Gregory S Girolami

2024

Compounds with Chelating 3-Dimethylamino-1-propyl Ligands as Chemical Vapor Deposition Precursors. Synthesis and Characterization of M[(CH₂)₃NMe₂]₂ Complexes of Nickel(II), Palladium(II), and Platinum(II)

Lastowski, R. J., Flores, V. J., Souqui, L., Abelson, J. R. & Girolami, G. S., Oct 28 2024, In: Organometallics. 43, 20, p. 2548-2556 9 p.

Research output: Contribution to journal › Article › peer-review

Measuring the Magnetic Anisotropy of Metal-Metal Multiple Bonds: The Importance of Correcting for Ligand Effects

Lastowski, R. J., Vogiatzis, K. D. & Girolami, G. S., Aug 26 2024, In: Inorganic Chemistry. 63, 34, p. 15546-15556 11 p.

Research output: Contribution to journal › Article › peer-review

Picosecond Metal-to-Ligand Charge-Transfer Deactivation in Co(ppy)₃ via Jahn-Teller Distortion

Malme, J. T., Weaver, J. N., Girolami, G. S. & Vura-Weis, J., Jul 29 2024, In: Inorganic Chemistry. 63, 30, p. 13825-13830 6 p.

Research output: Contribution to journal › Article › peer-review

Response to the rebuttal of the article Pathological crystal structures

Raymond, K. N. & Girolami, G. S., Jul 1 2024, In: Acta Crystallographica Section C: Structural Chemistry. 80, p. 258-261 4 p.

Research output: Contribution to journal › Article › peer-review

Volatile N,N′-dialkyl-β-dialdiminate complexes of magnesium and zinc as possible chemical vapor deposition precursors

Schmit, C. E. & Girolami, G. S., Jul 1 2024, In: Polyhedron. 256, 116985.

Research output: Contribution to journal › Article › peer-review

Open Access

2023

An osmium(II) methane complex: Elucidation of the methane coordination mode

Sempsrott, P. J., Trinh, B. B., Lovitt, C. F., Capra, N. E. & Girolami, G. S., Jun 2023, In: Science Advances. 9, 23, eadg8130.

Research output: Contribution to journal › Article › peer-review

Open Access

Area selective CVD of metallic films using precursor gases and inhibitors

Abelson, J. R. (Inventor), Girolami, G. S. (Inventor), Liu, S. (Inventor), Mohimi, E. (Inventor) & Zhang, Z. (Inventor), Feb 21 2023, U.S. Patent No. 11584986, Nov 1 2018

Research output: Patent

Margaret Bryan: Newly Discovered Biographical Information about the Author of A Compendious System of Astronomy (1797)

Girolami, G. S., Mar 22 2023, (E-pub ahead of print) In: Notes and Records of the Royal Society.

Research output: Contribution to journal › Article › peer-review

Pathological crystal structures

Raymond, K. N. & Girolami, G. S., Oct 24 2023, In: Acta Crystallographica Section C: Structural Chemistry. 79, Pt 11, p. 445-455 11 p.

Research output: Contribution to journal › Review article › peer-review

Open Access

Preparation and Characterization ofN,N′-Dialkyl-1,3-propanedialdiminium Chlorides, N,N′-Dialkyl-1,3-propanedialdimines, and Lithium N,N′-Dialkyl-1,3-propanedialdiminates

Schmit, C. E. & Girolami, G. S., May 2023, In: Helvetica Chimica Acta. 106, 5, e202200152.

Research output: Contribution to journal › Article › peer-review

Open Access

Structural and Spectroscopic Studies of Steric and Electronic Substituent Effects in a Series of Magnesium Aminodiboranates Mg[(BH₃)₂NMeR]₂

Caroff, C. M. & Girolami, G. S., Feb 20 2023, In: Inorganic Chemistry. 62, 7, p. 3116-3122 7 p.

Research output: Contribution to journal › Article › peer-review

Sub-5 nm Contacts and Induced p-n Junction Formation in Individual Atomically Precise Graphene Nanoribbons

Huang, P. C., Sun, H., Sarker, M., Caroff, C. M., Girolami, G. S., Sinitskii, A. & Lyding, J. W., Sep 26 2023, In: ACS Nano. 17, 18, p. 17771-17778 8 p.

Research output: Contribution to journal › Article › peer-review

Synthesis and Characterization of Chelating Alkyl-borohydride Complexes of Thorium and Uranium: Th(CH₂NMe₂BH₃)₄ and U(CH₂NMe₂BH₃)₄

Lastowski, R. J., Caroff, C. M., Vogiatzis, K. D. & Girolami, G. S., Oct 9 2023, In: Organometallics. 42, 19, p. 2839-2848 10 p.

Research output: Contribution to journal › Article › peer-review

Synthesis and Characterization of Ether Adducts of Thorium Tetrahydroborate Th(BH₄)₄ and Chemical Vapor Deposition of Thorium Boride Thin Films

Dunbar, A. C., Gozum, J. E., Lin, W., Flores, V. J. & Girolami, G. S., Mar 13 2023, In: Inorganic Chemistry. 62, 10, p. 4106-4115 10 p.

Research output: Contribution to journal › Article › peer-review

Three-Center M-H-B Bonds Are Strong Field Interactions. Synthesis and Characterization of M(CH₂NMe₂BH₃)₃ Complexes of Titanium, Chromium, and Cobalt

Lastowski, R. J., Yarranton, J. T., Zhu, L., Vogiatzis, K. D. & Girolami, G. S., Nov 1 2023, In: Journal of the American Chemical Society. 145, 43, p. 23585-23599 15 p.

Research output: Contribution to journal › Article › peer-review

Using metal precursors to passivate oxides for area selective deposition

Canova, K. L., Souqui, L., Girolami, G. S. & Abelson, J. R., May 2023, In: Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films. 41, 3, 033407.

Research output: Contribution to journal › Article › peer-review

2022

Metal complexes for depositing films and method of making and using the same

Girolami, G. S. (Inventor) & Liu, S. (Inventor), Feb 22 2022, U.S. Patent No. 11253846, Mar 13 2020

Research output: Patent

Pr(H₃BNMe₂BH₃)₃ and Pr(thd)₃ as Volatile Carriers for Actinium-225. Deposition of Actinium-Doped Praseodymium Boride Thin Films for Potential Use in Brachytherapy

Daly, S. R., Girolami, G. S., Bellott, B. J., McAlister, D. R. & Horwitz, E. P., May 16 2022, In: Inorganic Chemistry. 61, 19, p. 7217-7221 5 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Sodium Aminodiboranates Na(H₃BNR₂BH₃): Structural and Spectroscopic Studies of Steric and Electronic Substituent Effects

Caroff, C. M., Bellott, B. J., Daly, C. I., Daly, S. R., Dunbar, A. C., Mallek, J. L., Nesbit, M. A. & Girolami, G. S., Nov 21 2022, In: Inorganic Chemistry. 61, 46, p. 18412-18423 12 p.

Research output: Contribution to journal › Article › peer-review

Steric and Electronic Analyses of Ligand Effects on the Stability of σ-Methane Coordination Complexes: A DFT Study

Lovitt, C. F., Capra, N. E., Lastowski, R. J. & Girolami, G. S., Dec 26 2022, In: Organometallics. 41, 24, p. 3834-3844 11 p.

Research output: Contribution to journal › Article › peer-review

Synthesis, Structure, and Properties of Volatile Lanthanide Dialkyltriazenides

Caroff, C. M. & Girolami, G. S., Oct 24 2022, In: Inorganic Chemistry. 61, 42, p. 16740-16749 10 p.

Research output: Contribution to journal › Article › peer-review

Open Access

2021

Infrared reflection spectroscopy of adsorbed intermediates in real time during chemical vapor deposition of oxides

Zhang, Z. V., Girolami, G. S. & Abelson, J. R., Dec 1 2021, In: Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films. 39, 6, 063221.

Research output: Contribution to journal › Article › peer-review

Open Access

Metal complexes for depositing films and method of making and using the same

Girolami, G. S. (Inventor) & Liu, S. (Inventor), May 18 2021, U.S. Patent No. 11008353, Jul 13 2018

Research output: Patent

Microscale vacuum distillation apparatus for high-boiling, air- and heat-sensitive liquids

Liu, S. & Girolami, G. S., Feb 1 2021, In: Talanta. 223, 121747.

Research output: Contribution to journal › Article › peer-review

Nature of the Short Rh-Li Contact between Lithium and the Rhodium ω-Alkenyl Complex [Rh(CH₂CMe₂CH₂CH═CH₂)₂]^-

Liu, S., Smith, B. A., Kirkland, J. K., Vogiatzis, K. D. & Girolami, G. S., Jun 21 2021, In: Inorganic Chemistry. 60, 12, p. 8790-8801 12 p.

Research output: Contribution to journal › Article › peer-review

Platinum(II) Di-ω-alkenyl Complexes as "slow-Release" Precatalysts for Heat-Triggered Olefin Hydrosilylation

Liu, S. & Girolami, G. S., Oct 27 2021, In: Journal of the American Chemical Society. 143, 42, p. 17492-17509 18 p.

Research output: Contribution to journal › Article › peer-review

Selective chemical vapor deposition of HfB₂on Al₂O₃over SiO₂and the acceleration of nucleation on SiO₂by pretreatment with Hf[N(CH₃)₂]₄

Zhang, Z. V., Liu, S., Girolami, G. S. & Abelson, J. R., Mar 1 2021, In: Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films. 39, 2, 023415.

Research output: Contribution to journal › Article › peer-review

Open Access

Superconformal chemical vapor deposition using plasma-generated atomic species as a consumable growth inhibitor

Yang, Y., Canova, K. L., Jayaraman, S., Kim, D. Y., Girolami, G. S. & Abelson, J. R., Jul 1 2021, In: Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films. 39, 4, 043409.

Research output: Contribution to journal › Article › peer-review

Open Access

Superconformal growth and trench filling using a consumable inhibitor in chemical vapor deposition of Hf_1-xV_xB_y

Canova, K. L., Zhang, Z. V., Girolami, G. S. & Abelson, J. R., Jan 1 2021, In: Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films. 39, 1, 013402.

Research output: Contribution to journal › Article › peer-review

Open Access

Synthesis and Characterization of 2,2-Dimethylpent-4-en-1-yl Complexes of Rhodium and Iridium: Reversible Olefin Decomplexation and C-H Bond Activation

Liu, S. & Girolami, G. S., Mar 22 2021, In: Organometallics. 40, 6, p. 714-724 11 p.

Research output: Contribution to journal › Article › peer-review

Synthesis and Characterization of Divalent Samarium and Thulium N, N-Dimethylaminodiboranates

Anderson, N. T., Wright, J. C. & Girolami, G. S., Aug 2 2021, In: Inorganic Chemistry. 60, 15, p. 11164-11176 13 p.

Research output: Contribution to journal › Article › peer-review

Open Access

Ultrasmooth cobalt films on SiO₂by chemical vapor deposition using a nucleation promoter and a growth inhibitor

Zhang, Z. V., Liu, S., Girolami, G. S. & Abelson, J. R., Mar 1 2021, In: Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films. 39, 2, 023414.

Research output: Contribution to journal › Article › peer-review

Open Access

X-ray Crystal Structure of Thorium Tetrahydroborate, Th(BH₄)₄, and Computational Studies of An(BH₄)₄(An = Th, U)

Dunbar, A. C., Wright, J. C., Grant, D. J. & Girolami, G. S., Aug 16 2021, In: Inorganic Chemistry. 60, 16, p. 12489-12497 9 p.

Research output: Contribution to journal › Article › peer-review

2020

A Brief History of Thermodynamics, As Illustrated by Books and People

Girolami, G. S., Feb 13 2020, In: Journal of Chemical and Engineering Data. 65, 2, p. 298-311 14 p.

Research output: Contribution to journal › Article › peer-review

Area-selective chemical vapor deposition of cobalt from dicobalt octacarbonyl: Enhancement of dielectric-dielectric selectivity by adding a coflow of NH₃

Zhang, Z. V., Liu, S., Girolami, G. S. & Abelson, J. R., May 1 2020, In: Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films. 38, 3, 033401.

Research output: Contribution to journal › Article › peer-review

Open Access

Enhanced Electrical and Mechanical Properties of Chemically Cross-Linked Carbon-Nanotube-Based Fibers and Their Application in High-Performance Supercapacitors

Wang, G., Kim, S. K., Wang, M. C., Zhai, T., Munukutla, S., Girolami, G. S., Sempsrott, P. J., Nam, S., Braun, P. V. & Lyding, J. W., Jan 28 2020, In: ACS Nano. 14, 1, p. 632-639 8 p.

Research output: Contribution to journal › Article › peer-review

New strategies for conformal, superconformal, and ultrasmooth films by low temperature chemical vapor deposition

Abelson, J. R. & Girolami, G. S., May 1 2020, In: Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films. 38, 3, 030802.

Research output: Contribution to journal › Review article › peer-review

Open Access

Platinum ω-Alkenyl Compounds as Chemical Vapor Deposition Precursors: Synthesis and Characterization of Pt[CH₂CMe₂CH₂CH═CH₂]₂and the Impact of Ligand Design on the Deposition Process

Liu, S., Zhang, Z., Gray, D., Zhu, L., Abelson, J. R. & Girolami, G. S., Nov 10 2020, In: Chemistry of Materials. 32, 21, p. 9316-9334 19 p.

Research output: Contribution to journal › Article › peer-review

Platinum ω-Alkenyl Compounds as Chemical Vapor Deposition Precursors. Mechanistic Studies of the Thermolysis of Pt[CH₂CMe₂CH₂CH= CH₂]₂in Solution and the Origin of Rapid Nucleation

Liu, S., Zhang, Z., Abelson, J. R. & Girolami, G. S., Nov 9 2020, In: Organometallics. 39, 21, p. 3817-3829 13 p.

Research output: Contribution to journal › Article › peer-review

Synthesis and Characterization of Strontium N, N-Dimethylaminodiboranates as Possible Chemical Vapor Deposition Precursors

Dunbar, A. C., Joseph Lastowski, R. & Girolami, G. S., Dec 7 2020, In: Inorganic Chemistry. 59, 23, p. 16893-16904 12 p.

Research output: Contribution to journal › Article › peer-review

Zirconium alkyls with ancillary cyclooctatetraenyl ligands. X-ray crystal structures of [Li(tmed)][(C₈H₈)Zr(p-C₆H₄Me)Cl₂] and (C₈H₈)Zr[CH(SiMe₃)₂]₂

Nelsen, M. J. & Girolami, G. S., Sep 1 2020, In: Polyhedron. 187, 114581.

Research output: Contribution to journal › Article › peer-review

Open Access

2019

A Book Collector's View of the Periodic Table: Key Documents before Mendeleev's Contributions of 1869

Girolami, G. S., 2019, In: Substantia. 3, 2, p. 109-124 16 p.

Research output: Contribution to journal › Article › peer-review

Lithium-Olefin π-Complexes and the Mechanism of Carbolithiation: Synthesis, Solution Behavior, and Crystal Structure of (2,2-Dimethylpent-4-en-1-yl)lithium

Liu, S., Gray, D., Zhu, L. & Girolami, G. S., May 13 2019, In: Organometallics. 38, 9, p. 2199-2210 12 p.

Research output: Contribution to journal › Article › peer-review

Low temperature chemical vapor deposition of superconducting molybdenum carbonitride thin films

Mohimi, E., Canova, K., Zhang, Z., Liu, S., Mallek, J. L., Girolami, G. S. & Abelson, J. R., Mar 1 2019, In: Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films. 37, 2, 021503.

Research output: Contribution to journal › Article › peer-review

Low temperature chemical vapor deposition of superconducting vanadium nitride thin films

Mohimi, E., Zhang, Z. V., Mallek, J. L., Liu, S., Trinh, B. B., Shetty, P. P., Girolami, G. S. & Abelson, J. R., May 1 2019, In: Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films. 37, 3, 031509.

Research output: Contribution to journal › Article › peer-review

Salt elimination reactions do not always eliminate. Mechanistic study of the reaction of NdCl₃ with sodium N,N-dimethylaminodiboranate

Chang, N. N., Daly, S. R. & Girolami, G. S., Apr 1 2019, In: Polyhedron. 162, p. 52-58 7 p.

Research output: Contribution to journal › Article › peer-review

Seamless fill of deep trenches by chemical vapor deposition: Use of a molecular growth inhibitor to eliminate pinch-off

Talukdar, T. K., Girolami, G. S. & Abelson, J. R., Mar 1 2019, In: Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films. 37, 2, 021509.

Research output: Contribution to journal › Article › peer-review

Tracking the Metal-Centered Triplet in Photoinduced Spin Crossover of Fe(phen)₃ ²⁺ with Tabletop Femtosecond M-Edge X-ray Absorption Near-Edge Structure Spectroscopy

Zhang, K., Ash, R., Girolami, G. S. & Vura-Weis, J., Oct 30 2019, In: Journal of the American Chemical Society. 141, 43, p. 17180-17188 9 p.

Research output: Contribution to journal › Article › peer-review

Open Access

2018

Area selective CVD of metallic films from molybdenum, iron, and ruthenium carbonyl precursors: Use of ammonia to inhibit nucleation on oxide surfaces

Mohimi, E., Zhang, Z. V., Liu, S., Mallek, J. L., Girolami, G. S. & Abelson, J. R., Jul 1 2018, In: Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films. 36, 4, 041507.

Research output: Contribution to journal › Article › peer-review

Chemical vapor deposition of magnetic iron-cobalt alloy thin films: Use of ammonia to stabilize growth from carbonyl precursors

Zhang, P., Zhang, Z., Abelson, J. R. & Girolami, G. S., Nov 1 2018, In: Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films. 36, 6, 061505.

Research output: Contribution to journal › Article › peer-review

Gregory S Girolami

Research output

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