Scott E Denmark

1975 …2019
If you made any changes in Pure, your changes will be visible here soon.

Research Output 1975 2019

Benzyl isopropoxymethyl carbamate - An aminomethylating reagent for mannich reactions of titanium enolates

Meyer, H., Beck, A. K., Sebesta, R., Seebach, D., Denmark, S. E. & Wilson, T. W., Jan 1 2008, Organic Syntheses. Wiley-Blackwell, p. 287-294 8 p. (Organic Syntheses; vol. 85).

Research output: Chapter in Book/Report/Conference proceedingChapter

reagents
titanium

Bifunctional and Synergistic Catalysis: Lewis Acid Catalysis and Lewis Base-Assisted Bond Polarization (n → σ*)

Chung, W. J. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1213-1258 46 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Lewis Acids
Catalysis
Polarization
Chemical activation

Bifunctional Lewis Base Catalysis With Dual Activation of X3Si Nu and C=O(n → σ*)

Fu, J., Fujimori, S. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 1. p. 281-338 58 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Catalysis
Chemical activation
Phosphoramides
Catalysts

Carbanion-accelerated claisen rearrangements: Asymmetric induction with chiral phosphorus-stabilized anions

Denmark, S. E., Marlin, J. E. & Rajendra, G., Jan 4 2013, In : Journal of Organic Chemistry. 78, 1, p. 66-82 17 p.

Research output: Contribution to journalArticle

Phosphorus
Anions
Oxides
Metals
Temperature

Carbanion-Accelerated Claisen Rearrangements

Denmark, S. E. & Harmata, M. A., Jan 1 1982, In : Journal of the American Chemical Society. 104, 18, p. 4972-4974 3 p.

Research output: Contribution to journalArticle

Carbanion-Accelerated Claisen Rearrangements. 2. Studies on Internal Asymmetric Induction

Denmark, S. E. & Harmata, M. A., Sep 1983, In : Journal of Organic Chemistry. 48, 19, p. 3369-3370 2 p.

Research output: Contribution to journalArticle

Temperature
Hot Temperature

Carbanion-Accelerated Claisen Rearrangements. 4. Asymmetric Induction via l,3,2-Oxazaphosphorinanesla

Denmark, S. E. & Marlin, J. E., Dec 1 1987, In : Journal of Organic Chemistry. 52, 26, p. 5742-5745 4 p.

Research output: Contribution to journalLetter

Anions
Lithium
Phosphorus
Cations
vinyl ether

Carbanion-Accelerated Claisen Rearrangements. 6. Preparative and Stereochemical Studies with Sulfonyl-Stabilized Anions

Denmark, S. E., White, K. S. & Harmata, M. A., Nov 1 1989, In : Journal of the American Chemical Society. 111, 24, p. 8878-8891 14 p.

Research output: Contribution to journalArticle

Anions
anion
sulfoxide
Negative ions
Stereoselectivity

Carbanion-Accelerated Claisen Rearrangements. 7. Phosphine Oxide and Phosphonate Anion Stabilizing Groups

Denmark, S. E. & Marlin, J. E., Feb 1 1991, In : Journal of Organic Chemistry. 56, 3, p. 1003-1013 11 p.

Research output: Contribution to journalArticle

phosphine
Organophosphonates
Oxides
Anions
Lithium Chloride

Carbanion-Accelerated Claisen Rearrangements. 8. Phosphonamide Anion-Stabilizing Groups

Denmark, S. E., Stadler, H., Dorow, R. L. & Kim, J. H., Aug 1 1991, In : Journal of Organic Chemistry. 56, 17, p. 5063-5079 17 p.

Research output: Contribution to journalArticle

Organophosphonates
Anions
Stereoselectivity
Regioselectivity
Sulfones

Carbanion-accelerated Claisen rearrangements 3. Vicinal quaternary centers

Denmark, S. E. & Harmata, M. A., 1984, In : Tetrahedron Letters. 25, 15, p. 1543-1546 4 p.

Research output: Contribution to journalArticle

Hot Temperature
vinyl ether

Carbanion-accelerated Claisen rearrangements 5. Studies on stereocontrol with phosphorus-stabilized anions

Denmark, S. E., Rajendra, G. & Marlin, J. E., 1989, In : Tetrahedron Letters. 30, 19, p. 2469-2472 4 p.

Research output: Contribution to journalArticle

Phosphorus
Anions
Nitrogen
Atoms
vinyl ether

Carbanion Hybridization of Thiophosphonamide-Stabilized Anions: Remarkable Steric and Solvation Effects

Denmark, S. E. & Swiss, K. A., Dec 1 1993, In : Journal of the American Chemical Society. 115, 25, p. 12195-12196 2 p.

Research output: Contribution to journalArticle

Solvation
Anions

Carbonylative ring opening of terminal epoxides at atmospheric pressure

Denmark, S. E. & Ahmad, M., Dec 7 2007, In : Journal of Organic Chemistry. 72, 25, p. 9630-9634 5 p.

Research output: Contribution to journalArticle

Epoxy Compounds
Atmospheric pressure
Bearings (structural)
Acetals
Carbon Monoxide

Catalytic, asymmetric halofunctionalization of alkenes-a critical perspective

Denmark, S. E., Kuester, W. E. & Burk, M. T., Oct 29 2012, In : Angewandte Chemie - International Edition. 51, 44, p. 10938-10953 16 p.

Research output: Contribution to journalReview article

Alkenes
Catalysis
Olefins
Halogenation
Halogens

Catalytic, enantioselective, intramolecular carbosulfenylation of olefins

Denmark, S. E. & Jaunet, A., May 1 2013, In : Journal of the American Chemical Society. 135, 17, p. 6419-6422 4 p.

Research output: Contribution to journalArticle

alkene
Alkenes
Olefins
Tetrahydronaphthalenes
Nucleophiles
Lewis Bases
Alkenes
catalysis
Catalysis
Olefins

Catalytic, enantioselective, intramolecular carbosulfenylation of olefins. preparative and stereochemical aspects

Denmark, S. E. & Jaunet, A., Jan 3 2014, In : Journal of Organic Chemistry. 79, 1, p. 140-171 32 p.

Research output: Contribution to journalArticle

Alkenes
Enantioselectivity
Nucleophiles
Electrons
Acids

Catalytic, Enantioselective, Intramolecular Sulfenoamination of Alkenes with Anilines

Denmark, S. E. & Chi, H. M., Apr 7 2017, In : Journal of Organic Chemistry. 82, 7, p. 3826-3843 18 p.

Research output: Contribution to journalArticle

Aniline Compounds
Nucleophiles
Enantioselectivity
Alkenes
Catalysts

Catalytic, Enantioselective, Intramolecular Sulfenofunctionalization of Alkenes with Phenols

Denmark, S. E. & Kornfilt, D. J. P., Mar 17 2017, In : Journal of Organic Chemistry. 82, 6, p. 3192-3222 31 p.

Research output: Contribution to journalArticle

Phenols
Alkenes
Lewis Bases
Cyclization
Benzoxepins

Catalytic, enantioselective, vinylogous aldol reactions

Denmark, S. E., Heemstra, J. R. & Beutner, G. L., Jul 25 2005, In : Angewandte Chemie - International Edition. 44, 30, p. 4682-4698 17 p.

Research output: Contribution to journalReview article

Functional groups
Carbon
Carbonyl compounds
Ethers
Enantioselectivity

Catalytic, enantioselective aldol additions to ketones

Denmark, S. E. & Fan, Y., Apr 24 2002, In : Journal of the American Chemical Society. 124, 16, p. 4233-4235 3 p.

Research output: Contribution to journalArticle

ketone
Ketones
oxide
Stereoselectivity
Acetals

Catalytic, Enantioselective Cyclopropanation of Allylic Alcohols. Substrate Generality

Denmark, S. E. & O'Connor, S. P., Jan 1 1997, In : Journal of Organic Chemistry. 62, 3, p. 584-594 11 p.

Research output: Contribution to journalArticle

Substrates
Deprotonation
Zinc
Bearings (structural)
Stereoselectivity

Catalytic, Enantioselective Sulfenylation of Ketone-Derived Enoxysilanes

Denmark, S. E., Rossi, S., Webster, M. P. & Wang, H., Sep 5 2014, In : Journal of the American Chemical Society. 136, 37, p. 13016-13028 13 p.

Research output: Contribution to journalArticle

Lewis Bases
Enantioselectivity
ketone
Ketones
ether

Catalytic, Enantioselective syn-Diamination of Alkenes

Tao, Z., Gilbert, B. B. & Denmark, S. E., Dec 4 2019, In : Journal of the American Chemical Society. 141, 48, p. 19161-19170 10 p.

Research output: Contribution to journalArticle

alkene
Alkenes
Olefins
Bearings (structural)
catalysis

Catalytic, enantioselective α-additions of isocyanides: Lewis base catalyzed Passerini-type reactions

Denmark, S. E. & Fan, Y., Nov 25 2005, In : Journal of Organic Chemistry. 70, 24, p. 9667-9676 10 p.

Research output: Contribution to journalArticle

Lewis Bases
Cyanides
Enantioselectivity
Aldehydes
Amides
Allylation
Water gas shift
Aldehydes
Acetates
Carbon

Catalytic, nucleophilic allylation of aldehydes with allyl acetate

Denmark, S. E. & Nguyen, S. T., Feb 5 2009, In : Organic Letters. 11, 3, p. 781-784 4 p.

Research output: Contribution to journalArticle

Allylation
aldehydes
Aldehydes
acetates
Carbon Monoxide

Catalytic, Stereoselective Dihalogenation of Alkenes: Challenges and Opportunities

Cresswell, A. J., Eey, S. T. C. & Denmark, S. E., Dec 21 2015, In : Angewandte Chemie - International Edition. 54, 52, p. 15642-15682 41 p.

Research output: Contribution to journalReview article

Alkenes
Olefins
Bearings (structural)
Arsenals
Halogens

Catalytic, stereospecific syn-dichlorination of alkenes

Cresswell, A. J., Eey, S. T. C. & Denmark, S. E., Feb 2015, In : Nature Chemistry. 7, 2, p. 146-152 7 p.

Research output: Contribution to journalArticle

Alkenes
Olefins
Chlorides
Organic Chemicals
Bromine

Catalytic asymmetric synthesis

Jacobsen, E. N. & Denmark, S. E., 2000, Columbus, Oh: Unknown Publisher.

Research output: Book/ReportBook

Catalytic asymmetric synthesis

Denmark, S. E., Jul 19 2000, In : Accounts of chemical research. 33, 6, 1 p.

Research output: Contribution to journalEditorial

Organometallic Compounds
Stereoisomerism
Catalysis

Catalytic asymmetric thiofunctionalization of unactivated alkenes

Denmark, S. E., Kornfilt, D. J. P. & Vogler, T., Oct 5 2011, In : Journal of the American Chemical Society. 133, 39, p. 15308-15311 4 p.

Research output: Contribution to journalArticle

Styrenes
Furans
Nucleophiles
alkene
Alkenes

Catalytic conjugate addition of acyl anion equivalents promoted by fluorodesilylation

Denmark, S. E. & Cullen, L. R., Jan 3 2014, In : Organic Letters. 16, 1, p. 70-73 4 p.

Research output: Contribution to journalArticle

Anions
anions
Ketones
reaction time
ketones

Catalytic enantioselective addition of allylic organometallic reagents to aldehydes and ketones

Denmark, S. E. & Fu, J., Aug 1 2003, In : Chemical reviews. 103, 8, p. 2763-2793 31 p.

Research output: Contribution to journalArticle

Allylation
Organometallics
Ketones
Aldehydes
Lewis Acids

Catalytic enantioselective addition of dialkylzincs to aldehydes using (2S)-(-)-3-exo-(dimethylamino)isoborneol [(2S)-daib]: (S)-1-phenyl-1-propanol: [Benzenemethanol, α-ethyl-, (S)-]

Kitamura, M., Oka, H., Suga, S., Noyori, R., Kaelin, D. E., Martin, S. F., Beutner, G. L. & Denmark, S. E., Jan 1 2002, In : Organic Syntheses. 79, 1 p.

Research output: Contribution to journalArticle

Benzyl Alcohol
Aldehydes
alpha-ethylbenzyl alcohol
isoborneol

Catalytic enantioselective allylation with chiral Lewis bases

Denmark, S. E. & Fu, J., Feb 4 2003, In : Chemical Communications. 9, 2, p. 167-170 4 p.

Research output: Contribution to journalArticle

Lewis Bases
Allylation
Aldehydes
Alcohols
Catalysts

Catalytic enantioselective cyclopropanation with bis(halomethyl)zinc reagents. I. Optimization of reaction protocol

Denmark, S. E., Christenson, B. L., Coe, D. M. & O'Connor, S. P., Mar 27 1995, In : Tetrahedron Letters. 36, 13, p. 2215-2218 4 p.

Research output: Contribution to journalArticle

Zinc
cinnamyl alcohol
zinc iodide

Catalytic enantioselective cyclopropanation with bis(halomethyl)zinc reagents. II. The effect of promoter structure on selectivity

Denmark, S. E., Christenson, B. L. & O'Connor, S. P., Mar 27 1995, In : Tetrahedron Letters. 36, 13, p. 2219-2222 4 p.

Research output: Contribution to journalArticle

Sulfonamides
Zinc
Diamines
Amines

Catalytic Epoxidation of Alkenes with Oxone

Denmark, S. E., Forbes, D. C., Hays, D. S., DePue, J. S. & Wilde, R. G., Mar 1 1995, In : Journal of Organic Chemistry. 60, 5, p. 1391-1407 17 p.

Research output: Contribution to journalArticle

Epoxidation
Alkenes
Bearings (structural)
Epoxy Compounds
Oxidants

Catalytic Epoxidation of Alkenes with Oxone. 2. Flupro Ketones

Denmark, S. E., Wu, Z., Crudden, C. M. & Matsuhashi, H., Dec 1 1997, In : Journal of Organic Chemistry. 62, 24, p. 8288-8289 2 p.

Research output: Contribution to journalArticle

Epoxidation
Alkenes
Ketones
potassium peroxymonosulfuric acid

Catalytic Nucleophilic Allylation Driven by the Water-Gas Shift Reaction

Denmark, S. E., Matesich, Z. D., Nguyen, S. T. & Milicevic Sephton, S., Jan 5 2018, In : Journal of Organic Chemistry. 83, 1, p. 23-48 26 p.

Research output: Contribution to journalArticle

Allylation
Nucleophiles
Water gas shift
Aldehydes
Carbon

Chapter 1 Total synthesis of RK-397

Denmark, S. E. & Fujimori, S., Dec 1 2008, In : Strategies and Tactics in Organic Synthesis. 7, C, p. 1-34 34 p.

Research output: Contribution to journalArticle

Lewis Bases
Polyenes
Acetals
Macrolides
Aldehydes
Silicon
brasilenyne

Chemistry of Enoxysilacyclobutanes: Highly Selective Uncatalyzed Aldol Additions

Denmark, S. E., Griedel, B. D., Coe, D. M. & Schnute, M. E., Aug 1 1994, In : Journal of the American Chemical Society. 116, 16, p. 7026-7043 18 p.

Research output: Contribution to journalArticle

aldehyde
Aldehydes
Acetals
silicon
ester

Chemistry of Enoxysilacyclobutanes. 3. Uncatalyzed, Syn-Selective, Asymmetric Aldol Additions

Denmark, S. E. & Griedel, B. D., Sep 1 1994, In : Journal of Organic Chemistry. 59, 18, p. 5136-5138 3 p.

Research output: Contribution to journalArticle

Esters
Acetals
Aldehydes
Temperature
3-hydroxybutanal

Chemistry of trichlorosilyl enolates. 1. New reagents for catalytic, asymmetric aldol additions

Denmark, S. E., Winter, S. B. D., Su, X. & Wong, K. T., Aug 7 1996, In : Journal of the American Chemical Society. 118, 31, p. 7404-7405 2 p.

Research output: Contribution to journalArticle

3-hydroxybutanal

Chiral Amino Alcohol Modified Halomethylzinc Reagents

Denmark, S. E. & Edwards, J. P., Jan 1 1992, In : Synlett. 1992, 3, p. 229-230 2 p.

Research output: Contribution to journalArticle

Amino Alcohols
Alkenes
Zinc
N-methylephedrine
allyl alcohol

Chiral fluoro ketones for catalytic asymmetric epoxidation of alkenes with oxone

Denmark, S. E. & Matsuhashi, H., May 17 2002, In : Journal of Organic Chemistry. 67, 10, p. 3479-3486 8 p.

Research output: Contribution to journalArticle

Epoxidation
Alkenes
Ketones
Enantioselectivity
Catalysts