Scott E Denmark

1975 …2019
If you made any changes in Pure, your changes will be visible here soon.

Research Output 1975 2019

2019

(R)-n,n’-dimethyl-1,1’-binaphthyldiamine

Denmark, S. E. & Ryabchuk, P. G., Jan 1 2019, In : Organic Syntheses. 96, p. 382-399 18 p.

Research output: Contribution to journalArticle

Open Access

A Dinuclear Mechanism Implicated in Controlled Carbene Polymerization

Zhukhovitskiy, A. V., Kobylianskii, I. J., Thomas, A. A., Evans, A. M., Delaney, C. P., Flanders, N. C., Denmark, S. E., DIchtel, W. R. & Toste, F. D., Apr 24 2019, In : Journal of the American Chemical Society. 141, 16, p. 6473-6478 6 p.

Research output: Contribution to journalArticle

polymerization
Polymerization
Living polymerization
Polyolefins
Dimers

Catalytic, Enantioselective syn-Diamination of Alkenes

Tao, Z., Gilbert, B. B. & Denmark, S. E., Dec 4 2019, In : Journal of the American Chemical Society. 141, 48, p. 19161-19170 10 p.

Research output: Contribution to journalArticle

alkene
Alkenes
Olefins
Bearings (structural)
catalysis

Dynamically Chiral Helical Polymers: A New Frontier in Asymmetric Catalysis?

Denmark, S. E., Jul 24 2019, In : ACS Central Science. 5, 7, p. 1117-1119 3 p.

Research output: Contribution to journalArticle

Open Access
Catalysis
Polymers
Catalysts

Enantio- and Diastereoselective, Lewis Base Catalyzed, Cascade Sulfenoacetalization of Alkenyl Aldehydes

Matviitsuk, A. & Denmark, S. E., Jan 1 2019, In : Angewandte Chemie - International Edition. 58, 36, p. 12486-12490 5 p.

Research output: Contribution to journalArticle

Bearings (structural)
Lewis Bases
Acetals
Aldehydes
Ions

Enantioselective, lewis base-catalyzed, intermolecular sulfenoamination of alkenes

Roth, A. & Denmark, S. E., Sep 4 2019, In : Journal of the American Chemical Society. 141, 35, p. 13767-13771 5 p.

Research output: Contribution to journalArticle

Lewis Bases
alkene
Alkenes
Sulfur
Olefins

Enantioselective Synthesis of γ-Lactams by Lewis Base Catalyzed Sulfenoamidation of Alkenes

Panger, J. L. & Denmark, S. E., Jan 1 2019, (Accepted/In press) In : Organic Letters.

Research output: Contribution to journalArticle

Lewis Bases
Lactams
Lewis base
Alkenes
alkenes

Evaluating continuous chirality measure as a 3D descriptor in chemoinformatics applied to asymmetric catalysis

Zahrt, A. F. & Denmark, S. E., Mar 29 2019, In : Tetrahedron. 75, 13, p. 1841-1851 11 p.

Research output: Contribution to journalArticle

Chirality
Catalysis
Catalysts
Forests

Organoselenium-catalyzed enantioselective syn-dichlorination of unbiased alkenes

Gilbert, B. B., Eey, S. T. C., Ryabchuk, P., Garry, O. & Denmark, S. E., Aug 2 2019, In : Tetrahedron. 75, 31, p. 4086-4098 13 p.

Research output: Contribution to journalArticle

Alkenes
Synthetic Chemistry Techniques
Biological Products
Chlorides
Kinetics

Potassium Trimethylsilanolate Enables Rapid, Homogeneous Suzuki-Miyaura Cross-Coupling of Boronic Esters

Delaney, C. P., Kassel, V. M. & Denmark, S. E., Jan 1 2019, (Accepted/In press) In : ACS Catalysis. p. 73-80 8 p.

Research output: Contribution to journalArticle

Potassium
Esters
potassium trimethylsilanolate

Prediction of higher-selectivity catalysts by computer-driven workflow and machine learning

Zahrt, A. F., Henle, J. J., Rose, B. T., Wang, Y., Darrow, W. T. & Denmark, S. E., Jan 18 2019, In : Science. 363, 6424, eaau5631.

Research output: Contribution to journalArticle

Workflow
Empiricism
Sulfhydryl Compounds
Machine Learning
Support Vector Machine

Preface for volume 100

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 100, p. xxi-xxvii

Research output: Contribution to journalEditorial

Preface to volume 97

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 97, p. vii-ix

Research output: Contribution to journalEditorial

Preface to volume 98

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 98, p. vii-x

Research output: Contribution to journalEditorial

Preface to volume 99

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 99, p. vii-ix

Research output: Contribution to journalEditorial

Preparation of a diisopropylselenophosphoramide catalyst and its use in enantioselective sulfenoetherification

Denmark, S. E., Ryabchuk, P., Chi, H. M. & Matviitsuk, A., Jan 1 2019, In : Organic Syntheses. 96, p. 400-417 18 p.

Research output: Contribution to journalArticle

Open Access

Unusual Kinetic Profiles for Lewis Base-Catalyzed Sulfenocyclization of ortho -Geranylphenols in Hexafluoroisopropyl Alcohol

Robb, K. A., Athavale, S. V. & Denmark, S. E., Jan 1 2019, In : Synlett. 30, 14, p. 1656-1661 6 p.

Research output: Contribution to journalArticle

Lewis Bases
Polyenes
Alcohols
Nucleophiles
Kinetics
2018

Catalytic Nucleophilic Allylation Driven by the Water-Gas Shift Reaction

Denmark, S. E., Matesich, Z. D., Nguyen, S. T. & Milicevic Sephton, S., Jan 5 2018, In : Journal of Organic Chemistry. 83, 1, p. 23-48 26 p.

Research output: Contribution to journalArticle

Allylation
Nucleophiles
Water gas shift
Aldehydes
Carbon

Elucidating the Role of the Boronic Esters in the Suzuki-Miyaura Reaction: Structural, Kinetic, and Computational Investigations

Thomas, A. A., Zahrt, A. F., Delaney, C. P. & Denmark, S. E., Mar 28 2018, In : Journal of the American Chemical Society. 140, 12, p. 4401-4416 16 p.

Research output: Contribution to journalArticle

Boron
palladium
Palladium
boron
ester

Enantioselective, Lewis Base-Catalyzed Carbosulfenylation of Alkenylboronates by 1,2-Boronate Migration

Tao, Z., Robb, K. A., Panger, J. L. & Denmark, S. E., Nov 21 2018, In : Journal of the American Chemical Society. 140, 46, p. 15621-15625 5 p.

Research output: Contribution to journalArticle

Lewis Bases
ester
Esters
Bearings (structural)
Enantioselectivity

Enantioselective, Lewis Base-Catalyzed Sulfenocyclization of Polyenes

Tao, Z., Robb, K. A., Zhao, K. & Denmark, S. E., Mar 14 2018, In : Journal of the American Chemical Society. 140, 10, p. 3569-3573 5 p.

Research output: Contribution to journalArticle

Lewis Bases
Polyenes
Ions
ion
alkene

Investigating the Enantiodetermining Step of a Chiral Lewis Base Catalyzed Bromocycloetherification of Privileged Alkenes

Böse, D. & Denmark, S. E., Mar 1 2018, In : Synlett. 29, 4, p. 433-439 7 p., st-2017-b0700-c.

Research output: Contribution to journalArticle

Lewis Bases
Alkenes
Catalysts
Substrates

Organic Synthesis: Wherefrom and Whither? (Some Very Personal Reflections)

Denmark, S. E., Feb 2018, In : Israel Journal of Chemistry. 58, 1, p. 61-72 12 p.

Research output: Contribution to journalArticle

Steroid hormones
Oral Contraceptives
Biological Products
Health
Molecules
Rhodium
Palladium
Aldehydes
Catalysis
Carbonylation

Preface to volume 95

Denmark, S. E., Jan 1 2018, In : Organic Reactions. 95, p. vii-ix

Research output: Contribution to journalEditorial

Preface to volume 96

Denmark, S. E., Jan 1 2018, In : Organic Reactions. 96, p. vii-ix

Research output: Contribution to journalEditorial

Selective extraction of supported Rh nanoparticles under mild, non-acidic conditions with carbon monoxide

Ibrahim, M. Y. S. & Denmark, S. E., Jan 1 2018, In : Journal of Materials Chemistry A. 6, 37, p. 18075-18083 9 p.

Research output: Contribution to journalArticle

Rhodium
Carbon Monoxide
Carbon monoxide
Nanoparticles
Leaching

Synthesis, Reactivity, Functionalization, and ADMET Properties of Silicon-Containing Nitrogen Heterocycles

Barraza, S. J. & Denmark, S. E., May 30 2018, In : Journal of the American Chemical Society. 140, 21, p. 6668-6684 17 p.

Research output: Contribution to journalArticle

Silicon
Metabolism
excretion
silicon
Toxicity
2017

Catalytic, Enantioselective, Intramolecular Sulfenoamination of Alkenes with Anilines

Denmark, S. E. & Chi, H. M., Apr 7 2017, In : Journal of Organic Chemistry. 82, 7, p. 3826-3843 18 p.

Research output: Contribution to journalArticle

Aniline Compounds
Nucleophiles
Enantioselectivity
Alkenes
Catalysts

Catalytic, Enantioselective, Intramolecular Sulfenofunctionalization of Alkenes with Phenols

Denmark, S. E. & Kornfilt, D. J. P., Mar 17 2017, In : Journal of Organic Chemistry. 82, 6, p. 3192-3222 31 p.

Research output: Contribution to journalArticle

Phenols
Alkenes
Lewis Bases
Cyclization
Benzoxepins

Preface to volume 92

Denmark, S. E., Jan 1 2017, In : Organic Reactions. 92, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 93

Denmark, S. E., Jan 1 2017, In : Organic Reactions. 93, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 94

Denmark, S. E., Jan 1 2017, In : Organic Reactions. 94, p. vii-viii

Research output: Contribution to journalEditorial

Room Temperature, Reductive Alkylation of Activated Methylene Compounds: Carbon-Carbon Bond Formation Driven by the Rhodium-Catalyzed Water-Gas Shift Reaction

Denmark, S. E., Ibrahim, M. Y. S. & Ambrosi, A., Jan 6 2017, In : ACS Catalysis. 7, 1, p. 613-630 18 p.

Research output: Contribution to journalArticle

Rhodium
Water gas shift
Alkylation
Carbon
Alkylating Agents

Structural, Kinetic, and Computational Characterization of the Elusive Arylpalladium(II)boronate Complexes in the Suzuki-Miyaura Reaction

Thomas, A. A., Wang, H., Zahrt, A. F. & Denmark, S. E., Mar 15 2017, In : Journal of the American Chemical Society. 139, 10, p. 3805-3821 17 p.

Research output: Contribution to journalArticle

ligand
Ligands
Boronic Acids
kinetics
Kinetics
Lewis Bases
Lewis base
Enantioselectivity
Alkenes
alkenes

Synthesis of 2-Alkenyl-Tethered Anilines

Denmark, S. E. & Chi, H. M., Jul 3 2017, In : Synthesis (Germany). 49, 13, p. 2873-2888 16 p.

Research output: Contribution to journalArticle

Aniline Compounds
Aniline
Styrenes
Lewis Acids
Palladium

Understanding Site Selectivity in the Palladium-Catalyzed Cross-Coupling of Allenylsilanolates

Denmark, S. E. & Ambrosi, A., Nov 13 2017, In : Synlett. 28, 18, p. 2415-2420 6 p.

Research output: Contribution to journalArticle

Palladium
Isomers
Tuning

Unexpected Rearrangement of 2-Bromoaniline under Biphasic Alkylation Conditions

Barraza, S. J. & Denmark, S. E., Dec 18 2017, In : Synlett. 28, 20, p. 2891-2895 5 p.

Research output: Contribution to journalArticle

Alkylation
Bromine
Electrons
3-bromoaniline
2016

Bifunctional and Synergistic Catalysis: Lewis Acid Catalysis and Lewis Base-Assisted Bond Polarization (n → σ*)

Chung, W. J. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1213-1258 46 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Lewis Acids
Catalysis
Polarization
Chemical activation

Bifunctional Lewis Base Catalysis With Dual Activation of X3Si Nu and C=O(n → σ*)

Fu, J., Fujimori, S. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 1. p. 281-338 58 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Catalysis
Chemical activation
Phosphoramides
Catalysts

Harnessing the Power of the Water-Gas Shift Reaction for Organic Synthesis

Ambrosi, A. & Denmark, S. E., Jan 1 2016, In : Angewandte Chemie - International Edition. 55, 40, p. 12164-12189 26 p.

Research output: Contribution to journalReview article

Water gas shift
Carbon Monoxide
Ammonia
Catalysis
Hydrogenation

Lewis Base Catalysis: A Platform for Enantioselective Addition to Alkenes Using Group 16 and 17 Lewis Acids (n → σ*)

Kalyani, D., Kornfilt, D. J. P., Burk, M. T. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1153-1211 59 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Lewis Acids
Alkenes
Catalysis
Nucleophiles

Lewis Base Catalysis in Organic Synthesis

Vedejs, E. & Denmark, S. E., Aug 17 2016, Wiley-VCH Verlag. 1400 p.

Research output: Book/ReportBook

Lewis Bases
Catalysis
Electrons

Lewis Base-Catalyzed, Lewis Acid-Mediated Reactions (n → σ*)

Rossi, S. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1039-1076 38 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Bases
Lewis Acids
Silicon
Phosphoramides
Methyl Ethers

Preface

Vedejs, E. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 1-3. p. xxvii-xxxii

Research output: Chapter in Book/Report/Conference proceedingForeword/postscript

Speech synthesis

Preface to volume 89

Denmark, S. E., Jan 1 2016, In : Organic Reactions. 89, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 90

Denmark, S. E., Jan 1 2016, In : Organic Reactions. 90, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 91

Denmark, S. E., Jan 1 2016, In : Organic Reactions. 91, 1, p. vii-viii

Research output: Contribution to journalEditorial

Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link

Thomas, A. A. & Denmark, S. E., Apr 15 2016, In : Science. 352, 6283, p. 329-332 4 p.

Research output: Contribution to journalArticle

Palladium
Boron
Bearings (structural)
Carbon
Boronic Acids