David William Flaherty

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Research Output

  • 55 Article
  • 5 Conference contribution
  • 2 Review article
  • 1 Chapter
2020

Catalytic Microgelators for Decoupled Control of Gelation Rate and Rigidity of the Biological Gels

Hong, Y. T., Bregante, D. T., Lee, J. C. W., Seo, Y., Kim, D. H., Lee, Y. J., Schook, L. B., Jeon, H., Sung, H. J., Flaherty, D. W., Rogers, S. A. & Kong, H., Jan 10 2020, In : Journal of Controlled Release. 317, p. 166-180 15 p.

Research output: Contribution to journalArticle

Open Access

Effects of phosphorus addition on selectivity and stability of Pd model catalysts during cyclohexene dehydrogenation

Sampath, A. & Flaherty, D. W., Feb 21 2020, In : Catalysis Science and Technology. 10, 4, p. 993-1005 13 p.

Research output: Contribution to journalArticle

Heteroatom substituted zeolite FAU with ultralow Al contents for liquid-phase oxidation catalysis

Bregante, D. T., Tan, J. Z., Sutrisno, A. & Flaherty, D. W., Feb 7 2020, In : Catalysis Science and Technology. 10, 3, p. 635-647 13 p.

Research output: Contribution to journalArticle

2019

Cooperative effects between hydrophilic pores and solvents: Catalytic consequences of hydrogen bonding on alkene epoxidation in zeolites

Bregante, D. T., Johnson, A. M., Patel, A. Y., Ayla, E. Z., Cordon, M. J., Bukowski, B. C., Greeley, J., Gounder, R. & Flaherty, D. W., Jan 16 2019, In : Journal of the American Chemical Society. 141, 18, p. 7302-7319 18 p.

Research output: Contribution to journalArticle

Form of the catalytically active Pd species during the direct synthesis of hydrogen peroxide

Priyadarshini, P. & Flaherty, D. W., Dec 1 2019, In : AIChE Journal. 65, 12, e16829.

Research output: Contribution to journalArticle

In Situ Methods for Identifying Reactive Surface Intermediates during Hydrogenolysis Reactions: C-O Bond Cleavage on Nanoparticles of Nickel and Nickel Phosphides

Witzke, M. E., Almithn, A., Coonrod, C. L., Triezenberg, M. D., Hibbitts, D. D. & Flaherty, D. W., Oct 23 2019, In : Journal of the American Chemical Society. 141, 42, p. 16671-16684 14 p.

Research output: Contribution to journalArticle

Kinetic analysis of the asymmetric hydrogenation of ß-keto esters over Α-amino acid-functionalized Pt nanoparticles

Šulce, A., Flaherty, D. W. & Kunz, S., Jun 2019, In : Journal of Catalysis. 374, p. 82-92 11 p.

Research output: Contribution to journalArticle

2018

Catalytic Hydrogen Transfer and Decarbonylation of Aromatic Aldehydes on Ru and Ru Phosphide Model Catalysts

Sampath, A., Chang, S. A. & Flaherty, D. W., Oct 18 2018, In : Journal of Physical Chemistry C. 122, 41, p. 23600-23609 10 p.

Research output: Contribution to journalArticle

Consequences of Confinement for Alkene Epoxidation with Hydrogen Peroxide on Highly Dispersed Group 4 and 5 Metal Oxide Catalysts

Bregante, D. T., Thornburg, N. E., Notestein, J. M. & Flaherty, D. W., Apr 6 2018, In : ACS Catalysis. 8, 4, p. 2995-3010 16 p.

Research output: Contribution to journalArticle

Direct Synthesis of H2O2 from H2 and O2 on Pd Catalysts: Current Understanding, Outstanding Questions, and Research Needs

Flaherty, D. W., Feb 2 2018, In : ACS Catalysis. 8, 2, p. 1520-1527 8 p.

Research output: Contribution to journalReview article

Direct Synthesis of H2O2 on AgPt Octahedra: The Importance of Ag-Pt Coordination for High H2O2 Selectivity

Wilson, N. M., Pan, Y. T., Shao, Y. T., Zuo, J. M., Yang, H. & Flaherty, D. W., Apr 6 2018, In : ACS Catalysis. 8, 4, p. 2880-2889 10 p.

Research output: Contribution to journalArticle

Direct synthesis of H2O2 on Pd and AuxPd1 clusters: Understanding the effects of alloying Pd with Au

Wilson, N. M., Priyadarshini, P., Kunz, S. & Flaherty, D. W., Jan 2018, In : Journal of Catalysis. 357, p. 163-175 13 p.

Research output: Contribution to journalArticle

Direct synthesis of H2O2 on PdZn nanoparticles: The impact of electronic modifications and heterogeneity of active sites

Wilson, N. M., Schröder, J., Priyadarshini, P., Bregante, D. T., Kunz, S. & Flaherty, D. W., Dec 2018, In : Journal of Catalysis. 368, p. 261-274 14 p.

Research output: Contribution to journalArticle

Dominant Role of Entropy in Stabilizing Sugar Isomerization Transition States within Hydrophobic Zeolite Pores

Cordon, M. J., Harris, J. W., Vega-Vila, J. C., Bates, J. S., Kaur, S., Gupta, M., Witzke, M. E., Wegener, E. C., Miller, J. T., Flaherty, D. W., Hibbitts, D. D. & Gounder, R., Jan 1 2018, (Accepted/In press) In : Journal of the American Chemical Society.

Research output: Contribution to journalArticle

Mechanisms and Active Sites for C-O Bond Rupture within 2-Methyltetrahydrofuran over Ni, Ni12P5, and Ni2P Catalysts

Witzke, M. E., Almithn, A., Coonrod, C. L., Hibbitts, D. D. & Flaherty, D. W., Aug 3 2018, In : ACS Catalysis. 8, 8, p. 7141-7157 17 p.

Research output: Contribution to journalArticle

2017

Effects of phosphorus on C–C, C–O, and C–H bond rupture during acetic acid decomposition over Ru(0001) and Px-Ru(0001)

Chang, S. W. A., Vermani, V. & Flaherty, D. W., Jan 1 2017, In : Journal of Catalysis. 353, p. 181-191 11 p.

Research output: Contribution to journalArticle

Formation Pathways toward 2- and 4-Methylbenzaldehyde via Sequential Reactions from Acetaldehyde over Hydroxyapatite Catalyst

Moteki, T., Rowley, A. T., Bregante, D. T. & Flaherty, D. W., Jun 8 2017, In : ChemCatChem. 9, 11, p. 1921-1929 9 p.

Research output: Contribution to journalArticle

Kinetic and spectroscopic evidence for reaction pathways and intermediates for olefin epoxidation on Nb in *BEA

Bregante, D. T., Priyadarshini, P. & Flaherty, D. W., 2017, In : Journal of Catalysis. 348, p. 75-89 15 p.

Research output: Contribution to journalArticle

Production and use of H2O2 for atom-efficient functionalization of hydrocarbons and small molecules

Wilson, N. M., Bregante, D. T., Priyadarshini, P. & Flaherty, D. W., Jan 1 2017, Catalysis. Spivey, J. J. & Han, Y-F. (eds.). Royal Society of Chemistry, p. 122-212 91 p. (Catalysis; vol. 29).

Research output: Chapter in Book/Report/Conference proceedingChapter

Spectroscopic evidence for origins of size and support effects on selectivity of Cu nanoparticle dehydrogenation catalysts

Witzke, M. E., Dietrich, P. J., Ibrahim, M. Y. S., Al-Bardan, K., Triezenberg, M. D. & Flaherty, D. W., 2017, In : Chemical Communications. 53, 3, p. 597-600 4 p.

Research output: Contribution to journalArticle

2016

Effects of Chain Length on the Mechanism and Rates of Metal-Catalyzed Hydrogenolysis of n-Alkanes

Hibbitts, D. D., Flaherty, D. W. & Iglesia, E., May 5 2016, In : Journal of Physical Chemistry C. 120, 15, p. 8125-8138 14 p.

Research output: Contribution to journalArticle

Mechanistic Insight to C-C Bond Formation and Predictive Models for Cascade Reactions among Alcohols on Ca- and Sr-Hydroxyapatites

Moteki, T. & Flaherty, D. W., Jul 1 2016, In : ACS Catalysis. 6, 7, p. 4170-4183 14 p.

Research output: Contribution to journalArticle

Mechanistic study of formic acid decomposition over Ru(0001) and Px-Ru(0001): Effects of phosphorus on C-H and C-O bond rupture

Chang, S. W. A. & Flaherty, D. W., Nov 10 2016, In : Journal of Physical Chemistry C. 120, 44, p. 25425-25435 11 p.

Research output: Contribution to journalArticle

Production of Fuels and Chemicals from Biomass: Condensation Reactions and Beyond

Wu, L., Moteki, T., Gokhale, A. A., Flaherty, D. W. & Toste, F. D., Dec 1 2016, In : Chem. 1, 1, p. 32-58 27 p.

Research output: Contribution to journalReview article

Role of Branching on the Rate and Mechanism of C-C Cleavage in Alkanes on Metal Surfaces

Hibbitts, D. D., Flaherty, D. W. & Iglesia, E., Jan 4 2016, In : ACS Catalysis. 6, 1, p. 469-482 14 p.

Research output: Contribution to journalArticle

Self-Terminated Cascade Reactions That Produce Methylbenzaldehydes from Ethanol

Moteki, T., Rowley, A. T. & Flaherty, D. W., Nov 4 2016, In : ACS Catalysis. 6, 11, p. 7278-7282 5 p.

Research output: Contribution to journalArticle

2015
2014

Metal-catalyzed C-C bond cleavage in alkanes: Effects of methyl substitution on transition-state structures and stability

Flaherty, D. W., Hibbitts, D. D. & Iglesia, E., Jul 9 2014, In : Journal of the American Chemical Society. 136, 27, p. 9664-9676 13 p.

Research output: Contribution to journalArticle

Selective hydrogen production from formic acid decomposition on Pd-Au bimetallic surfaces

Yu, W. Y., Mullen, G. M., Flaherty, D. W. & Mullins, C. B., Aug 6 2014, In : Journal of the American Chemical Society. 136, 31, p. 11070-11078 9 p.

Research output: Contribution to journalArticle

Theoretical and kinetic assessment of the mechanism of ethane hydrogenolysis on metal surfaces saturated with chemisorbed hydrogen

Flaherty, D. W., Hibbitts, D. D., Gürbüz, E. I. & Iglesia, E., Mar 1 2014, In : Journal of Catalysis. 311, p. 350-356 7 p.

Research output: Contribution to journalArticle

2013

Mechanism of C-C hydrogenolysis on Ir catalysts

Hibbitts, D. D., Flaherty, D. W. & Iglesia, E., Jan 1 2013, Fuels and Petrochemicals Division 2013 - Core Programming Area at the 2013 AIChE Annual Meeting: Global Challenges for Engineering a Sustainable Future. AIChE, 1 p. (Fuels and Petrochemicals Division 2013 - Core Programming Area at the 2013 AIChE Annual Meeting: Global Challenges for Engineering a Sustainable Future).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Mechanism of C-C hydrogenolysis on Ir catalysts

Hibbitts, D. D., Flaherty, D. W. & Iglesia, E., Jan 1 2013, Sustainable Engineering Forum 2013 - Core Programming Area at the 2013 AIChE Annual Meeting: Global Challenges for Engineering a Sustainable Future. AIChE, p. 116-117 2 p. (Sustainable Engineering Forum 2013 - Core Programming Area at the 2013 AIChE Annual Meeting: Global Challenges for Engineering a Sustainable Future).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Transition-state enthalpy and entropy effects on reactivity and selectivity in hydrogenolysis of n -alkanes

Flaherty, D. W. & Iglesia, E., Dec 11 2013, In : Journal of the American Chemical Society. 135, 49, p. 18586-18599 14 p.

Research output: Contribution to journalArticle

2012

CO oxidation on inverse Fe 2O 3/Au(1 1 1) model catalysts

Yan, T., Redman, D. W., Yu, W. Y., Flaherty, D. W., Rodriguez, J. A. & Mullins, C. B., Oct 1 2012, In : Journal of Catalysis. 294, p. 216-222 7 p.

Research output: Contribution to journalArticle

Influence of hydrofluoric acid formation on lithium ion insertion in nanostructured V 2O 5

Wu, J., Membreno, N., Yu, W. Y., Wiggins-Camacho, J. D., Flaherty, D. W., Mullins, C. B. & Stevenson, K. J., Oct 11 2012, In : Journal of Physical Chemistry C. 116, 40, p. 21208-21215 8 p.

Research output: Contribution to journalArticle

Reactive ballistic deposition of nanostructured model materials for electrochemical energy conversion and storage

Flaherty, D. W., Hahn, N. T., May, R. A., Berglund, S. P., Lin, Y. M., Stevenson, K. J., Dohnalek, Z., Kay, B. D. & Mullins, C. B., Mar 20 2012, In : Accounts of chemical research. 45, 3, p. 434-443 10 p.

Research output: Contribution to journalArticle

2011

Exocyclic and endocyclic C-C bond cleavage - Mechanism and site requirements

Flaherty, D. W., Uzun, A. & Iglesia, E., Jan 1 2011, Sustainable Engineering Forum: Core Programming Topic at the 2011 AIChE Annual Meeting. AIChE, p. 425-426 2 p. (Sustainable Engineering Forum: Core Programming Topic at the 2011 AIChE Annual Meeting; vol. 1).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Exocyclic and endocyclic c-c bond cleavage-mechanism and site requirements

Flaherty, D. W., Uzun, A. & Iglesia, E., Jan 1 2011, Catalysis and Reaction Engineering Division - Core Programming Topic at the 2011 AIChE Annual Meeting. AIChE, p. 333-334 2 p. (Catalysis and Reaction Engineering Division - Core Programming Topic at the 2011 AIChE Annual Meeting; vol. 1).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Low-temperature hydrogenation of acetaldehyde to ethanol on H-precovered Au(111)

Pan, M., Flaherty, D. W. & Mullins, C. B., Jun 16 2011, In : Journal of Physical Chemistry Letters. 2, 12, p. 1363-1367 5 p.

Research output: Contribution to journalArticle

Mechanism for the water-gas shift reaction on monofunctional platinum and cause of catalyst deactivation

Flaherty, D. W., Yu, W. Y., Pozun, Z. D., Henkelman, G. & Mullins, C. B., Sep 1 2011, In : Journal of Catalysis. 282, 2, p. 278-288 11 p.

Research output: Contribution to journalArticle

Morphology dependence of the lithium storage capability and rate performance of amorphous TiO2 electrodes

Lin, Y. M., Abel, P. R., Flaherty, D. W., Wu, J., Stevenson, K. J., Heller, A. & Mullins, C. B., Feb 10 2011, In : Journal of Physical Chemistry C. 115, 5, p. 2585-2591 7 p.

Research output: Contribution to journalArticle

Photoelectrochemical oxidation of water using nanostructured BiVO 4 films

Berglund, S. P., Flaherty, D. W., Hahn, N. T., Bard, A. J. & Mullins, C. B., Mar 10 2011, In : Journal of Physical Chemistry C. 115, 9, p. 3794-3802 9 p.

Research output: Contribution to journalArticle

The effect of adsorbed water in CO oxidation on Au/TiO2(110)

Yan, T., Gong, J., Flaherty, D. W. & Mullins, C. B., Feb 10 2011, In : Journal of Physical Chemistry C. 115, 5, p. 2057-2065 9 p.

Research output: Contribution to journalArticle