Scott E Denmark

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Research Output

2020

Asymmetric Hydrogenation of Unfunctionalized Tetrasubstituted Acyclic Olefins

Bigler, R., Mack, K. A., Shen, J., Tosatti, P., Han, C., Bachmann, S., Zhang, H., Scalone, M., Pfaltz, A., Denmark, S. E., Hildbrand, S. & Gosselin, F., Feb 10 2020, In : Angewandte Chemie - International Edition. 59, 7, p. 2844-2849 6 p.

Research output: Contribution to journalArticle

Demystifying the asymmetry-amplifying, autocatalytic behaviour of the Soai reaction through structural, mechanistic and computational studies

Athavale, S. V., Simon, A., Houk, K. N. & Denmark, S. E., Apr 1 2020, In : Nature Chemistry. 12, 4, p. 412-423 12 p.

Research output: Contribution to journalArticle

Development of a Computer-Guided Workflow for Catalyst Optimization. Descriptor Validation, Subset Selection, and Training Set Analysis

Henle, J. J., Zahrt, A. F., Rose, B. T., Darrow, W. T., Wang, Y. & Denmark, S. E., 2020, (Accepted/In press) In : Journal of the American Chemical Society.

Research output: Contribution to journalArticle

Quantitative Structure-Selectivity Relationships in Enantioselective Catalysis: Past, Present, and Future

Zahrt, A. F., Athavale, S. V. & Denmark, S. E., Jan 1 2020, (Accepted/In press) In : Chemical reviews.

Research output: Contribution to journalReview article

2019

(R)-n,n’-dimethyl-1,1’-binaphthyldiamine

Denmark, S. E. & Ryabchuk, P. G., Jan 1 2019, In : Organic Syntheses. 96, p. 382-399 18 p.

Research output: Contribution to journalArticle

Open Access

A Dinuclear Mechanism Implicated in Controlled Carbene Polymerization

Zhukhovitskiy, A. V., Kobylianskii, I. J., Thomas, A. A., Evans, A. M., Delaney, C. P., Flanders, N. C., Denmark, S. E., DIchtel, W. R. & Toste, F. D., Apr 24 2019, In : Journal of the American Chemical Society. 141, 16, p. 6473-6478 6 p.

Research output: Contribution to journalArticle

Catalytic, Enantioselective syn-Diamination of Alkenes

Tao, Z., Gilbert, B. B. & Denmark, S. E., Dec 4 2019, In : Journal of the American Chemical Society. 141, 48, p. 19161-19170 10 p.

Research output: Contribution to journalArticle

Dynamically Chiral Helical Polymers: A New Frontier in Asymmetric Catalysis?

Denmark, S. E., Jul 24 2019, In : ACS Central Science. 5, 7, p. 1117-1119 3 p.

Research output: Contribution to journalArticle

Open Access

Enantio- and Diastereoselective, Lewis Base Catalyzed, Cascade Sulfenoacetalization of Alkenyl Aldehydes

Matviitsuk, A. & Denmark, S. E., Jan 1 2019, In : Angewandte Chemie - International Edition. 58, 36, p. 12486-12490 5 p.

Research output: Contribution to journalArticle

Enantioselective, lewis base-catalyzed, intermolecular sulfenoamination of alkenes

Roth, A. & Denmark, S. E., Sep 4 2019, In : Journal of the American Chemical Society. 141, 35, p. 13767-13771 5 p.

Research output: Contribution to journalArticle

Enantioselective Synthesis of γ-Lactams by Lewis Base Catalyzed Sulfenoamidation of Alkenes

Panger, J. L. & Denmark, S. E., Jan 1 2019, (Accepted/In press) In : Organic Letters.

Research output: Contribution to journalArticle

Evaluating continuous chirality measure as a 3D descriptor in chemoinformatics applied to asymmetric catalysis

Zahrt, A. F. & Denmark, S. E., Mar 29 2019, In : Tetrahedron. 75, 13, p. 1841-1851 11 p.

Research output: Contribution to journalArticle

Organoselenium-catalyzed enantioselective syn-dichlorination of unbiased alkenes

Gilbert, B. B., Eey, S. T. C., Ryabchuk, P., Garry, O. & Denmark, S. E., Aug 2 2019, In : Tetrahedron. 75, 31, p. 4086-4098 13 p.

Research output: Contribution to journalArticle

Potassium Trimethylsilanolate Enables Rapid, Homogeneous Suzuki-Miyaura Cross-Coupling of Boronic Esters

Delaney, C. P., Kassel, V. M. & Denmark, S. E., Jan 1 2019, (Accepted/In press) In : ACS Catalysis. p. 73-80 8 p.

Research output: Contribution to journalArticle

Prediction of higher-selectivity catalysts by computer-driven workflow and machine learning

Zahrt, A. F., Henle, J. J., Rose, B. T., Wang, Y., Darrow, W. T. & Denmark, S. E., Jan 18 2019, In : Science. 363, 6424, eaau5631.

Research output: Contribution to journalArticle

Preface for volume 100

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 100, p. xxi-xxvii

Research output: Contribution to journalEditorial

Preface to volume 97

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 97, p. vii-ix

Research output: Contribution to journalEditorial

Preface to volume 98

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 98, p. vii-x

Research output: Contribution to journalEditorial

Preface to volume 99

Denmark, S. E., Jan 1 2019, In : Organic Reactions. 99, p. vii-ix

Research output: Contribution to journalEditorial

Preparation of a diisopropylselenophosphoramide catalyst and its use in enantioselective sulfenoetherification

Denmark, S. E., Ryabchuk, P., Chi, H. M. & Matviitsuk, A., Jan 1 2019, In : Organic Syntheses. 96, p. 400-417 18 p.

Research output: Contribution to journalArticle

Open Access

Unusual Kinetic Profiles for Lewis Base-Catalyzed Sulfenocyclization of ortho -Geranylphenols in Hexafluoroisopropyl Alcohol

Robb, K. A., Athavale, S. V. & Denmark, S. E., Jan 1 2019, In : Synlett. 30, 14, p. 1656-1661 6 p.

Research output: Contribution to journalArticle

2018

Catalytic Nucleophilic Allylation Driven by the Water-Gas Shift Reaction

Denmark, S. E., Matesich, Z. D., Nguyen, S. T. & Milicevic Sephton, S., Jan 5 2018, In : Journal of Organic Chemistry. 83, 1, p. 23-48 26 p.

Research output: Contribution to journalArticle

Elucidating the Role of the Boronic Esters in the Suzuki-Miyaura Reaction: Structural, Kinetic, and Computational Investigations

Thomas, A. A., Zahrt, A. F., Delaney, C. P. & Denmark, S. E., Mar 28 2018, In : Journal of the American Chemical Society. 140, 12, p. 4401-4416 16 p.

Research output: Contribution to journalArticle

Enantioselective, Lewis Base-Catalyzed Carbosulfenylation of Alkenylboronates by 1,2-Boronate Migration

Tao, Z., Robb, K. A., Panger, J. L. & Denmark, S. E., Nov 21 2018, In : Journal of the American Chemical Society. 140, 46, p. 15621-15625 5 p.

Research output: Contribution to journalArticle

Enantioselective, Lewis Base-Catalyzed Sulfenocyclization of Polyenes

Tao, Z., Robb, K. A., Zhao, K. & Denmark, S. E., Mar 14 2018, In : Journal of the American Chemical Society. 140, 10, p. 3569-3573 5 p.

Research output: Contribution to journalArticle

Investigating the Enantiodetermining Step of a Chiral Lewis Base Catalyzed Bromocycloetherification of Privileged Alkenes

Böse, D. & Denmark, S. E., Mar 1 2018, In : Synlett. 29, 4, p. 433-439 7 p., st-2017-b0700-c.

Research output: Contribution to journalArticle

Organic Synthesis: Wherefrom and Whither? (Some Very Personal Reflections)

Denmark, S. E., Feb 2018, In : Israel Journal of Chemistry. 58, 1, p. 61-72 12 p.

Research output: Contribution to journalArticle

Preface to volume 95

Denmark, S. E., Jan 1 2018, In : Organic Reactions. 95, p. vii-ix

Research output: Contribution to journalEditorial

Preface to volume 96

Denmark, S. E., Jan 1 2018, In : Organic Reactions. 96, p. vii-ix

Research output: Contribution to journalEditorial

Selective extraction of supported Rh nanoparticles under mild, non-acidic conditions with carbon monoxide

Ibrahim, M. Y. S. & Denmark, S. E., Jan 1 2018, In : Journal of Materials Chemistry A. 6, 37, p. 18075-18083 9 p.

Research output: Contribution to journalArticle

Synthesis, Reactivity, Functionalization, and ADMET Properties of Silicon-Containing Nitrogen Heterocycles

Barraza, S. J. & Denmark, S. E., May 30 2018, In : Journal of the American Chemical Society. 140, 21, p. 6668-6684 17 p.

Research output: Contribution to journalArticle

2017

Catalytic, Enantioselective, Intramolecular Sulfenoamination of Alkenes with Anilines

Denmark, S. E. & Chi, H. M., Apr 7 2017, In : Journal of Organic Chemistry. 82, 7, p. 3826-3843 18 p.

Research output: Contribution to journalArticle

Catalytic, Enantioselective, Intramolecular Sulfenofunctionalization of Alkenes with Phenols

Denmark, S. E. & Kornfilt, D. J. P., Mar 17 2017, In : Journal of Organic Chemistry. 82, 6, p. 3192-3222 31 p.

Research output: Contribution to journalArticle

Preface to volume 92

Denmark, S. E., Jan 1 2017, In : Organic Reactions. 92, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 93

Denmark, S. E., Jan 1 2017, In : Organic Reactions. 93, 1, p. vii-viii

Research output: Contribution to journalEditorial

Preface to volume 94

Denmark, S. E., Jan 1 2017, In : Organic Reactions. 94, p. vii-viii

Research output: Contribution to journalEditorial

Room Temperature, Reductive Alkylation of Activated Methylene Compounds: Carbon-Carbon Bond Formation Driven by the Rhodium-Catalyzed Water-Gas Shift Reaction

Denmark, S. E., Ibrahim, M. Y. S. & Ambrosi, A., Jan 6 2017, In : ACS Catalysis. 7, 1, p. 613-630 18 p.

Research output: Contribution to journalArticle

Structural, Kinetic, and Computational Characterization of the Elusive Arylpalladium(II)boronate Complexes in the Suzuki-Miyaura Reaction

Thomas, A. A., Wang, H., Zahrt, A. F. & Denmark, S. E., Mar 15 2017, In : Journal of the American Chemical Society. 139, 10, p. 3805-3821 17 p.

Research output: Contribution to journalArticle

Synthesis of 2-Alkenyl-Tethered Anilines

Denmark, S. E. & Chi, H. M., Jul 3 2017, In : Synthesis (Germany). 49, 13, p. 2873-2888 16 p.

Research output: Contribution to journalArticle

Understanding Site Selectivity in the Palladium-Catalyzed Cross-Coupling of Allenylsilanolates

Denmark, S. E. & Ambrosi, A., Nov 13 2017, In : Synlett. 28, 18, p. 2415-2420 6 p.

Research output: Contribution to journalArticle

Unexpected Rearrangement of 2-Bromoaniline under Biphasic Alkylation Conditions

Barraza, S. J. & Denmark, S. E., Dec 18 2017, In : Synlett. 28, 20, p. 2891-2895 5 p.

Research output: Contribution to journalArticle

2016

Bifunctional and Synergistic Catalysis: Lewis Acid Catalysis and Lewis Base-Assisted Bond Polarization (n → σ*)

Chung, W. J. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1213-1258 46 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Bifunctional Lewis Base Catalysis With Dual Activation of X3Si Nu and C=O(n → σ*)

Fu, J., Fujimori, S. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 1. p. 281-338 58 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Harnessing the Power of the Water-Gas Shift Reaction for Organic Synthesis

Ambrosi, A. & Denmark, S. E., Jan 1 2016, In : Angewandte Chemie - International Edition. 55, 40, p. 12164-12189 26 p.

Research output: Contribution to journalReview article

Lewis Base Catalysis: A Platform for Enantioselective Addition to Alkenes Using Group 16 and 17 Lewis Acids (n → σ*)

Kalyani, D., Kornfilt, D. J. P., Burk, M. T. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1153-1211 59 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Lewis Base Catalysis in Organic Synthesis

Vedejs, E. & Denmark, S. E., Aug 17 2016, Wiley-VCH Verlag. 1400 p.

Research output: Book/Report/Conference proceedingBook

Lewis Base-Catalyzed, Lewis Acid-Mediated Reactions (n → σ*)

Rossi, S. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 3. p. 1039-1076 38 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

Preface

Vedejs, E. & Denmark, S. E., Aug 17 2016, Lewis Base Catalysis in Organic Synthesis. Wiley-VCH Verlag, Vol. 1-3. p. xxvii-xxxii

Research output: Chapter in Book/Report/Conference proceedingForeword/postscript