Scott E Denmark

1975 …2020
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Research Output 1975 2020

The effects of a remote stereogenic center in the Lewis base catalyzed aldol additions of chiral trichlorosilyl enolates

Denmark, S. E. & Fujimori, S., Oct 3 2002, In : Organic Letters. 4, 20, p. 3477-3480 4 p.

Research output: Contribution to journalArticle

Bearings (structural)
Lewis Bases
Lewis base
Ketones
Aldehydes
Lewis Bases
Cyanides
aldehyde
Aldehydes
Enantioselectivity

The first catalytic, diastereoselective, and enantioselective crossed-aldol reactions of aldehydes

Denmark, S. E. & Ghosh, S. K., Dec 17 2001, In : Angewandte Chemie - International Edition. 40, 24, p. 4759-4762 4 p.

Research output: Contribution to journalArticle

Aldehydes
Enantioselectivity
Catalysis
Condensation
3-hydroxybutanal

The interplay of invention, discovery, development, and application in organic synthetic methodology: A case study

Denmark, S. E., Apr 17 2009, In : Journal of Organic Chemistry. 74, 8, p. 2915-2927 13 p.

Research output: Contribution to journalReview article

Patents and inventions
Palladium
Silicon
Biological Products
Derivatives

The interplay of invention, observation, and discovery in the development of lewis base activation of lewis acids for catalytic enantioselective synthesis

Beutner, G. L. & Denmark, S. E., Jan 1 2013, Inventing Reactions. Goossen, L. (ed.). p. 55-89 35 p. (Topics in Organometallic Chemistry; vol. 44).

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Lewis Acids
Patents and inventions
Esters
Nucleophiles

The Origin of Stereoselective Opening of Chiral Dioxane and Dioxolane Acetals: Solution Structure of Their Lewis Acid Complexes+

Denmark, S. E., Willson, T. M. & Almstead, N. G., Dec 1989, In : Journal of the American Chemical Society. 111, 26, p. 9258-9260 3 p.

Research output: Contribution to journalArticle

Lewis Acids
Acetals
Acids
1,4-dioxane
formal glycol
Azides
Phosphorus
Phenethylamines
Nitrogen
Carbon

The stereostructures of [1,1′-bicyclohexyl]-2,2′-diones: A reassignment

Denmark, S. E., Cramer, C. J. & Sternberg, J. A., 1986, In : Tetrahedron Letters. 27, 32, p. 3693-3696 4 p.

Research output: Contribution to journalArticle

Isomers
Crystal structure
X-Rays
X rays

The stereostructures of [1,1′-bicyclohexyl]-2,2′-diones: A reassignment

Denmark, S. E., Cramer, C. J. & Sternberg, J. A., 1986, In : Tetrahedron Letters. 27, 48, 1 p.

Research output: Contribution to journalComment/debate

The synthesis and use of cyclic nitronic esters

Kesler, B. S. & Denmark, S. E., 1993, Urbana, Il: University of Illinois.

Research output: Book/ReportBook

The tandem cycloaddition chemistry of nitroalkenes

Denmark, S. E., Schnute, M. E., Thorarensen, A., Middleton, D. S. & Stolle, A., Jan 1 1994, In : Pure and Applied Chemistry. 66, 10-11, p. 2041-2044 4 p.

Research output: Contribution to journalArticle

Cycloaddition
Stereoselectivity
hastanecine

The Tandem Cycloaddition Chemistry of Nitroalkenes. A Novel Synthesis of (−)-Hastanecine

Denmark, S. E. & Thorarensen, A., Sep 1 1994, In : Journal of Organic Chemistry. 59, 19, p. 5672-5680 9 p.

Research output: Contribution to journalArticle

Cycloaddition
Acetals
Lewis Acids
hastanecine

The Theoretical Structures of Neutral, Anionic, and Lithiated P-Allylphosphonic Diamide

Denmark, S. E. & Cramer, C. J., Jan 1 1990, In : Journal of Organic Chemistry. 55, 6, p. 1806-1813 8 p.

Research output: Contribution to journalArticle

Diamide
Anions
Isomers
Lithium
Charge distribution

The Vinylogous Anomeric Effect in 3-Alkyl-2-chlorocyclohexanone Oximes and Oxime Ethers

Denmark, S. E., Dappen, M. S., Sear, N. L. & Jacobs, R. T., Jan 1990, In : Journal of the American Chemical Society. 112, 9, p. 3466-3474 9 p.

Research output: Contribution to journalArticle

Oximes
Ethers
crystal structure
ether
Conformations

Topics in Stereochemistry

Denmark, S. E., Feb 27 2007, Wiley. 314 p.

Research output: Book/ReportBook

Stereochemistry
Chirality
Catalytic Antibodies
Catalysis
Lanthanoid Series Elements

Topics in Stereochemistry

Denmark, S. E. & Siegel, J. S., May 5 2006, Wiley Blackwell. 403 p.

Research output: Book/ReportBook

Stereochemistry
Crystals
Hydrogen bonds
Pyrimidinones
Stilbenes

Topics in Stereochemistry: Introduction to the series

Denmark, S. E. & Siegel, J. S., Jul 13 2006, In : Topics in Stereochemistry. 25, p. v

Research output: Contribution to journalEditorial

Stereochemistry

Topics in stereochemistry. Vol. 23

Denmark, S. E., 2003, Hoboken: Wiley-Interscience.

Research output: Book/ReportBook

Topics in stereochemistry. Vol. 25

Siegel, J. S. & Denmark, S. E., 2006, Hoboken, N, J: John Wiley & Sons.

Research output: Book/ReportBook

Total syntheses of isodomoic acids G and H

Denmark, S. E., Liu, J. H. C. & Muhuhi, J. M., Oct 14 2009, In : Journal of the American Chemical Society. 131, 40, p. 14188-14189 2 p.

Research output: Contribution to journalArticle

Halogenation
Silicon
Rhodium
silicon
Acids

Total synthesis of (+)-brasilenyne. Application of an intramolecular silicon-assisted cross-coupling reaction

Denmark, S. E. & Yang, S. M., Oct 6 2004, In : Journal of the American Chemical Society. 126, 39, p. 12432-12440 9 p.

Research output: Contribution to journalArticle

Cross Reactions
Silicon
silicon
Acids
acid

Total synthesis of (+)-papulacandin D

Denmark, S. E., Kobayashi, T. & Regens, C. S., Jun 26 2010, In : Tetrahedron. 66, 26, p. 4745-4759 15 p.

Research output: Contribution to journalArticle

Lewis Bases
Cross Reactions
Palladium
Iodides
Unsaturated Fatty Acids

Total synthesis of papulacandin D

Kobayashi, T., Regens, C. S. & Denmark, S. E., Jun 2008, In : Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry. 66, 6, p. 616-628 13 p.

Research output: Contribution to journalArticle

Allylation
Calcium Gluconate
Molecules
Palladium
Glycosides

Total synthesis of papulacandin D

Denmark, S. E., Regens, C. S. & Kobayashi, T., Mar 14 2007, In : Journal of the American Chemical Society. 129, 10, p. 2774-2776 3 p.

Research output: Contribution to journalArticle

Calcium Gluconate
Antifungal Agents
palladium
Palladium
Biological Products

Total synthesis of papulacandin D

Kobayashi, T., Regens, C. S. & Denmark, S. E., 2012, Strategies and Tactics in Organic Synthesis. Academic Press Inc., p. 79-126 48 p. (Strategies and Tactics in Organic Synthesis; vol. 8).

Research output: Chapter in Book/Report/Conference proceedingChapter

Palladium
Biological Products
papulacandins

Total synthesis of RK-397

Denmark, S. E. & Fujimori, S., Jun 29 2005, In : Journal of the American Chemical Society. 127, 25, p. 8971-8973 3 p.

Research output: Contribution to journalArticle

palladium
carbon
Polyenes
Polyols
Macrolides

Toward Catalytic, Enantioselective Chlorolactonization of 1,2-Disubstituted Styrenyl Carboxylic Acids

Denmark, S. E., Ryabchuk, P., Burk, M. T. & Gilbert, B. B., Nov 4 2016, In : Journal of Organic Chemistry. 81, 21, p. 10411-10423 13 p.

Research output: Contribution to journalArticle

Lewis Bases
Carboxylic Acids
Catalysis
Ions
Enantioselectivity

Transformation of primary amines to N-monoalkylhydroxylamines: N-hydroxy-(S)-1-phenylethylamine oxalate: [(Benzenemethanamine, N-hydroxy--methyl-, (S)-, ethanedioate)]

Tokuyama, H., Kuboyama, T., Fukuyama, T., Denmark, S. E. & Cottell, J. J., Jan 1 2003, In : Organic Syntheses. 80, p. 207-218 12 p.

Research output: Contribution to journalArticle

Phenethylamines
Oxalates
Amines

Triarylcarbenium ions as catalysts in the Mukaiyama Aldol addition: A mechanistic investigation

Denmark, S. E. & Chen, C. T., Jun 20 1994, In : Tetrahedron Letters. 35, 25, p. 4327-4330 4 p.

Research output: Contribution to journalArticle

Ethers
Ions
Catalysts
Salts
Kinetics

Trifluoromethylation at the -position of ,-unsaturated ketones: 4-Phenyl-3-(trifluoromethyl)butan-2-one

Sato, K., Omote, M., Ando, A., Kumadaki, I., Denmark, S. E. & Chung, W. J., Jan 1 2006, In : Organic Syntheses. 83, p. 177-183 7 p.

Research output: Contribution to journalArticle

ketones

Understanding Site Selectivity in the Palladium-Catalyzed Cross-Coupling of Allenylsilanolates

Denmark, S. E. & Ambrosi, A., Nov 13 2017, In : Synlett. 28, 18, p. 2415-2420 6 p.

Research output: Contribution to journalArticle

Palladium
Isomers
Tuning

Unexpected ambidoselectivity in crossed-aldol reactions of α-oxy aldehyde trichlorosilyl enolates

Denmark, S. E. & Ghosh, S. K., Aug 27 2007, In : Tetrahedron. 63, 35, p. 8636-8644 9 p.

Research output: Contribution to journalArticle

Aldehydes
Enantioselectivity
Stereoselectivity
Acetaldehyde
3-hydroxybutanal

Unexpected Rearrangement of 2-Bromoaniline under Biphasic Alkylation Conditions

Barraza, S. J. & Denmark, S. E., Dec 18 2017, In : Synlett. 28, 20, p. 2891-2895 5 p.

Research output: Contribution to journalArticle

Alkylation
Bromine
Electrons
3-bromoaniline

Unusual Kinetic Profiles for Lewis Base-Catalyzed Sulfenocyclization of ortho -Geranylphenols in Hexafluoroisopropyl Alcohol

Robb, K. A., Athavale, S. V. & Denmark, S. E., Jan 1 2019, In : Synlett. 30, 14, p. 1656-1661 6 p.

Research output: Contribution to journalArticle

Lewis Bases
Polyenes
Alcohols
Nucleophiles
Kinetics

Vinylation of aromatic halides using inexpensive organosilicon reagents. Illustration of design of experiment protocols

Denmark, S. E. & Butler, C. R., Mar 19 2008, In : Journal of the American Chemical Society. 130, 11, p. 3690-3704 15 p.

Research output: Contribution to journalArticle

halide
Design of experiments
iodide
Iodides
Styrenes

Vinylation of aryl bromides using an inexpensive vinylpolysiloxane

Denmark, S. E. & Butler, C. R., Jan 5 2006, In : Organic Letters. 8, 1, p. 63-66 4 p.

Research output: Contribution to journalArticle

Styrenes
Palladium
Bromides
styrenes
fluorides

Vinylation with inexpensive silicon-based reagents: Preparation of 3-vinylquinoline and 4-vinylbenzophenone

Denmark, S. E., Butler, C. R., Pfaltz, A. & Woodmansee, D. H., Dec 1 2009, In : Organic Syntheses. 86, p. 274-286 13 p.

Research output: Contribution to journalArticle

reagents
preparation
silicon

Why You Really Should Consider Using Palladium-Catalyzed Cross-Coupling of Silanols and Silanolates

Denmark, S. E. & Ambrosi, A., Jul 30 2015, In : Organic Process Research and Development. 19, 8, p. 982-994 13 p.

Research output: Contribution to journalArticle

cross coupling
Palladium
Silicon
palladium
Fluorides

α-chloro ketoximes as precursors of nitrosoalkenes: Preparation, stereochemistry and conformation

Denmark, S. E. & Dappen, M. S., Dec 1984, In : Journal of Organic Chemistry. 49, 5, p. 798-806 9 p.

Research output: Contribution to journalArticle

Stereochemistry
Oximes
Conformations
Cyclohexanones
Geometry

α-Nitro Keto Hydrazone and Keto Imine Dianions. Synthetic Equivalents for the Nitroalkene d3 Synthon

Denmark, S. E., Sternberg, J. A. & Lueoend, R., Mar 1 1988, In : Journal of Organic Chemistry. 53, 6, p. 1251-1263 13 p.

Research output: Contribution to journalArticle

Hydrazones
Imines
Deprotonation
Alkylation
Iodides
cross coupling
Bromides
adducts
bromides
Salts