M Christina White

2024

Palladium-catalyzed cross-coupling of alcohols with olefins by positional tuning of a counteranion

Kaster, S. H. M., Zhu, L., Lyon, W. L., Ma, R., Ammann, S. E. & White, M. C., Sep 6 2024, In: Science. 385, 6713, p. 1067-1076 10 p.

Research output: Contribution to journal › Article › peer-review

2023

A preparative small-molecule mimic of liver CYP450 enzymes in the aliphatic C–H oxidation of carbocyclic N-heterocycles

Chambers, R. K., Weaver, J. D., Kim, J., Hoar, J. L., Krska, S. W. & Christina White, M., Jul 18 2023, In: Proceedings of the National Academy of Sciences of the United States of America. 120, 29, e2300315120.

Research output: Contribution to journal › Article › peer-review

Open Access

2022

Allylic C–H amination cross-coupling furnishes tertiary amines by electrophilic metal catalysis

Ali, S. Z., Budaitis, B. G., Fontaine, D. F. A., Pace, A. L., Garwin, J. A. & White, M. C., Apr 15 2022, In: Science. 376, 6590, p. 276-283 8 p.

Research output: Contribution to journal › Article › peer-review

Open Access

2021

Chemoselective methylene hydroxylation in aromatic molecules

White, M. C. (Inventor) & Zhao, J. (Inventor), Mar 30 2021, U.S. Patent No. 10961266, Sep 12 2019

Research output: Patent

Late-Stage Intermolecular Allylic C-H Amination

Ide, T., Feng, K., Dixon, C. F., Teng, D., Clark, J. R., Han, W., Wendell, C. I., Koch, V. & White, M. C., Sep 22 2021, In: Journal of the American Chemical Society. 143, 37, p. 14969-14975 7 p.

Research output: Contribution to journal › Article › peer-review

Open Access

2020

Chemoselective Tertiary C−H Hydroxylation for Late-Stage Functionalization with Mn(PDP)/Chloroacetic Acid Catalysis

Chambers, R. K., Zhao, J., Delaney, C. P. & White, M. C., Jan 23 2020, In: Advanced Synthesis and Catalysis. 362, 2, p. 417-423 7 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Late-stage oxidative C(sp ³)–H methylation

Feng, K., Quevedo, R. E., Kohrt, J. T., Oderinde, M. S., Reilly, U. & White, M. C., Apr 30 2020, In: Nature. 580, 7805, p. 621-627 7 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Manganese (III) catalyzed C—H aminations

White, M. C. (Inventor), Clark, J. R. (Inventor), Feng, K. (Inventor), Sookezian, A. (Inventor) & Wendell, C. (Inventor), Apr 7 2020, U.S. Patent No. 10611786, Oct 5 2018

Research output: Patent

2019

Chemoselective methylene oxidation in aromatic molecules

Zhao, J., Nanjo, T., de Lucca, E. C. & White, M. C., Mar 1 2019, In: Nature Chemistry. 11, 3, p. 213-221 9 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Sulfoxide ligand metal catalyzed oxidation of olefins

White, M. C. (Inventor), Ammann, S. E. (Inventor), Liu, W. (Inventor) & Ma, R. (Inventor), Apr 23 2019, U.S. Patent No. 10266503, May 24 2017

Research output: Patent

Synthesis of anti-1,3 Amino Alcohol Motifs via Pd(II)/SOX Catalysis with the Capacity for Stereodivergence

Ma, R., Young, J., Promontorio, R., Dannheim, F. M., Pattillo, C. C. & White, M. C., Jun 19 2019, In: Journal of the American Chemical Society. 141, 24, p. 9468-9473 6 p.

Research output: Contribution to journal › Article › peer-review

Open Access

2018

Aliphatic C-H Oxidations for Late-Stage Functionalization

White, M. C. & Zhao, J., Oct 31 2018, In: Journal of the American Chemical Society. 140, 43, p. 13988-14009 22 p.

Research output: Contribution to journal › Review article › peer-review

Open Access

Asymmetric Allylic C-H Alkylation via Palladium(II)/ cis-ArSOX Catalysis

Liu, W., Ali, S. Z., Ammann, S. E. & White, M. C., Aug 29 2018, In: Journal of the American Chemical Society. 140, 34, p. 10658-10662 5 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Catalyst-controlled aliphatic C—H oxidations

White, M. C. (Inventor) & Gormisky, P. E. (Inventor), Mar 27 2018, U.S. Patent No. 9925528

Research output: Patent

C-H to C-N Cross-Coupling of Sulfonamides with Olefins

Ma, R. & Christina White, M., Mar 7 2018, In: Journal of the American Chemical Society. 140, 9, p. 3202-3205 4 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Manganese-catalysed benzylic C(sp ³)-H amination for late-stage functionalization

Clark, J. R., Feng, K., Sookezian, A. & White, M. C., Jun 1 2018, In: Nature Chemistry. 10, 6, p. 583-591 9 p.

Research output: Contribution to journal › Article › peer-review

Open Access

2017

Catalytic C(sp³)-H alkylation via an iron carbene intermediate

Griffin, J. R., Wendell, C. I., Garwin, J. A. & White, M. C., Oct 4 2017, In: Journal of the American Chemical Society. 139, 39, p. 13624-13627 4 p.

Research output: Contribution to journal › Article › peer-review

Open Access

General catalyst for C-H functionalization

White, M. C. (Inventor), Zhao, J. (Inventor), Paradine, S. M. (Inventor), Griffin, J. R. (Inventor) & Petronico, A. L. (Inventor), Sep 26 2017, U.S. Patent No. 9770711

Research output: Patent

Remote, Late-Stage Oxidation of Aliphatic C-H Bonds in Amide-Containing Molecules

Nanjo, T., De Lucca, E. C. & White, M. C., Oct 18 2017, In: Journal of the American Chemical Society. 139, 41, p. 14586-14591 6 p.

Research output: Contribution to journal › Article › peer-review

Open Access

2016

Aerobic Linear Allylic C-H Amination: Overcoming Benzoquinone Inhibition

Pattillo, C. C., Strambeanu, I. I., Calleja, P., Vermeulen, N. A., Mizuno, T. & White, M. C., Feb 3 2016, In: Journal of the American Chemical Society. 138, 4, p. 1265-1272 8 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Base-Metal Catalysis: Embrace the Wild Side

White, M. C., Jul 28 2016, In: Advanced Synthesis and Catalysis. 358, 15, p. 2364-2365 2 p.

Research output: Contribution to journal › Comment/debate › peer-review

Open Access

Enantioselective Allylic C−H Oxidation of Terminal Olefins to Isochromans by Palladium(II)/Chiral Sulfoxide Catalysis

Ammann, S. E., Liu, W. & White, M. C., Aug 8 2016, In: Angewandte Chemie - International Edition. 55, 33, p. 9571-9575 5 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Oxidative diversification of amino acids and peptides by small-molecule iron catalysis

Osberger, T. J., Rogness, D. C., Kohrt, J. T., Stepan, A. F. & White, M. C., Aug 1 2016, In: Nature. 537, 7619, p. 214-219 6 p.

Research output: Contribution to journal › Article › peer-review

Open Access

2015

A manganese catalyst for highly reactive yet chemoselective intramolecular C(sp 3)-H amination

Paradine, S. M., Griffin, J. R., Zhao, J., Petronico, A. L., Miller, S. M. & Christina White, M., Dec 1 2015, In: Nature Chemistry. 7, 12, p. 987-994 8 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Remote Oxidation of Aliphatic C-H Bonds in Nitrogen-Containing Molecules

Howell, J. M., Feng, K., Clark, J. R., Trzepkowski, L. J. & White, M. C., Nov 25 2015, In: Journal of the American Chemical Society. 137, 46, p. 14590-14593 4 p.

Research output: Contribution to journal › Article › peer-review

Open Access

2014

General allylic C-H alkylation with tertiary nucleophiles

Howell, J. M., Liu, W., Young, A. J. & White, M. C., Apr 16 2014, In: Journal of the American Chemical Society. 136, 15, p. 5750-5754 5 p.

Research output: Contribution to journal › Article › peer-review

N -Boc amines to oxazolidinones via Pd(II)/bis-sulfoxide/brønsted acid Co-catalyzed allylic C-H oxidation

Osberger, T. J. & White, M. C., Aug 6 2014, In: Journal of the American Chemical Society. 136, 31, p. 11176-11181 6 p.

Research output: Contribution to journal › Article › peer-review

Organometallics roundtable 2013-2014

Gladysz, J. A., Bedford, R. B., Fujita, M., Gabbaï, F. P., Goldberg, K. I., Holland, P. L., Kiplinger, J. L., Krische, M. J., Louie, J., Lu, C. C., Norton, J. R., Petrukhina, M. A., Ren, T., Stahl, S. S., Tilley, T. D., Webster, C. E., White, M. C. & Whiteker, G. T., Apr 14 2014, In: Organometallics. 33, 7, p. 1505-1527 23 p.

Research output: Contribution to journal › Review article › peer-review

Terminal olefins to chromans, isochromans, and pyrans via allylic C-H oxidation

Ammann, S. E., Rice, G. T. & White, M. C., Aug 6 2014, In: Journal of the American Chemical Society. 136, 31, p. 10834-10837 4 p.

Research output: Contribution to journal › Article › peer-review

2013

A C-H oxidation approach for streamlining synthesis of chiral polyoxygenated motifs Dedicated to Professor Paul Wender for his pioneering and inspirational work on complexity generating organometallic reactions for streamlining complex molecule synthesis

Covell, D. J. & White, M. C., Sep 9 2013, In: Tetrahedron. 69, 36, p. 7771-7778 8 p.

Research output: Contribution to journal › Article › peer-review

Catalyst-controlled aliphatic c-h oxidations with a predictive model for site-selectivity

Gormisky, P. E. & White, M. C., Sep 25 2013, In: Journal of the American Chemical Society. 135, 38, p. 14052-14055 4 p.

Research output: Contribution to journal › Article › peer-review

Catalyst-controlled C-O versus C-N allylic functionalization of terminal olefins

Strambeanu, I. I. & White, M. C., Aug 14 2013, In: Journal of the American Chemical Society. 135, 32, p. 12032-12037 6 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Oxidative heck vinylation for the synthesis of complex dienes and polyenes

Delcamp, J. H., Gormisky, P. E. & White, M. C., Jun 12 2013, In: Journal of the American Chemical Society. 135, 23, p. 8460-8463 4 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Terminal olefins to linear α,β-unsaturated ketones: Pd(II)/hypervalent iodine co-catalyzed wacker oxidation-dehydrogenation

Bigi, M. A. & White, M. C., May 29 2013, In: Journal of the American Chemical Society. 135, 21, p. 7831-7834 4 p.

Research output: Contribution to journal › Article › peer-review

Open Access

2012

Adding aliphatic C-H bond oxidations to synthesis

White, M. C., Feb 17 2012, In: Science. 335, 6070, p. 807-809 3 p.

Research output: Contribution to journal › Short survey › peer-review

Cafestol to tricalysiolide B and oxidized analogues: Biosynthetic and derivatization studies using non-heme iron catalyst Fe(PDP)

Bigi, M. A., Liu, P., Zou, L., Houk, K. N. & White, M. C., 2012, In: Synlett. 23, 19, p. 2768-2772 5 p.

Research output: Contribution to journal › Article › peer-review

Open Access

2011

Open Access

On the macrocyclization of the erythromycin core: Preorganization is not required

Stang, E. M. & White, M. C., Feb 25 2011, In: Angewandte Chemie - International Edition. 50, 9, p. 2094-2097 4 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Synthetic versatility in C-H oxidation: A rapid approach to differentiated diols and pyrans from simple olefins

Gormisky, P. E. & White, M. C., Aug 17 2011, In: Journal of the American Chemical Society. 133, 32, p. 12584-12589 6 p.

Research output: Contribution to journal › Article › peer-review

Open Access

2010

Combined effects on selectivity in Fe-catalyzed methylene oxidation

Chen, M. S. & White, M. C., 2010, In: Science. 327, 5965, p. 533-571 39 p.

Research output: Contribution to journal › Article › peer-review

Diversification of a β-lactam pharmacophore via allylic C-H amination: Accelerating effect of Lewis acid co-catalyst

Qi, X., Rice, G. T., Lall, M. S., Plummer, M. S. & White, M. C., Jun 26 2010, In: Tetrahedron. 66, 26, p. 4816-4826 11 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Selective aliphatic C-H oxidation

White, M. C. (Inventor) & Chen, M. S. (Inventor), Nov 9 2010, U.S. Patent No. 7829342

Research output: Patent

Synthesis of complex allylic esters via C-H oxidation vs C-C Bond formation

Vermeulen, N. A., Delcamp, J. H. & White, M. C., Aug 18 2010, In: Journal of the American Chemical Society. 132, 32, p. 11323-11328 6 p.

Research output: Contribution to journal › Article › peer-review

Open Access

2009

A catalytic, Brønsted base strategy for intermolecular allylic C-H amination

Reed, S. A., Mazzotti, A. R. & White, M. C., Aug 26 2009, In: Journal of the American Chemical Society. 131, 33, p. 11701-11706 6 p.

Research output: Contribution to journal › Article › peer-review

M Christina White

Research output

Search results