Scott E Denmark

1975 …2019
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Research Output 1975 2019

Preface to volume 88

Denmark, S. E., Jan 1 2015, In : Organic Reactions. 88, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 89

Denmark, S. E., Jan 1 2016, In : Organic Reactions. 89, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 90

Denmark, S. E., Jan 1 2016, In : Organic Reactions. 90, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 91

Denmark, S. E., Jan 1 2016, In : Organic Reactions. 91, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 92

Denmark, S. E., Jan 1 2017, In : Organic Reactions. 92, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 93

Denmark, S. E., Jan 1 2017, In : Organic Reactions. 93, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 94

Denmark, S. E., Jan 1 2017, In : Organic Reactions. 94, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 95

Denmark, S. E., Jan 1 2018, In : Organic Reactions. 95, p. vii-ix

Research output: Contribution to journalEditorial

Preface to volume 96

Denmark, S. E., Jan 1 2018, In : Organic Reactions. 96, p. vii-ix

Research output: Contribution to journalEditorial

Preface to volume 97

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 97, p. vii-ix

Research output: Contribution to journalEditorial

Preface to volume 98

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 98, p. vii-x

Research output: Contribution to journalEditorial

Preface to volume 99

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 99, p. vii-ix

Research output: Contribution to journalEditorial

Preparation of 2,3-disubstituted indoles by sequential Larock heteroannulation and silicon-based cross-coupling reactions

Denmark, S. E. & Baird, J. D., Apr 18 2009, In : Tetrahedron. 65, 16, p. 3120-3129 10 p.

Research output: Contribution to journalArticle

Indoles
Cross Reactions
Silicon
Ether
Bromides

Preparation of 2-chloro-1,3 bis(dimethylamino) trimethinium hexafluorophosphate [[methanaminium, N-[2-chloro-3-(dimethylamino)-2-propenylidene]-N-methyl-, hexafluorophosphate(1-)]]

Davies, I. W., Marcoux, J. F., Taylor, J., Fan, Y. & Denmark, S. E., Jan 1 2003, In : Organic Syntheses. 80, p. 200-206 7 p.

Research output: Contribution to journalArticle

preparation

Preparation of a carbazole-based macrocycle via precipitation-driven alkyne metathesis

Zhang, W., Cho, H. M., Moore, J. S., Denmark, S. E. & Butler, C. R., Jan 1 2007, Organic Syntheses. Wiley-Blackwell, p. 177-191 15 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

carbazoles
metathesis
alkynes
preparation

Preparation of a diisopropylselenophosphoramide catalyst and its use in enantioselective sulfenoetherification

Denmark, S. E., Ryabchuk, P., Chi, H. M. & Matviitsuk, A., Jan 1 2019, In : Organic Syntheses. 96, p. 400-417 18 p.

Research output: Contribution to journalArticle

Open Access

Preparation of chiral bipyridine bis-N-oxides by oxidative dimerization of chiral pyridine N-oxides

Denmark, S. E. & Fan, Y., Feb 20 2006, In : Tetrahedron Asymmetry. 17, 4, p. 687-707 21 p.

Research output: Contribution to journalArticle

Dimerization
dimerization
Pyridine
Oxides
pyridines

Preparation of Chiral Bisoxazolines: Observations on the Effect of Substituents

Denmark, S. E., Nakajima, N., Nicaise, O. J. C., Faucher, A. M. & Edwards, J. P., Jul 1 1995, In : Journal of Organic Chemistry. 60, 15, p. 4884-4892 9 p.

Research output: Contribution to journalArticle

Amino Alcohols
Amides
Cyclization
Derivatives
Heating

Preparation of chlorosilyl enolates

Denmark, S. E., Stavenger, R. A., Winter, S. B. D., Wong, K. T. & Barsanti, P. A., Dec 11 1998, In : Journal of Organic Chemistry. 63, 25, p. 9517-9523 7 p.

Research output: Contribution to journalArticle

Ketones
Esters
Carbonyl compounds
Ethers
Sulfhydryl Compounds

Preparation of enantiomerically enriched (1S)-1-phenylpropan-1-amine hydrochloride by a catalytic addition of diorganozinc reagents to imines :[Benzenemethanamine, -ethyl-, hydrochloride, (S)-]

Desrosiers, J. N., Côté, A., Boezio, A. A., Charette, A. B., Denmark, S. E. & Montgomery, J. I., Jan 1 2006, In : Organic Syntheses. 83, p. 5-17 13 p.

Research output: Contribution to journalArticle

Preparation of enantiomerically pure (R,R)-BozPHOS: [(2R,5R)-1-{2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl}-2,5-dimethylphospholane 1-oxide]

Côté, A., Desrosiers, J. N., Boezio, A. A., Charette, A. B., Denmark, S. E. & Montgomery, J. I., Jan 1 2006, In : Organic Syntheses. 83, p. 1-4 4 p.

Research output: Contribution to journalArticle

Preparation of hexakis(4-Bromophenyl)benzene (HBB) [1,1':2',1''-Terphenyl, 4,4''-dibromo-3',4',5',6'-tetrakis(4-Bromophenyl)-]

Rathore, R., Burns, C. L., Denmark, S. E. & Fujimori, S., Jan 1 2005, In : Organic Syntheses. 82, p. 30-33 4 p.

Research output: Contribution to journalArticle

Benzene

Preparation of n-butyl 4-chlorophenyl sulfide

McWilliams, J. C., Fleitz, F. J., Zheng, N., Armstrong, J. D., Denmark, S. E. & Sweis, R. F., Jan 1 2002, In : Organic Syntheses. 79, 1 p.

Research output: Contribution to journalArticle

Sulfides

Preparative and mechanistic studies toward the rational development of catalytic, enantioselective selenoetherification reactions

Denmark, S. E., Kalyani, D. & Collins, W. R., Nov 10 2010, In : Journal of the American Chemical Society. 132, 44, p. 15752-15765 14 p.

Research output: Contribution to journalArticle

Lewis Bases
Olefins
racemization
Alkenes
Selenium

Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link

Thomas, A. A. & Denmark, S. E., Apr 15 2016, In : Science. 352, 6283, p. 329-332 4 p.

Research output: Contribution to journalArticle

Palladium
Boron
Bearings (structural)
Carbon
Boronic Acids

Principles, Definitions, Terminology, and Orbital Analysis of Lewis Base-Lewis Acid Interactions Leading to Catalysis

Denmark, S. E. & Beutner, G. L., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 1. p. 33-54 22 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Lewis Acids
Terminology
Catalysis
Quantum theory

Probing the electronic demands of transmetalation in the palladium-catalyzed cross-coupling of arylsilanolates

Denmark, S. E., Smith, R. C. & Chang, W. T. T., Jun 17 2011, In : Tetrahedron. 67, 24, p. 4391-4396 6 p.

Research output: Contribution to journalArticle

Palladium
Electrons
Nucleophiles
Cross Reactions
Silicon

Protection of diols with 4-(tert-Butyldimethylsilyloxy)Benzylidene acetal and its deprotection: (4-((4R,5R)-4,5-diphenyl-1,3-dioxolan-2-yl)phenoxy) (tertbutyl)dimethylsilane

Osajima, H., Fujiwara, H., Okano, K., Tokuyama, H., Fukuyama, T., Denmark, S. E. & Chang, W. T. T., Dec 1 2009, In : Organic Syntheses. 86, p. 130-140 11 p.

Research output: Contribution to journalArticle

acetals

Reactions of epoxides (n → σ*)

Wilson, T. W. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1113-1151 39 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Epoxy Compounds
Lewis Acids
Lewis Bases
Chemical activation
Reaction kinetics

Reagents, auxiliaries, and catalysts for C-C bond formation

Denmark, S. E. & Coates, R. M., 1999, Chichester: Wiley.

Research output: Book/ReportBook

Reagents, auxiliaries and catalysts for C-C bonds

Coates, R. M. & Denmark, S. E., 1999, Chishester, Etc: John Wiley & Sons.

Research output: Book/ReportBook

Recent advances in catalytic asymmetric epoxidation of trisubstituted and trans-olefins

Dakin, L. A., Panek, J. S., Shi, Y., Wang, Z. X., Tu, Y., Frohn, M., Shi, Y., Wang, Z. X., Tu, Y., Frohn, M., Zhang, J. R., Shi, Y., Denmark, S. E., Forfaes, D. C., Hays, D. S., DePue, J., Wilde, R. G., Denmark, S. E., Wu, Z., Crudden, C. M. & 1 others, Matsuhashi, H., Jun 1 1998, In : Chemtracts. 11, 7, p. 531-536 6 p.

Research output: Contribution to journalComment/debate

Epoxidation
Alkenes

Redefining q: Quaternary ammonium cross sectional area (XSA) as a general descriptor for transport-limiting PTC rate approximations

Denmark, S. E. & Henle, J. J., Apr 1 2015, In : Chemical Science. 6, 4, p. 2211-2218 8 p.

Research output: Contribution to journalArticle

Ammonium Compounds
Catalysis
Ions
Alkylation
Catalysts

Reduction of allylpalladium(II)chloride dimer by formation of allyloxysilanes

Denmark, S. E. & Smith, R. C., Nov 3 2006, In : Synlett. 18, p. 2921-2928 8 p.

Research output: Contribution to journalArticle

Dimers
Chlorides
Alkali Metals
Chelation
Ligands

Reinvestigation of a Catalytic, Enantioselective Alkene Dibromination and Chlorohydroxylation

Denmark, S. E. & Carson, N., Nov 13 2015, In : Organic Letters. 17, 23, p. 5728-5731 4 p.

Research output: Contribution to journalArticle

Enantioselectivity
Alkenes
Nuclear magnetic resonance spectroscopy
alkenes
High Pressure Liquid Chromatography
Acetals
Oxazines
Cycloaddition
X ray crystallography
X Ray Crystallography

Room Temperature, Reductive Alkylation of Activated Methylene Compounds: Carbon-Carbon Bond Formation Driven by the Rhodium-Catalyzed Water-Gas Shift Reaction

Denmark, S. E., Ibrahim, M. Y. S. & Ambrosi, A., Jan 6 2017, In : ACS Catalysis. 7, 1, p. 613-630 18 p.

Research output: Contribution to journalArticle

Rhodium
Water gas shift
Alkylation
Carbon
Alkylating Agents

Selective extraction of supported Rh nanoparticles under mild, non-acidic conditions with carbon monoxide

Ibrahim, M. Y. S. & Denmark, S. E., Jan 1 2018, In : Journal of Materials Chemistry A. 6, 37, p. 18075-18083 9 p.

Research output: Contribution to journalArticle

Rhodium
Carbon Monoxide
Carbon monoxide
Nanoparticles
Leaching

Sequential cross-coupling of 1,4-bissilylbutadienes: Synthesis of unsymmetrical 1,4-disubstituted 1,3-butadienes

Denmark, S. E. & Tymonko, S. A., Jun 8 2005, In : Journal of the American Chemical Society. 127, 22, p. 8004-8005 2 p.

Research output: Contribution to journalArticle

Butadiene
electron
Electrons
halide
1,3-butadiene

Sequential processes in palladium-catalyzed silicon-based cross-coupling

Denmark, S. E. & Liu, J. H. C., Dec 1 2010, In : Israel Journal of Chemistry. 50, 5-6, p. 577-587 11 p.

Research output: Contribution to journalReview article

Palladium
Silicon
Substrates
Biological Products
Toxicity
Siloxanes
Ethers
Cross Reactions
Styrenes
Bearings (structural)
Styrenes
Bearings (structural)
Siloxanes
Ethers
metathesis

Sequential silylcarbocyclization/silicon-based cross-coupling reactions

Denmark, S. E. & Liu, J. H. C., Mar 28 2007, In : Journal of the American Chemical Society. 129, 12, p. 3737-3744 8 p.

Research output: Contribution to journalArticle

rhodium
Rhodium
Cross Reactions
palladium
Palladium

Silicon-based cross-coupling reactions in the total synthesis of natural products

Denmark, S. E. & Liu, J. H. C., Apr 12 2010, In : Angewandte Chemie - International Edition. 49, 17, p. 2978-2986 9 p.

Research output: Contribution to journalReview article

Silicon
Biological Products
Carbon
Transition metals
Molecules

Silicon-Directed Nazarov Cyclization

Denmark, S. E. & Jones, T. K., Jan 1 1982, In : Journal of the American Chemical Society. 104, 9, p. 2642-2645 4 p.

Research output: Contribution to journalArticle

Cyclization
Silicon

Silicon-directed Nazarov cyclizations. 8. Stereoelectronic control of torquoselectivity

Denmark, S. E., Wallace, M. A. & Walker, C. B., Dec 1 1990, In : Journal of Organic Chemistry. 55, 21, p. 5543-5545 3 p.

Research output: Contribution to journalArticle

Cyclization
Silicon
Carbon
Stereoselectivity
Ketones

Silicon‐Directed Nazarov Cyclizations. Part V. Substituent and heteroatom effects on the reaction

Denmark, S. E., Habermas, K. L. & Hite, G. A., Feb 3 1988, In : Helvetica Chimica Acta. 71, 1, p. 168-194 27 p.

Research output: Contribution to journalArticle

Cyclization
ketones
Ketones
cyclobutane
Cyclobutanes

Silicon‐Directed Nazarov Cyclizations. Part VI. The anomalous cyclization of vinyl dienyl ketones

Denmark, S. E. & Hite, G. A., Feb 3 1988, In : Helvetica Chimica Acta. 71, 1, p. 195-208 14 p.

Research output: Contribution to journalArticle

Cyclization
Ketones
ketones
Cations
Positive ions

Silicon-directed nazarov cyclizations-IV. Further studies in stereochemical control

Denmark, S. E., Habermas, K. L., Hite, G. A. & Jones, T. K., 1986, In : Tetrahedron. 42, 11, p. 2821-2829 9 p.

Research output: Contribution to journalArticle

Cyclization
Silicon
Bearings (structural)
Stereoselectivity
Isomers