Scott E Denmark

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Research Output

α-Nitro Keto Hydrazone and Keto Imine Dianions. Synthetic Equivalents for the Nitroalkene d3 Synthon

Denmark, S. E., Sternberg, J. A. & Lueoend, R., Mar 1 1988, In : Journal of Organic Chemistry. 53, 6, p. 1251-1263 13 p.

Research output: Contribution to journalArticle

α-chloro ketoximes as precursors of nitrosoalkenes: Preparation, stereochemistry and conformation

Denmark, S. E. & Dappen, M. S., Dec 1984, In : Journal of Organic Chemistry. 49, 5, p. 798-806 9 p.

Research output: Contribution to journalArticle

Why You Really Should Consider Using Palladium-Catalyzed Cross-Coupling of Silanols and Silanolates

Denmark, S. E. & Ambrosi, A., Jul 30 2015, In : Organic Process Research and Development. 19, 8, p. 982-994 13 p.

Research output: Contribution to journalArticle

Vinylation with inexpensive silicon-based reagents: Preparation of 3-vinylquinoline and 4-vinylbenzophenone

Denmark, S. E., Butler, C. R., Pfaltz, A. & Woodmansee, D. H., Dec 1 2009, In : Organic Syntheses. 86, p. 274-286 13 p.

Research output: Contribution to journalArticle

Vinylation of aryl bromides using an inexpensive vinylpolysiloxane

Denmark, S. E. & Butler, C. R., Jan 5 2006, In : Organic Letters. 8, 1, p. 63-66 4 p.

Research output: Contribution to journalArticle

Vinylation of aromatic halides using inexpensive organosilicon reagents. Illustration of design of experiment protocols

Denmark, S. E. & Butler, C. R., Mar 19 2008, In : Journal of the American Chemical Society. 130, 11, p. 3690-3704 15 p.

Research output: Contribution to journalArticle

Unusual Kinetic Profiles for Lewis Base-Catalyzed Sulfenocyclization of ortho -Geranylphenols in Hexafluoroisopropyl Alcohol

Robb, K. A., Athavale, S. V. & Denmark, S. E., Jan 1 2019, In : Synlett. 30, 14, p. 1656-1661 6 p.

Research output: Contribution to journalArticle

Unexpected Rearrangement of 2-Bromoaniline under Biphasic Alkylation Conditions

Barraza, S. J. & Denmark, S. E., Dec 18 2017, In : Synlett. 28, 20, p. 2891-2895 5 p.

Research output: Contribution to journalArticle

Unexpected ambidoselectivity in crossed-aldol reactions of α-oxy aldehyde trichlorosilyl enolates

Denmark, S. E. & Ghosh, S. K., Aug 27 2007, In : Tetrahedron. 63, 35, p. 8636-8644 9 p.

Research output: Contribution to journalArticle

Understanding Site Selectivity in the Palladium-Catalyzed Cross-Coupling of Allenylsilanolates

Denmark, S. E. & Ambrosi, A., Nov 13 2017, In : Synlett. 28, 18, p. 2415-2420 6 p.

Research output: Contribution to journalArticle

Trifluoromethylation at the -position of ,-unsaturated ketones: 4-Phenyl-3-(trifluoromethyl)butan-2-one

Sato, K., Omote, M., Ando, A., Kumadaki, I., Denmark, S. E. & Chung, W. J., Jan 1 2006, In : Organic Syntheses. 83, p. 177-183 7 p.

Research output: Contribution to journalArticle

Triarylcarbenium ions as catalysts in the Mukaiyama Aldol addition: A mechanistic investigation

Denmark, S. E. & Chen, C. T., Jun 20 1994, In : Tetrahedron Letters. 35, 25, p. 4327-4330 4 p.

Research output: Contribution to journalArticle

Transformation of primary amines to N-monoalkylhydroxylamines: N-hydroxy-(S)-1-phenylethylamine oxalate: [(Benzenemethanamine, N-hydroxy--methyl-, (S)-, ethanedioate)]

Tokuyama, H., Kuboyama, T., Fukuyama, T., Denmark, S. E. & Cottell, J. J., Jan 1 2003, In : Organic Syntheses. 80, p. 207-218 12 p.

Research output: Contribution to journalArticle

Toward Catalytic, Enantioselective Chlorolactonization of 1,2-Disubstituted Styrenyl Carboxylic Acids

Denmark, S. E., Ryabchuk, P., Burk, M. T. & Gilbert, B. B., Nov 4 2016, In : Journal of Organic Chemistry. 81, 21, p. 10411-10423 13 p.

Research output: Contribution to journalArticle

Total synthesis of RK-397

Denmark, S. E. & Fujimori, S., Jun 29 2005, In : Journal of the American Chemical Society. 127, 25, p. 8971-8973 3 p.

Research output: Contribution to journalArticle

Total synthesis of papulacandin D

Kobayashi, T., Regens, C. S. & Denmark, S. E., Jun 2008, In : Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry. 66, 6, p. 616-628 13 p.

Research output: Contribution to journalArticle

Total synthesis of papulacandin D

Kobayashi, T., Regens, C. S. & Denmark, S. E., 2012, Strategies and Tactics in Organic Synthesis. Academic Press Inc., p. 79-126 48 p. (Strategies and Tactics in Organic Synthesis; vol. 8).

Research output: Chapter in Book/Report/Conference proceedingChapter

Total synthesis of papulacandin D

Denmark, S. E., Regens, C. S. & Kobayashi, T., Mar 14 2007, In : Journal of the American Chemical Society. 129, 10, p. 2774-2776 3 p.

Research output: Contribution to journalArticle

Total synthesis of (+)-papulacandin D

Denmark, S. E., Kobayashi, T. & Regens, C. S., Jun 26 2010, In : Tetrahedron. 66, 26, p. 4745-4759 15 p.

Research output: Contribution to journalArticle

Total synthesis of (+)-brasilenyne. Application of an intramolecular silicon-assisted cross-coupling reaction

Denmark, S. E. & Yang, S. M., Oct 6 2004, In : Journal of the American Chemical Society. 126, 39, p. 12432-12440 9 p.

Research output: Contribution to journalArticle

Total syntheses of isodomoic acids G and H

Denmark, S. E., Liu, J. H. C. & Muhuhi, J. M., Oct 14 2009, In : Journal of the American Chemical Society. 131, 40, p. 14188-14189 2 p.

Research output: Contribution to journalArticle

Topics in stereochemistry. Vol. 25

Siegel, J. S. & Denmark, S. E., 2006, Hoboken, N, J: John Wiley & Sons.

Research output: Book/ReportBook

Topics in stereochemistry. Vol. 23

Denmark, S. E., 2003, Hoboken: Wiley-Interscience.

Research output: Book/ReportBook

Topics in Stereochemistry

Denmark, S. E. & Siegel, J. S., May 5 2006, Wiley-Blackwell. 403 p.

Research output: Book/ReportBook

Topics in Stereochemistry

Denmark, S. E., Feb 27 2007, Wiley. 314 p.

Research output: Book/ReportBook

Topics in Stereochemistry: Introduction to the series

Denmark, S. E. & Siegel, J. S., Jul 13 2006, In : Topics in Stereochemistry. 25, p. v

Research output: Contribution to journalEditorial

The Vinylogous Anomeric Effect in 3-Alkyl-2-chlorocyclohexanone Oximes and Oxime Ethers

Denmark, S. E., Dappen, M. S., Sear, N. L. & Jacobs, R. T., Jan 1990, In : Journal of the American Chemical Society. 112, 9, p. 3466-3474 9 p.

Research output: Contribution to journalArticle

The Theoretical Structures of Neutral, Anionic, and Lithiated P-Allylphosphonic Diamide

Denmark, S. E. & Cramer, C. J., Jan 1 1990, In : Journal of Organic Chemistry. 55, 6, p. 1806-1813 8 p.

Research output: Contribution to journalArticle

The Tandem Cycloaddition Chemistry of Nitroalkenes. A Novel Synthesis of (−)-Hastanecine

Denmark, S. E. & Thorarensen, A., Sep 1 1994, In : Journal of Organic Chemistry. 59, 19, p. 5672-5680 9 p.

Research output: Contribution to journalArticle

The tandem cycloaddition chemistry of nitroalkenes

Denmark, S. E., Schnute, M. E., Thorarensen, A., Middleton, D. S. & Stolle, A., Jan 1 1994, In : Pure and Applied Chemistry. 66, 10-11, p. 2041-2044 4 p.

Research output: Contribution to journalArticle

The synthesis and use of cyclic nitronic esters

Kesler, B. S. & Denmark, S. E., 1993, Urbana, Il: University of Illinois.

Research output: Book/ReportBook

The stereostructures of [1,1′-bicyclohexyl]-2,2′-diones: A reassignment

Denmark, S. E., Cramer, C. J. & Sternberg, J. A., 1986, In : Tetrahedron Letters. 27, 48, 1 p.

Research output: Contribution to journalComment/debate

The stereostructures of [1,1′-bicyclohexyl]-2,2′-diones: A reassignment

Denmark, S. E., Cramer, C. J. & Sternberg, J. A., 1986, In : Tetrahedron Letters. 27, 32, p. 3693-3696 4 p.

Research output: Contribution to journalArticle

The Origin of Stereoselective Opening of Chiral Dioxane and Dioxolane Acetals: Solution Structure of Their Lewis Acid Complexes+

Denmark, S. E., Willson, T. M. & Almstead, N. G., Dec 1989, In : Journal of the American Chemical Society. 111, 26, p. 9258-9260 3 p.

Research output: Contribution to journalArticle

The interplay of invention, observation, and discovery in the development of lewis base activation of lewis acids for catalytic enantioselective synthesis

Beutner, G. L. & Denmark, S. E., Jan 1 2013, Inventing Reactions. Goossen, L. (ed.). p. 55-89 35 p. (Topics in Organometallic Chemistry; vol. 44).

Research output: Chapter in Book/Report/Conference proceedingChapter

The interplay of invention, discovery, development, and application in organic synthetic methodology: A case study

Denmark, S. E., Apr 17 2009, In : Journal of Organic Chemistry. 74, 8, p. 2915-2927 13 p.

Research output: Contribution to journalReview article

The first catalytic, diastereoselective, and enantioselective crossed-aldol reactions of aldehydes

Denmark, S. E. & Ghosh, S. K., Dec 17 2001, In : Angewandte Chemie - International Edition. 40, 24, p. 4759-4762 4 p.

Research output: Contribution to journalArticle

The effects of a remote stereogenic center in the Lewis base catalyzed aldol additions of chiral trichlorosilyl enolates

Denmark, S. E. & Fujimori, S., Oct 3 2002, In : Organic Letters. 4, 20, p. 3477-3480 4 p.

Research output: Contribution to journalArticle

The development of chiral, nonracemic dioxiranes for the catalytic, enantioselective epoxidation of alkenes

Denmark, S. E. & Wu, Z., Jan 1 1999, In : Synlett. SPEC. ISS., p. 847-859 13 p.

Research output: Contribution to journalArticle

The chemistry of trichlorosilyl enolates. Aldol addition reactions of methyl ketones

Denmark, S. E. & Stavenger, R. A., Sep 20 2000, In : Journal of the American Chemical Society. 122, 37, p. 8837-8847 11 p.

Research output: Contribution to journalArticle

The chemistry of trichlorosilyl enolates. 6. Mechanistic duality in the lewis base-catalyzed aldol addition reaction [18]

Denmark, S. E., Su, X. & Nishigaichi, Y., Dec 16 1998, In : Journal of the American Chemical Society. 120, 49, p. 12990-12991 2 p.

Research output: Contribution to journalLetter

The chemistry of trichlorosilyl enolates. 2. Highly-selective asymmetric aldol additions of ketone enolates

Denmark, S. E., Wong, K. T. & Stavenger, R. A., Jan 1 1997, In : Journal of the American Chemical Society. 119, 9, p. 2333-2334 2 p.

Research output: Contribution to journalArticle

The Chemistry of Enoxysilacyclobutanes: Highly Selective, Uncatalyzed Aldol Additions

Denmark, S. E., Griedel, B. D. & Coe, D. M., Jan 1 1993, In : Journal of Organic Chemistry. 58, 5, p. 988-990 3 p.

Research output: Contribution to journalArticle

The Chemistry of Chlorosilyl Enolates 3. Variation of the Silyl Group and the Effect on Rate and Enantiomeric Excess of Acetate Aldol Additions

Denmark, S. E. & Winter, S. B. D., Jan 1 1997, In : Synlett. 1997, 9, p. 1087-1089 3 p.

Research output: Contribution to journalArticle