Scott E Denmark

1975 …2019
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Research Output 1975 2019

Enantioselective total syntheses of (+)-castanospermine, (+)-6- epicastanospermine, (+)-australine, and (+)-3-epiaustraline

Denmark, S. E. & Martinborough, E. A., Apr 7 1999, In : Journal of the American Chemical Society. 121, 13, p. 3046-3056 11 p.

Research output: Contribution to journalArticle

Alkaloids
Acetals
Cycloaddition
alkaloid
Indolizidines
Aldehydes
Organic Chemistry
Cyclohexanols
Cycloaddition
Organic Chemistry

Evaluating continuous chirality measure as a 3D descriptor in chemoinformatics applied to asymmetric catalysis

Zahrt, A. F. & Denmark, S. E., Mar 29 2019, In : Tetrahedron. 75, 13, p. 1841-1851 11 p.

Research output: Contribution to journalArticle

Chirality
Catalysis
Catalysts
Forests

ExCage

Dale, E. J., Vermeulen, N. A., Thomas, A. A., Barnes, J. C., Juríček, M., Blackburn, A. K., Strutt, N. L., Sarjeant, A. A., Stern, C. L., Denmark, S. E. & Stoddart, J. F., Jul 30 2014, In : Journal of the American Chemical Society. 136, 30, p. 10669-10682 14 p.

Research output: Contribution to journalArticle

Polycyclic Aromatic Hydrocarbons
Polycyclic aromatic hydrocarbons
PAH
Pyrene
Complexation

Facile Oxetane Formation in a Rigid Bicyclo[2.2.2]octane System

Denmark, S. E., Jul 1981, In : Journal of Organic Chemistry. 46, 15, p. 3144-3147 4 p.

Research output: Contribution to journalArticle

Fluoride-free cross-coupling of organosilanols

Denmark, S. E. & Sweis, R. F., Oct 9 2001, In : Journal of the American Chemical Society. 123, 26, p. 6439-6440 2 p.

Research output: Contribution to journalLetter

Fluorides

Fluoride-Promoted Cross-Coupling Reactions of Alkenylsilanols. Elucidation of the Mechanism through Spectroscopic and Kinetic Analysis

Denmark, S. E., Sweis, R. F. & Wehrli, D., Apr 21 2004, In : Journal of the American Chemical Society. 126, 15, p. 4865-4875 11 p.

Research output: Contribution to journalArticle

Cross Reactions
Fluorides
fluoride
Palladium
palladium

Formation of γ-keto esters from β-keto esters: Methyl 5,5-dimethyl-4-oxohexanoate: [Hexanoic acid, 5,5-dimethyl-4-oxo-, methyl ester]

Ronsheim, M. D., Hilgenkamp, R. K., Zercher, C. K., Denmark, S. E. & Beutner, G. L., Jan 1 2002, In : Organic Syntheses. 79, 1 p.

Research output: Contribution to journalArticle

esters
Esters
acids
hexanoic acid

Generation and [2+2] cycloadditions of thio-substituted ketenes: trans-1-(4-methoxyphenyl)-4-phenyl-3-(phenylthio)azetidin-2-one [(2-azetidinone, 1-(4-methoxyphenyl)-4-phenyl-3-(phenylthio)-, trans-)]

Danheiser, R. L., Okamoto, I., Lawlor, M. D., Lee, T. W., Denmark, S. E. & Ober, M. H., Jan 1 2003, In : Organic Syntheses. 80, p. 160-171 12 p.

Research output: Contribution to journalArticle

ketenes
Cycloaddition
cycloaddition
2-azetidinone

Generation and cyclization of 5-hexenyllithium: 2-cyclopentylacetophenone: (ethanone, 2-cyclopentyl-1-phenyl-)

Bailey, W. F., Luderer, M. R., Mealy, M. J., Punzalan, E. R., Denmark, S. E. & Macneil, S. L., Jan 1 2005, In : Organic Syntheses. 81, p. 121-133 13 p.

Research output: Contribution to journalArticle

Generation of ynolate and Z-selective olefination of acylsilanes: (Z)-2-methyl-3-trimethylsilyl-2-butenoic acid: ((Z)-2-butenoic acid, 2-methyl-3-trimethylsilyl-)

Shindo, M., Matsumoto, K., Shishido, K., Denmark, S. E. & Eklov, B. M., Jan 1 2007, Organic Syntheses. Wiley Blackwell, p. 11-21 11 p. (Organic Syntheses; vol. 84).

Research output: Chapter in Book/Report/Conference proceedingChapter

Harnessing the Power of the Water-Gas Shift Reaction for Organic Synthesis

Ambrosi, A. & Denmark, S. E., Jan 1 2016, In : Angewandte Chemie - International Edition. 55, 40, p. 12164-12189 26 p.

Research output: Contribution to journalReview article

Water gas shift
Carbon Monoxide
Ammonia
Catalysis
Hydrogenation

Highly 1,4-syn diastereoselective, phosphoramide-catalyzed aldol additions of chiral methyl ketone enolates

Denmark, S. E. & Stavenger, R. A., Dec 11 1998, In : Journal of Organic Chemistry. 63, 25, p. 9524-9527 4 p.

Research output: Contribution to journalArticle

Ketones
3-hydroxybutanal
phosphoramide

Highly diastereoselective aldol additions of a chiral ethyl ketone enolate under Lewis base catalysis

Denmark, S. E. & Pham, S. M., Jul 12 2001, In : Organic Letters. 3, 14, p. 2201-2204 4 p.

Research output: Contribution to journalArticle

Bearings (structural)
Hempa
Lewis Bases
Stereoselectivity
Lewis base

Highly stereoselective hydrocarbation of terminal alkynes via Pt-Catalyzed Hydrosilylation/Pd-Catalyzed cross-coupling reactions

Denmark, S. E. & Wang, Z., Apr 5 2001, In : Organic Letters. 3, 7, p. 1073-1076 4 p.

Research output: Contribution to journalArticle

Hydrosilylation
Alkynes
cross coupling
Cross Reactions
alkynes

Highly stereospecific, cross-coupling reactions of alkenylsilacyclobutanes

Denmark, S. E. & Choi, J. Y., Jun 23 1999, In : Journal of the American Chemical Society. 121, 24, p. 5821-5822 2 p.

Research output: Contribution to journalArticle

Highly stereospecific, palladium-catalyzed cross-coupling of alkenylsilanols

Denmark, S. E. & Wehrli, D., Feb 24 2000, In : Organic Letters. 2, 4, p. 565-568 4 p.

Research output: Contribution to journalArticle

cross coupling
Palladium
palladium
Bearings (structural)
Stereoselectivity

Inter- and intramolecular [4+2] cycloaddition of nitroalkenes with allenylsilanes. A case of unexpected regioselectivity

Denmark, S. E. & Gomez, L., Nov 22 2002, In : Heterocycles. 58, p. 129-136 8 p.

Research output: Contribution to journalArticle

Regioselectivity
Acetals
Cycloaddition
Cycloaddition Reaction
Carbon

Inter-and Intramolecular [4 + 2] Cycloadditions of Nitroalkenes with Olefins. 2-Nitrostyrenes

Denmark, S. E., Kesler, B. S. & Moon, Y. C., Aug 1 1992, In : Journal of Organic Chemistry. 57, 18, p. 4912-4924 13 p.

Research output: Contribution to journalArticle

Lewis Acids
Cycloaddition
Alkenes
Cycloparaffins

Intermolecular [4 + 2]‐Cycloadditions of Nitroalkenes with Cyclic Olefins. Transformations of Cyclic Nitronates

Denmark, S. E., Cramer, C. J. & Sternberg, J. A., Dec 10 1986, In : Helvetica Chimica Acta. 69, 8, p. 1971-1989 19 p.

Research output: Contribution to journalArticle

Cycloparaffins
Cycloaddition
Cycloaddition Reaction
cycloaddition
alkenes

Intramolecular [4 + 2] cycloaddition of nitroalkenes for construction of vicinal quaternary stereocenters

Denmark, S. E. & Baiazitov, R. Y., Dec 8 2005, In : Organic Letters. 7, 25, p. 5617-5620 4 p.

Research output: Contribution to journalArticle

Cycloaddition
Cycloaddition Reaction
cycloaddition
dienes
alkenes

Intramolecular [4 + 2] Cycloadditions of (Z)-α,β-Unsaturated Aldehydes with Vinyl Sulfides and Ketene Dithioacetals

Denmark, S. E. & Sternberg, J. A., Jan 1 1986, In : Journal of the American Chemical Society. 108, 26, p. 8277-8279 3 p.

Research output: Contribution to journalArticle

Cycloaddition
Cycloaddition Reaction
Sulfides
Aldehydes
ketene

Intramolecular [4 + 2] Cycloadditions of Nitroalkenes with Olefins

Denmark, S. E., Dappen, M. S. & Cramer, C. J., Jan 1 1986, In : Journal of the American Chemical Society. 108, 6, p. 1306-1307 2 p.

Research output: Contribution to journalArticle

Cycloaddition
Cycloaddition Reaction
Alkenes
Olefins

Intramolecular [4+2]-cycloadditions of nitroalkenes with olefins. 2

Denmark, S. E., Moon, Y. C., Cramer, C. J., Dappen, M. S. & Senanayake, C. B. W., 1990, In : Tetrahedron. 46, 21, p. 7373-7392 20 p.

Research output: Contribution to journalArticle

Cycloaddition
Cycloaddition Reaction
Alkenes
Stereochemistry
Fusion reactions

Intramolecular [4 + 2] Cycloadditions of Nitrosoalkenes with Olefins

Denmark, S. E., Dappen, M. S. & Sternberg, J. A., Jun 1984, In : Journal of Organic Chemistry. 49, 24, p. 4741-4743 3 p.

Research output: Contribution to journalArticle

Oximes
Cycloaddition
Alkenes

Intramolecular [4 + 2]-Cycloadditions of Vinylnitrosonium Cations with Olefins

Denmark, S. E., Cramer, C. J. & Dappen, M. S., Mar 1 1987, In : Journal of Organic Chemistry. 52, 5, p. 877-887 11 p.

Research output: Contribution to journalArticle

Cycloaddition
Alkenes
Cations
Nuclear magnetic resonance
Potassium Cyanide
Hydrosilylation
cross coupling
Silicon
alcohols
Alcohols

Intramolecular hydrosilylation and silicon-assisted cross-coupling: An efficient route to trisubstituted homoallylic alcohols

Denmark, S. E. & Weitao, P., Jan 11 2001, In : Organic Letters. 3, 1, p. 61-64 4 p.

Research output: Contribution to journalArticle

Hydrosilylation
cross coupling
Silicon
alcohols
routes

Intramolecular silicon-assisted cross-coupling: Total synthesis of (+)-brasilenyne

Denmark, S. E. & Yang, S. M., Dec 25 2002, In : Journal of the American Chemical Society. 124, 51, p. 15196-15197 2 p.

Research output: Contribution to journalArticle

Acetylene
Cross Reactions
acetylene
Silicon
silicon
Bearings (structural)
Siloxanes
Cross Reactions
Silicon
silicon
Hydrosilylation
cross coupling
Cross Reactions
Iodides
Silicon

Introduction to the series

Denmark, S. E., Feb 27 2007, Topics in Stereochemistry. Wiley, p. vii

Research output: Chapter in Book/Report/Conference proceedingForeword/postscript

Introduction to the series

Denmark, S. E., Feb 27 2007, Topics in Stereochemistry. Wiley, p. vii

Research output: Chapter in Book/Report/Conference proceedingForeword/postscript

Introduction to the Series

Denmark, S. E. & Siegel, J. S., May 5 2006, Topics in Stereochemistry. Wiley Blackwell, Vol. 25. p. v

Research output: Chapter in Book/Report/Conference proceedingForeword/postscript

Investigating the Enantiodetermining Step of a Chiral Lewis Base Catalyzed Bromocycloetherification of Privileged Alkenes

Böse, D. & Denmark, S. E., Mar 1 2018, In : Synlett. 29, 4, p. 433-439 7 p., st-2017-b0700-c.

Research output: Contribution to journalArticle

Lewis Bases
Alkenes
Catalysts
Substrates

Investigations into transition-state geometry in the Mukaiyama directed aldol reaction

Denmark, S. E. & Lee, W., Feb 1 2008, In : Chemistry - An Asian Journal. 3, 2, p. 327-341 15 p.

Research output: Contribution to journalArticle

Silanes
Cyclization
Lewis Acids
Geometry
Tin

Investigations on Transition-State Geometry in the Aldol Condensation

Denmark, S. E. & Henke, B. R., Jan 1 1991, In : Journal of the American Chemical Society. 113, 6, p. 2177-2194 18 p.

Research output: Contribution to journalArticle

Cyclization
condensation
Condensation
geometry
Geometry

Investigations on Transition-State Geometry in the Aldol Condensation

Denmark, S. E. & Henke, B. R., Sep 1 1989, In : Journal of the American Chemical Society. 111, 20, p. 8032-8034 3 p.

Research output: Contribution to journalArticle

Condensation
Geometry
3-hydroxybutanal

Investigations on Transition-State Geometry in the Lewis Acid- (Mukaiyama) and Fluoride-Promoted Aldol Reactions

Denmark, S. E. & Lee, W., Feb 1 1994, In : Journal of Organic Chemistry. 59, 4, p. 707-709 3 p.

Research output: Contribution to journalArticle

Lewis Acids
Fluorides
Geometry
Cyclization
Ions

Investigations on transition state geometry of the aldol condensation in aqueous medium

Denmark, S. E. & Lee, W., Dec 8 1993, In : Tetrahedron Letters. 33, 50, p. 7729-7732 4 p.

Research output: Contribution to journalArticle

Condensation
Water content
Geometry
Acids
Water

Iron-catalyzed cross-coupling of unactivated secondary alkyl thio ethers and sulfones with aryl grignard reagents

Denmark, S. E. & Cresswell, A. J., Dec 20 2013, In : Journal of Organic Chemistry. 78, 24, p. 12593-12628 36 p.

Research output: Contribution to journalArticle

Sulfones
Ethers
Iron
Sulfur Compounds
Nucleophiles
Lewis Bases
Lewis base
Ethers
ethers
divergence

Lewis acid-promoted conjugate addition of dienol silyl ethers to nitroalkenes: Synthesis of 3-substituted azepanes

Denmark, S. E. & Xie, M., Aug 31 2007, In : Journal of Organic Chemistry. 72, 18, p. 7050-7053 4 p.

Research output: Contribution to journalArticle

Lewis Acids
Ethers

Lewis base activation of lewis acids: Development of a lewis base catalyzed selenolactonization

Denmark, S. E. & Collins, W. R., Sep 13 2007, In : Organic Letters. 9, 19, p. 3801-3804 4 p.

Research output: Contribution to journalArticle

Lewis Bases
Lewis Acids
Lewis base
Chemical activation
activation

Lewis base activation of Lewis acids: Vinylogous aldol additions of silyl dienol ethers to aldehydes

Denmark, S. E. & Heemstra, J. R., Nov 3 2004, In : Synlett. 13, p. 2411-2416 6 p.

Research output: Contribution to journalArticle

Lewis Bases
Lewis Acids
Ethers
Aldehydes
Chemical activation

Lewis base activation of Lewis acids: Catalytic enantioselective glycolate aldol reactions

Denmark, S. E. & Chung, W. J., Feb 22 2008, In : Angewandte Chemie - International Edition. 47, 10, p. 1890-1892 3 p.

Research output: Contribution to journalArticle

glycolic acid
Lewis Bases
Lewis Acids
Acetals
Enantioselectivity

Lewis base activation of Lewis acids: Catalytic, enantioselective vinylogous aldol addition reactions

Denmark, S. E. & Heemstra, J. R., Jul 20 2007, In : Journal of Organic Chemistry. 72, 15, p. 5668-5688 21 p.

Research output: Contribution to journalArticle

Lewis Bases
Lewis Acids
Addition reactions
Ketones
Aldehydes