, In : Journal of the Mexican Chemical Society. 53, 3, p. 174-192 19 p.

Research output: Contribution to journalArticle

Stereochemical and spectroscopic studies on the reaction of allylstannanes with aldehydes

Denmark, S. E., Weber, E. J., Wilson, T. M. & Willson, T. M., 1989, In : Tetrahedron. 45, 4, p. 1053-1065 13 p.

Research output: Contribution to journalArticle

Spectroscopic studies on the TiCl4-promoted reaction of allylsilanes with aldehydes and α,β-enones

Denmark, S. E. & Almstead, N. G., Jul 3 1992, In : Tetrahedron. 48, 27, p. 5565-5578 14 p.

Research output: Contribution to journalArticle

Spectroscopic Studies on the Structure and Conformation of Lewis Acid-Aldehyde Complexes

Denmark, S. E. & Almstead, N. G., Apr 1 1993, In : Journal of the American Chemical Society. 115, 8, p. 3133-3139 7 p.

Research output: Contribution to journalArticle

Special issue dedicated to Professor Albert Eschenmoser

Jung, M. E., Pfaltz, A. & Denmark, S. E., 1999, Stuttgart: Unknown Publisher.

Research output: Book/Report/Conference proceedingBook

Solution and solid-state studies of a chiral zinc- sulfonamide complex relevant to enantioselective cyclopropanations

Denmark, S. E., O'Connor, S. P. & Wilson, S. R., May 4 1998, In : Angewandte Chemie - International Edition. 37, 8, p. 1149-1151 3 p.

Research output: Contribution to journalArticle

Solution and solid-state structures of lithiated cyclic phosphonates

Denmark, S. E., Swiss, K. A., Miller, P. C. & Wilson, S. R., Jan 1 1998, In : Heteroatom Chemistry. 9, 2, p. 209-218 10 p.

Research output: Contribution to journalArticle

Solution and Solid-State Structure of the “Wittig-Furukawa” Cyclopropanation Reagent

Denmark, S. E., Edwards, J. P. & Wilson, S. R., Jan 1 1991, In : Journal of the American Chemical Society. 113, 2, p. 723-725 3 p.

Research output: Contribution to journalArticle

Solution and Solid-State Structure of a Phosphorus-Stabilized Carbanion

Denmark, S. E. & Dorow, R. L., Jan 1 1990, In : Journal of the American Chemical Society. 112, 2, p. 864-866 3 p.

Research output: Contribution to journalArticle

Solution and solid-state structure of a lithiated phosphane oxide

Denmark, S. E., Swiss, K. A. & Wilson, S. R., Jan 1 1996, In : Angewandte Chemie (International Edition in English). 35, 21, p. 2515-2517 3 p.

Research output: Contribution to journalArticle

Solution- and Solid-State Structure and Dynamics of Thiophosphonamide Anions: Electronic Tuning of Rotational Barriers

Denmark, S. E., Swiss, K. A. & Wilson, S. R., May 1 1993, In : Journal of the American Chemical Society. 115, 9, p. 3826-3827 2 p.

Research output: Contribution to journalLetter

Solution-and Solid-State Structural Studies of (Halomethyl)zinc Reagents

Denmark, S. E., Edwards, J. P. & Wilsonf, S. R., Mar 1 1992, In : Journal of the American Chemical Society. 114, 7, p. 2592-2602 11 p.

Research output: Contribution to journalArticle

Solid state and solution structural studies of chiral phosphoramide-tin complexes relevant to Lewis base catalyzed aldol reactions

Denmark, S. E. & Su, X., Jul 16 1999, In : Tetrahedron. 55, 29, p. 8727-8738 12 p.

Research output: Contribution to journalArticle

SnCl4(4-t-BuC6H4CHO)2. X-ray Crystal Structure, Solution NMR, and Implications for Reactions at Complexed Carbonyls1a

Denmark, S. E., Henke, B. R. & Weber, E., Apr 1 1987, In : Journal of the American Chemical Society. 109, 8, p. 2512-2514 3 p.

Research output: Contribution to journalArticle

Silyl ketene imines: Highly versatile nucleophiles for catalytic, asymmetric synthesis

Denmark, S. E. & Wilson, T. W., Oct 1 2012, In : Angewandte Chemie - International Edition. 51, 40, p. 9980-9992 13 p.

Research output: Contribution to journalReview article

Silicon‐Directed Nazarov Reactions III. Stereochemical and Mechanistic Considerations

Jones, T. K. & Denmark, S. E., Jan 1 1983, In : Helvetica Chimica Acta. 66, 8, p. 2397-2411 15 p.

Research output: Contribution to journalArticle

Silicon‐Directed Nazarov Reactions II. Preparation and Cyclization of β‐Silyl‐substituted Divinyl Ketones

Jones, T. K. & Denmark, S. E., Jan 1 1983, In : Helvetica Chimica Acta. 66, 8, p. 2377-2396 20 p.

Research output: Contribution to journalArticle

Silicon-directed nazarov cyclizations VII. Linearly-fused tricyclics

Denmark, S. E. & Klix, R. C., 1988, In : Tetrahedron. 44, 13, p. 4043-4060 18 p.

Research output: Contribution to journalArticle

Silicon-directed nazarov cyclizations-IV. Further studies in stereochemical control

Denmark, S. E., Habermas, K. L., Hite, G. A. & Jones, T. K., 1986, In : Tetrahedron. 42, 11, p. 2821-2829 9 p.

Research output: Contribution to journalArticle

Silicon‐Directed Nazarov Cyclizations. Part VI. The anomalous cyclization of vinyl dienyl ketones

Denmark, S. E. & Hite, G. A., Feb 3 1988, In : Helvetica Chimica Acta. 71, 1, p. 195-208 14 p.

Research output: Contribution to journalArticle

Silicon‐Directed Nazarov Cyclizations. Part V. Substituent and heteroatom effects on the reaction

Denmark, S. E., Habermas, K. L. & Hite, G. A., Feb 3 1988, In : Helvetica Chimica Acta. 71, 1, p. 168-194 27 p.

Research output: Contribution to journalArticle

Silicon-directed Nazarov cyclizations. 8. Stereoelectronic control of torquoselectivity

Denmark, S. E., Wallace, M. A. & Walker, C. B., Dec 1 1990, In : Journal of Organic Chemistry. 55, 21, p. 5543-5545 3 p.

Research output: Contribution to journalArticle

Silicon-Directed Nazarov Cyclization

Denmark, S. E. & Jones, T. K., Jan 1 1982, In : Journal of the American Chemical Society. 104, 9, p. 2642-2645 4 p.

Research output: Contribution to journalArticle

Silicon-based cross-coupling reactions in the total synthesis of natural products

Denmark, S. E. & Liu, J. H. C., Apr 12 2010, In : Angewandte Chemie - International Edition. 49, 17, p. 2978-2986 9 p.

Research output: Contribution to journalReview article

Sequential silylcarbocyclization/silicon-based cross-coupling reactions

Denmark, S. E. & Liu, J. H. C., Mar 28 2007, In : Journal of the American Chemical Society. 129, 12, p. 3737-3744 8 p.

Research output: Contribution to journalArticle