Scott E Denmark

1975 …2019
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Research Output 1975 2019

Synthesis of (+)-casuarine

Denmark, S. E. & Hurd, A. R., Oct 21 1999, In : Organic Letters. 1, 8, p. 1311-1314 4 p.

Research output: Contribution to journalArticle

Pyrrolizidine Alkaloids
Silanes
alkaloids
Cycloaddition
Glycoside Hydrolases

Synthesis of (1R,2R,3R,7R,7aR)-hexahydro. 3-(hydroxymethyl)- 1H- pyrrolizine-1,2,7-triol: 7-Epiaustraline [6]

Denmark, S. E. & Herbert, B., Jul 29 1998, In : Journal of the American Chemical Society. 120, 29, p. 7357-7358 2 p.

Research output: Contribution to journalLetter

Synthesis of 2-Alkenyl-Tethered Anilines

Denmark, S. E. & Chi, H. M., Jul 3 2017, In : Synthesis (Germany). 49, 13, p. 2873-2888 16 p.

Research output: Contribution to journalArticle

Aniline Compounds
Aniline
Styrenes
Lewis Acids
Palladium

Synthesis of 2-arylindole-4-carboxylic amides: [2(4-Fluorophenyl)-1H-indol- 4-yl]-1-pyrrolidinylmethanone

Kuethe, J. T., Beutner, G. L., Denmark, S. E. & Muhuhi, J. M., Dec 1 2009, In : Organic Syntheses. 86, p. 92-104 13 p.

Research output: Contribution to journalArticle

Amides
amides
synthesis

Synthesis of 2-substituted biaryls via Cu/Pd-catalyzed decarboxylative cross-coupling of 2-substituted potassium benzoates: 4-Methyl-2'-nitrobiphenyl and 2-acetyl-4'-methylbiphenyl: [Biphenyl, 4-Methyl-2’-nitro-] [Biphenyl, 4-Methyl-2’-acetyl-]

Gooßen, L. J., Rodríguez, N., Linder, C., Zimmermann, B., Knauber, T., Denmark, S. E. & Werner, N. S., Jan 1 2008, Organic Syntheses. Wiley Blackwell, p. 196-208 13 p. (Organic Syntheses; vol. 85).

Research output: Chapter in Book/Report/Conference proceedingChapter

cross coupling
potassium
synthesis

Synthesis of 3,4,5-trisubstituted isoxazoles via sequential [3 + 2] cycloaddition/silicon-based cross-coupling reactions

Denmark, S. E. & Kallemeyn, J. M., Apr 1 2005, In : Journal of Organic Chemistry. 70, 7, p. 2839-2842 4 p.

Research output: Contribution to journalArticle

Isoxazoles
Cycloaddition
Silicon
Nitriles
Ethers

Synthesis of 3-pyridylboronic acid and its pinacol ester. Application of 3-pyridylboronic acid in suzuki coupling to prepare 3-pyridin-3-ylquinoline [quinoline, 3-(3-pyridinyl)-]

Li, W., Nelson, D. P., Jensen, M. S., Scott Hoerrner, R., Cai, D., Larsen, R. D., Denmark, S. E., Halvorsen, G. T. & Kallemeyn, J. M., Jan 1 2005, In : Organic Syntheses. 81, p. 89-97 9 p.

Research output: Contribution to journalArticle

Esters
Acids
quinoline

Synthesis of acylsilanes from morpholine amides. Synthesis of 1-(dimethyl(phenyl)silyl)propan-1-one [dimethyl(1-oxopropyl)phenylsilane]

Lettan, R. B., Milgram, B. C., Scheidt, K. A., Denmark, S. E. & Baiazitov, R. Y., Jan 1 2007, Organic Syntheses. Wiley Blackwell, p. 22-31 10 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

Amides
morpholine

Synthesis of cis,cis,cis,cis-[5.5.5.4]-1-azafenestrane with discovery of an unexpected dyotropic rearrangement

Denmark, S. E. & Montgomery, J. I., Jun 13 2005, In : Angewandte Chemie - International Edition. 44, 24, p. 3732-3736 5 p.

Research output: Contribution to journalArticle

Cycloaddition
Carbon
Derivatives
X rays
Atoms

Synthesis of cis,cis,cis,cis-[5.5.5.5]-1-Azafenestrane

Denmark, S. E., Kramps, L. A. & Montgomery, J. I., Nov 4 2002, In : Angewandte Chemie - International Edition. 41, 21, p. 4122-4125 4 p.

Research output: Contribution to journalArticle

X ray analysis
Atoms
Carbon
Boranes
Cycloaddition

Synthesis of Cyclophanes Derived from l-Amino-3,7-dialkyl-4-methylnaphthalenes

Kemp, D. S., Garst, M. E., Harper, R. W., Cox, D. D., Carlson, D. & Denmark, S., Jan 1 1979, In : Journal of Organic Chemistry. 44, 25, p. 4469-4473 5 p.

Research output: Contribution to journalArticle

Hexanes
cyclophane 1
naphthalene

Synthesis of electron-deficient secondary phosphine oxides and secondary phosphines: Bis[3,5bis(trifluoromethyl)phenyl]phosphine oxide and bis[3,5-bis(trifluoromethyl)phenyl]phosphine

Busacca, C. A., Lorenz, J. C., Sabila, P., Haddad, N., Senandyake, C. H., Denmark, S. E. & Regens, C. S., Jan 1 2007, Organic Syntheses. Wiley Blackwell, p. 242-261 20 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

phosphine
Phosphines
phosphines
Oxides
oxides

Synthesis of phosphoramides for the lewis base-catalyzed allylation and aldol addition reactions

Denmark, S. E., Su, X., Nishigaichi, Y., Coe, D. M., Wong, K. T., Winter, S. B. D. & Choi, J. Y., Mar 19 1999, In : Journal of Organic Chemistry. 64, 6, p. 1958-1967 10 p.

Research output: Contribution to journalArticle

ethylenediamine
Phosphoramides
Lewis Bases
Allylation
Addition reactions

Synthesis of terminal 1,3-diynes via sonogashira coupling of vinylidene chloride followed by elimination. preparation of 1,3-decadiyne

Kohnen, A. L., Danheiser, R. L., Denmark, S. E. & Liu, X., Jan 1 2007, Organic Syntheses. Wiley Blackwell, p. 77-87 11 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

vinylidene
elimination
chlorides
preparation
synthesis

Synthesis of unsymmetrical biaryls from arylsilacyclobutanes

Denmark, S. E. & Wu, Z., Nov 4 1999, In : Organic Letters. 1, 9, p. 1495-1498 4 p.

Research output: Contribution to journalArticle

Cross Reactions
Palladium
Iodides
Ligands
Catalysts

Synthesis of ynamides by N-alkynylation of amine derivatives. Preparation of N-allyl-N-(methoxycarbonyl)-1,3-decadiynylamine

Kohnen, A. L., Dunetz, J. R., Danheiser, R. L., Denmark, S. E. & Liu, X., Jan 1 2007, Organic Syntheses. Wiley Blackwell, p. 88-101 14 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

amines
preparation
synthesis
Iron-Sulfur Proteins
Dimers
Catalytic Domain
Sulfur
Salts

Tandem [4+2]/[3+2] Cycloadditions

Baiazitov, R. Y. & Denmark, S. E., Feb 10 2014, Methods and Applications of Cycloaddition Reactions in Organic Syntheses. Wiley Blackwell, Vol. 9781118299883. p. 471-550 80 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Cycloaddition
Biological Products
Molecules

Tandem [4 + 2]/[3 + 2] Cycloadditions: Facile and Stereoselective Construction of Polycyclic Frameworks

Denmark, S. E., Moon, Y. C. & Senanayake, C. B. W., Jan 1 1990, In : Journal of the American Chemical Society. 112, 1, p. 311-315 5 p.

Research output: Contribution to journalArticle

Cycloaddition
Cycloaddition Reaction
Lactams
Lewis Acids
Acetals

Tandem [4+2]/[3+2]-cycloadditions. 2. Asymmetric induction with a chiral vinyl ether

Denmark, S. E., Senanayake, C. B. W. & Ginny-Dai, H., 1990, In : Tetrahedron. 46, 13-14, p. 4857-4876 20 p.

Research output: Contribution to journalArticle

Cycloaddition
Cycloaddition Reaction
Lactams
Acetals
Esters

Tandem [4+2]/[3+2] cycloadditions of nitroalkenes

Denmark, S. E. & Thorarensen, A., Jan 1 1996, In : Chemical reviews. 96, 1, p. 137-165 29 p.

Research output: Contribution to journalArticle

Cycloaddition

Tandem [4 + 2]/[3 + 2] cycloadditions of nitroalkenes. 10. Trans-2-(1-methyl-1-phenylethyl)cyclohexanol as a new auxiliary

Denmark, S. E. & Thorarensen, A., Sep 20 1996, In : Journal of Organic Chemistry. 61, 19, p. 6727-6729 3 p.

Research output: Contribution to journalArticle

Cyclohexanols
Cycloaddition

Tandem [4 + 2]/[3 + 2] cycloadditions of nitroalkenes. 11. The synthesis of (+)-crotanecine

Denmark, S. E. & Thorarensen, A., Jan 8 1997, In : Journal of the American Chemical Society. 119, 1, p. 125-137 13 p.

Research output: Contribution to journalArticle

Cycloaddition
alkaloid
Cycloaddition Reaction
ether
alcohol

Tandem [4 + 2]/[3 + 2] cycloadditions of nitroalkenes. 12. Synthesis of (-)-platynecine

Denmark, S. E., Parker, J. & Dixon, J. A., Jan 1 1997, In : Journal of Organic Chemistry. 62, 2, p. 435-436 2 p.

Research output: Contribution to journalArticle

Cycloaddition
platynecine

Tandem [4 + 2]/[3 + 2] cycloadditions of nitroalkenes. 13. The synthesis of (-)-detoxinine

Denmark, S. E., Hurd, A. R. & Sacha, H. J., Jan 1 1997, In : Journal of Organic Chemistry. 62, 6, p. 1668-1674 7 p.

Research output: Contribution to journalArticle

Cycloaddition
Silicon
Amino Acids
detoxinine
vinyl ether

Tandem [4+2]/[3+2] cycloadditions of nitroalkenes. 9. Synthesis of (-)-rosmarinecine

Denmark, S. E., Thorarensen, A. & Middleton, D. S., Sep 4 1996, In : Journal of the American Chemical Society. 118, 35, p. 8266-8277 12 p.

Research output: Contribution to journalArticle

Alkaloids
Cycloaddition
alkaloid
Cycloaddition Reaction
ether

Tandem [4 + 2]/[3 + 2] Cycloadditions with Nitroethylene

Denmark, S. E. & Hurd, A. R., May 1 1998, In : Journal of Organic Chemistry. 63, 9, p. 3045-3050 6 p.

Research output: Contribution to journalArticle

Cycloaddition
Lewis Acids
Pyrrolizidine Alkaloids
Acetals
Alkenes

Tandem cycloaddition chemistry of nitroalkenes: Probing the remarkable stereochemical influence of the Lewis acid

Denmark, S. E. & Seierstad, M., Mar 5 1999, In : Journal of Organic Chemistry. 64, 5, p. 1610-1619 10 p.

Research output: Contribution to journalArticle

Lewis Acids
Cycloaddition
Bromides
Chlorides
Titanium
Regioselectivity
Cycloaddition

Tandem double intramolecular [4+2]/[3+2] cycloadditions of nitroalkenes: construction of the pentacyclic core structure of daphnilactone B

Denmark, S. E., Baiazitov, R. Y. & Nguyen, S. T., Aug 15 2009, In : Tetrahedron. 65, 33, p. 6535-6548 14 p.

Research output: Contribution to journalArticle

Acetals
Cycloaddition
Cycloaddition Reaction
Hydrogenolysis
Hydrogenation

Tandem double intramolecular [4 + 2]/[3 + 2] cycloadditions of nitroalkenes

Denmark, S. E., Baiazitov, R. Y. & Nguyen, S. T., Jan 1 2001, In : Organic Letters. 3, 18, p. 2907-2910 4 p.

Research output: Contribution to journalArticle

Cycloaddition
Cycloaddition Reaction
cycloaddition
Bearings (structural)
Polyenes
Cycloaddition
Functional groups
Acetals
Biological Products
Alkaloids

Tandem double intramolecular [4+2]/[3+2] cycloadditions of nitroalkenes. The fused/bridged mode

Denmark, S. E. & Gomez, L., Oct 17 2003, In : Journal of Organic Chemistry. 68, 21, p. 8015-8024 10 p.

Research output: Contribution to journalArticle

Cycloaddition
Bearings (structural)
Polyenes

Tandem Inter [4 + 2]/Intra [3 + 2] Cycloadditions. 17. The Spiro Mode. Efficient and Highly Selective Synthesis of Azapropellanes

Denmark, S. E. & Middleton, D. S., Mar 6 1998, In : Journal of Organic Chemistry. 63, 5, p. 1604-1618 15 p.

Research output: Contribution to journalArticle

Cycloaddition
Acetals
Carbon
Esters
Bearings (structural)

Tandem Inter [4 + 2]/Intra [3 + 2] Cycloadditions. 3. The Stereochemical Influence of the Lewis Acid

Denmark, S. E. & Schnute, M. E., Nov 1 1991, In : Journal of Organic Chemistry. 56, 24, p. 6738-6739 2 p.

Research output: Contribution to journalArticle

Lewis Acids
Cycloaddition
vinyl ether

Tandem Inter [4 + 2]/Intra [3 + 2] Cycloadditions. 6. The Bridged Model

Denmark, S. E., Stolle, A., Dixon, J. A. & Guagnano, V., Jan 1 1995, In : Journal of the American Chemical Society. 117, 7, p. 2100-2101 2 p.

Research output: Contribution to journalArticle

Tandem inter [4+2]/intra [3+2] cycloadditions. 8. Cycloadditions with unactivated dipolarophiles

Denmark, S. E. & Senanayake, C. B. W., Aug 26 1996, In : Tetrahedron. 52, 35, p. 11579-11600 22 p.

Research output: Contribution to journalArticle

Cycloaddition
Cycloaddition Reaction
Alkenes
Bearings (structural)
Pyrrolidines

Tandem Inter [4 + 2]/Intra [3 + 2] Cycloadditions of Nitroalkenes. 15. The Bridged Mode (α-Tether)

Denmark, S. E., Guagnano, V., Dixon, J. A. & Stolle, A., Jan 1 1997, In : Journal of Organic Chemistry. 62, 14, p. 4610-4628 19 p.

Research output: Contribution to journalArticle

Cycloaddition
Alkadienes
Hydrogenation
Regioselectivity
Acetals

Tandem inter [4+2]/intra [3+2] cycloadditions of nitroalkenes. Application to the synthesis of aminocarbasugars

Denmark, S. E. & Juhl, M., Jan 1 2002, In : Helvetica Chimica Acta. 85, 11, p. 3712-3736 25 p.

Research output: Contribution to journalArticle

Acetals
Cycloaddition
Cycloaddition Reaction
cycloaddition
Stereoselectivity
Cycloaddition
Lewis Acids
Bearings (structural)
Acetals
Alkenes
Cycloaddition

Tandem Inter [4 + 2]/Intra [3 + 2] Cycloadditions of Nitroalkenes. the Bridged Mode (β-Tether)

Denmark, S. E. & Dixon, J. A., Sep 4 1998, In : Journal of Organic Chemistry. 63, 18, p. 6167-6177 11 p.

Research output: Contribution to journalArticle

Cycloaddition
Bearings (structural)
Lewis Acids
Acetals
Alkenes

Tandem Inter [4 + 2]/Intra [3 + 2] Nitroalkene Cycloadditions. 4. Cycloadditions with (E)- and (Z)-1-Propenyl Ethers

Denmark, S. E. & Senanayake, C. B. W., Jan 1 1993, In : Journal of Organic Chemistry. 58, 7, p. 1853-1858 6 p.

Research output: Contribution to journalArticle

Ethers
Cycloaddition
Ether
Lactams
Hydrogenolysis

Tandem Inter [4 + 2]/Intra [3 + 2] Nitroalkene Cycloadditions. 5. Origin of the Lewis Acid Dependent Reversal of Stereoselectivity

Denmark, S. E., Schnute, M. E. & Senanayake, C. B. W., Jan 1 1993, In : Journal of Organic Chemistry. 58, 7, p. 1859-1874 16 p.

Research output: Contribution to journalArticle

Stereoselectivity
Lewis Acids
Cycloaddition
Ethers
Lactams
Ethers
Silicon
Aldehydes
Palladium
Copper

The Chemistry of Chlorosilyl Enolates 3. Variation of the Silyl Group and the Effect on Rate and Enantiomeric Excess of Acetate Aldol Additions

Denmark, S. E. & Winter, S. B. D., Jan 1 1997, In : Synlett. 1997, 9, p. 1087-1089 3 p.

Research output: Contribution to journalArticle

Acetates
Hempa
Acetals
Enantioselectivity
3-hydroxybutanal

The Chemistry of Enoxysilacyclobutanes: Highly Selective, Uncatalyzed Aldol Additions

Denmark, S. E., Griedel, B. D. & Coe, D. M., Jan 1 1993, In : Journal of Organic Chemistry. 58, 5, p. 988-990 3 p.

Research output: Contribution to journalArticle

Acetals
Esters
Sulfhydryl Compounds
Aldehydes
Amides

The chemistry of trichlorosilyl enolates. 2. Highly-selective asymmetric aldol additions of ketone enolates

Denmark, S. E., Wong, K. T. & Stavenger, R. A., Jan 1 1997, In : Journal of the American Chemical Society. 119, 9, p. 2333-2334 2 p.

Research output: Contribution to journalArticle

Ketones
3-hydroxybutanal

The chemistry of trichlorosilyl enolates. 6. Mechanistic duality in the lewis base-catalyzed aldol addition reaction [18]

Denmark, S. E., Su, X. & Nishigaichi, Y., Dec 16 1998, In : Journal of the American Chemical Society. 120, 49, p. 12990-12991 2 p.

Research output: Contribution to journalLetter

Lewis Bases
Addition reactions
3-hydroxybutanal