Scott E Denmark

1975 …2020
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Research Output 1975 2020

On the stereochemical course of the addition of allylsilanes to aldehydes

Denmark, S. E., Weber, E. J., Almstead, N. G. & Wolf, L. M., Sep 16 2012, In : Tetrahedron. 68, 37, p. 7701-7718 18 p.

Research output: Contribution to journalArticle

Cyclization
Aldehydes
Lewis Acids
allylsilane

On the stereochemistry of allylmetal‐aldehyde condensations. Preliminary communication

Denmark, S. E. & Weber, E. J., Sep 21 1983, In : Helvetica Chimica Acta. 66, 6, p. 1655-1660 6 p.

Research output: Contribution to journalArticle

Stereochemistry
Chemical bonds
Cyclization
stereochemistry
Fluorides

On the stereochemistry of the SN' reaction

Denmark, S. E., 1980, S, L: [s.n.].

Research output: Book/ReportBook

On the Stereoselective Opening of Achiral Dioxane Acetals

Denmark, S. E. & Almstead, N. G., Oct 1 1991, In : Journal of Organic Chemistry. 56, 22, p. 6458-6467 10 p.

Research output: Contribution to journalArticle

Acetals
Lewis Acids
Ions
Isomerization
Stoichiometry

On the Stereoselective Opening of Chiral Dioxane Acetals. Nucleophile Dependence

Denmark, S. E. & Almstead, N. G., Nov 1 1991, In : Journal of Organic Chemistry. 56, 23, p. 6485-6487 3 p.

Research output: Contribution to journalArticle

Allylation
Acetals
Nucleophiles
1,4-dioxane

Organic chemistry: Catalysts break symmetry

Denmark, S. E., Sep 7 2006, In : Nature. 443, 7107, p. 40-41 2 p.

Research output: Contribution to journalShort survey

Organic Chemistry
Synthetic Chemistry Techniques

Organic reactions

Denmark, S. E., 2009, Oxford: Wiley-Blackwell.

Research output: Book/ReportBook

Organic reactions. Vol. 73

Denmark, S. E., 2009, Oxford: Wiley-Blackwell.

Research output: Book/ReportBook

Organic reactions. Volume 74

Denmark, S. E., 2009, Oxford: Wiley-Blackwell.

Research output: Book/ReportBook

Organic reactions. Volume 76

Denmark, S. E., 2012, Hoboken, N, J: Wiley.

Research output: Book/ReportBook

Organic reactions. Volume 77

Denmark, S. E., 2012, Hoboken, N, J: Wiley-Blackwell.

Research output: Book/ReportBook

Organic reactions. Volume 78

Denmark, S. E., 2012, Hoboken, N, J: Wiley.

Research output: Book/ReportBook

Organic syntheses. Volume 85, 2008

Denmark, S. E., 2008, Hoboken, N, J: Wiley.

Research output: Book/ReportBook

Organic Synthesis: Wherefrom and Whither? (Some Very Personal Reflections)

Denmark, S. E., Feb 2018, In : Israel Journal of Chemistry. 58, 1, p. 61-72 12 p.

Research output: Contribution to journalArticle

Steroid hormones
Oral Contraceptives
Biological Products
Health
Molecules

Organocerium additions to chiral α,α-dialkoxy hydrazones: Asymmetric synthesis of JV-protected a-amino acetals and α-amino aldehydes

Denmark, S. E. & Nicaise, O., May 1993, In : Synlett. 1993, 5, p. 359-361 3 p.

Research output: Contribution to journalArticle

Hydrazones
Acetals
Aldehydes
Carbamates
Lithium

Organocerium Additions to Hydrazones: Effects of Reagent Stoichiometry on Efficiency and Selectivity

Denmark, S. E., Edwards, J. P. & Nicaise, O., Jan 1 1993, In : Journal of Organic Chemistry. 58, 3, p. 569-578 10 p.

Research output: Contribution to journalArticle

Hydrazones
Stoichiometry
Nucleophiles
Organometallics
Amines

Organocerium additions to proline-derived hydrazones: Synthesis of enantiomerically enriched amines

Denmark, S. E., Edwards, J. P., Weber, T. & Piotrowski, D. W., May 17 2010, In : Tetrahedron Asymmetry. 21, 9-10, p. 1278-1302 25 p.

Research output: Contribution to journalArticle

Bearings (structural)
Hydrazones
hydrazones
Proline
Amines

Organocerium Additions to SAMP-Hydrazones: General Synthesis of Chiral Amines

Denmark, S. E., Weber, T. & Piotrowski, D. W., Apr 1 1987, In : Journal of the American Chemical Society. 109, 7, p. 2224-2225 2 p.

Research output: Contribution to journalArticle

Organoselenium-catalyzed enantioselective syn-dichlorination of unbiased alkenes

Gilbert, B. B., Eey, S. T. C., Ryabchuk, P., Garry, O. & Denmark, S. E., Aug 2 2019, In : Tetrahedron. 75, 31, p. 4086-4098 13 p.

Research output: Contribution to journalArticle

Alkenes
Synthetic Chemistry Techniques
Biological Products
Chlorides
Kinetics

Organosilicon Compounds in Cross-Coupling Reactions

Denmark, S. E. & Sweis, R. F., Nov 30 2013, Metal Catalyzed Cross-Coupling Reactions and More. Wiley-VCH Verlag, Vol. 3. p. 475-532 58 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Fluorine compounds
Silicon compounds

Organosilicon Reagents: Synthesis and Application to Palladium-Catalyzed Cross-Coupling Reactions

Denmark, S. E. & Ober, M. H., Dec 1 2003, In : Aldrichimica Acta. 36, 3, p. 75-85 11 p.

Research output: Contribution to journalReview article

Palladium
Rhodium
Palladium
Aldehydes
Catalysis
Carbonylation

Palladium- (and nickel-) catalyzed vinylation of aryl halides

Denmark, S. E. & Butler, C. R., Jan 1 2009, In : Chemical Communications. 1, p. 20-33 14 p.

Research output: Contribution to journalReview article

Styrenes
Palladium
Nickel
Styrene
Functional polymers

Palladium-catalyzed conjugate addition of organosiloxanes to α,β-unsaturated carbonyl compounds and nitroalkenes

Denmark, S. E. & Amishiro, N., Sep 5 2003, In : Journal of Organic Chemistry. 68, 18, p. 6997-7003 7 p.

Research output: Contribution to journalArticle

Silicon Compounds
Carbonyl compounds
Palladium
Ketones
Aldehydes

Palladium catalyzed cross-coupling of (Z)-1-heptenyldimethylsilanol with 4-iodoanisole: (Z)-1-Heptenyl-4-methoxybenzene: [Benzene,1-(1Z)-1-heptenyl-4-methoxy-]

Denmark, S. E., Wang, Z., Campbell, M. & Curran, D. P., Jan 1 2005, In : Organic Syntheses. 81, p. 42-53 12 p.

Research output: Contribution to journalArticle

Palladium-catalyzed cross-coupling of five-membered heterocyclic silanolates

Denmark, S. E., Baird, J. D. & Regens, C. S., Feb 15 2008, In : Journal of Organic Chemistry. 73, 4, p. 1440-1455 16 p.

Research output: Contribution to journalArticle

Alkali Metals
Palladium
Iodides
Bromides
Chlorides

Palladium-catalyzed cross-coupling of five-membered heterocyclic silanolates

Denmark, S. E., Baird, J. & Regens, C., Mar 2010, In : Chemtracts. 23, 2, p. 41-46 6 p.

Research output: Contribution to journalReview article

Cross Reactions
Palladium
Alkali Metals
Iodides
Derivatives

Palladium-catalyzed cross-coupling reactions of 2-indolyldimethylsilanols with substituted aryl halides

Denmark, S. E. & Baird, J. D., Sep 30 2004, In : Organic Letters. 6, 20, p. 3649-3652 4 p.

Research output: Contribution to journalArticle

cross coupling
Cross Reactions
Palladium
Iodides
iodides

Palladium-catalyzed cross-coupling reactions of heterocyclic silanolates with substituted aryl iodides and bromides

Denmark, S. E. & Baird, J. D., Feb 16 2006, In : Organic Letters. 8, 4, p. 793-795 3 p.

Research output: Contribution to journalArticle

cross coupling
Cross Reactions
Palladium
Iodides
Bromides

Palladium-catalyzed cross-coupling reactions of organosilanols and their salts: Practical alternatives to boron- and tin-based methods

Denmark, S. E. & Regens, C. S., Nov 1 2008, In : Accounts of chemical research. 41, 11, p. 1486-1499 14 p.

Research output: Contribution to journalReview article

Boron
Tin
Palladium
Silicon
Salts

Palladium-catalyzed cross-coupling reactions of silanolates: A paradigm shift in silicon-based cross-coupling reactions

Denmark, S. E. & Baird, J. D., Jun 23 2006, In : Chemistry - A European Journal. 12, 19, p. 4954-4963 10 p.

Research output: Contribution to journalArticle

Palladium
Silicon
Patents and inventions
Fluorides
Chemical activation

Palladium-catalyzed cross-coupling reactions of substituted aryl(dimethyl)silanols

Denmark, S. E. & Ober, M. H., Dec 1 2004, In : Advanced Synthesis and Catalysis. 346, 13-15, p. 1703-1714 12 p.

Research output: Contribution to journalArticle

Palladium
Cesium
Electrons
Iodides
Bromides

Palladium-Catalyzed Silylation of Aryl Bromides Leading to Functionalized Aryldimethylsilanols

Denmark, S. E. & Kallemeyn, J. M., Sep 18 2003, In : Organic Letters. 5, 19, p. 3483-3486 4 p.

Research output: Contribution to journalArticle

Ethers
Palladium
Bromides
palladium
bromides

Palladium-Promoted Intramolecular Addition of an Aryl Iodide to a Nitroalkene

Denmark, S. E. & Schnute, M. E., Feb 1 1995, In : Journal of Organic Chemistry. 60, 4, p. 1013-1019 7 p.

Research output: Contribution to journalArticle

Cyclization
Palladium
Iodides
Alkenes
Isomerization

Phosphine oxides as stabilizing ligands for the palladium-catalyzed cross-coupling of potassium aryldimethylsilanolates

Denmark, S. E., Smith, R. C. & Tymonko, S. A., Jun 25 2007, In : Tetrahedron. 63, 26, p. 5730-5738 9 p.

Research output: Contribution to journalArticle

phosphine
Palladium
Bromides
Oxides
Potassium

Potassium Trimethylsilanolate Enables Rapid, Homogeneous Suzuki-Miyaura Cross-Coupling of Boronic Esters

Delaney, C. P., Kassel, V. M. & Denmark, S. E., Jan 1 2019, (Accepted/In press) In : ACS Catalysis. p. 73-80 8 p.

Research output: Contribution to journalArticle

Potassium
Esters
potassium trimethylsilanolate

Prediction of higher-selectivity catalysts by computer-driven workflow and machine learning

Zahrt, A. F., Henle, J. J., Rose, B. T., Wang, Y., Darrow, W. T. & Denmark, S. E., Jan 18 2019, In : Science. 363, 6424, eaau5631.

Research output: Contribution to journalArticle

Workflow
Empiricism
Sulfhydryl Compounds
Machine Learning
Support Vector Machine

Preface

Vedejs, E. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 1-3. p. xxvii-xxxii

Research output: Chapter in Book/Report/Conference proceedingForeword/postscript

Speech synthesis

Preface

Denmark, S. E., Feb 27 2007, Topics in Stereochemistry. Wiley, p. xi-xii

Research output: Chapter in Book/Report/Conference proceedingForeword/postscript

Preface

Denmark, S. E., Feb 27 2007, Topics in Stereochemistry. Wiley, p. xi-xii

Research output: Chapter in Book/Report/Conference proceedingForeword/postscript

Preface

Denmark, S. E., 1992, In : Tetrahedron. 48, 11, 1 p.

Research output: Contribution to journalEditorial

Preface for volume 100

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 100, p. xxi-xxvii

Research output: Contribution to journalEditorial

Preface to special issue of heterocycles honoring the 85th birthday of prof. Dr. Albert eschenmoser

Denmark, S. E. & Sorensen, E. J., Dec 1 2010, In : Heterocycles. 82, 1, p. 5-10 6 p.

Research output: Contribution to journalReview article

Preface to volume 82

Denmark, S. E., 2013, In : Organic Reactions. 82, 1, p. Vii-Viii

Research output: Contribution to journalEditorial

Preface to volume 83

Denmark, S. E., 2014, In : Organic Reactions. 83, 1, p. Vii-Viii

Research output: Contribution to journalEditorial

Preface to volume 84

Denmark, S. E., Jan 1 2014, In : Organic Reactions. 84, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 85

Denmark, S. E., Jan 1 2014, In : Organic Reactions. 85, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 86

Denmark, S. E., Jan 1 2015, In : Organic Reactions. 86, 1, p. vii-viii

Research output: Contribution to journalEditorial