Alison R Fout

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Research Output

2020

Catalytic Perchlorate Reduction Using Iron: Mechanistic Insights and Improved Catalyst Turnover

Drummond, M. J., Miller, T. J., Ford, C. L. & Fout, A. R., Mar 6 2020, In : ACS Catalysis. 10, 5, p. 3175-3182 8 p.

Research output: Contribution to journalArticle

2019

Characterization of Terminal Iron(III)-Oxo and Iron(III)-Hydroxo Complexes Derived from O2 Activation

Gordon, Z., Miller, T. J., Leahy, C. A., Matson, E. M., Burgess, M., Drummond, M. J., Popescu, C. V., Smith, C. M., Lord, R. L., Rodríguez-López, J. & Fout, A. R., Dec 2 2019, In : Inorganic Chemistry. 58, 23, p. 15801-15811 11 p.

Research output: Contribution to journalArticle

Electronic Ligand Modifications on Cobalt Complexes and Their Application toward the Semi-Hydrogenation of Alkynes and Para-Hydrogenation of Alkenes

Muhammad, S. R., Nugent, J. W., Tokmic, K., Zhu, L., Mahmoud, J. & Fout, A. R., Aug 26 2019, In : Organometallics. 38, 16, p. 3132-3138 7 p.

Research output: Contribution to journalArticle

Radical Rebound Hydroxylation Versus H-Atom Transfer in Non-Heme Iron(III)-Hydroxo Complexes: Reactivity and Structural Differentiation

Drummond, M. J., Ford, C. L., Gray, D. L., Popescu, C. V. & Fout, A. R., Apr 24 2019, In : Journal of the American Chemical Society. 141, 16, p. 6639-6650 12 p.

Research output: Contribution to journalArticle

Synthesis and Characterization of (DIPPCCC)Fe Complexes: A Zwitterionic Metalation Method and CO2 Reactivity

Jackson, B. J., Najera, D. C., Matson, E. M., Woods, T. J., Bertke, J. A. & Fout, A. R., Aug 12 2019, In : Organometallics. 38, 15, p. 2943-2952 10 p.

Research output: Contribution to journalArticle

Open Access
2018

13C NMR Signal Enhancement Using Parahydrogen-Induced Polarization Mediated by a Cobalt Hydrogenation Catalyst

Tokmic, K., Greer, R. B., Zhu, L. & Weitzel, A. R., Nov 7 2018, In : Journal of the American Chemical Society. 140, 44, p. 14844-14850 7 p.

Research output: Contribution to journalArticle

Simple Nickel Salts for the Amination of (Hetero)aryl Bromides and Iodides with Lithium Bis(trimethylsilyl)amide

Martinez, G. E., Nugent, J. W. & Fout, A. R., Sep 24 2018, In : Organometallics. 37, 18, p. 2941-2944 4 p.

Research output: Contribution to journalArticle

2017

Cobalt-Catalyzed and Lewis Acid-Assisted Nitrile Hydrogenation to Primary Amines: A Combined Effort

Tokmic, K., Jackson, B. J., Salazar, A., Woods, T. J. & Fout, A. R., Jan 1 2017, In : Journal of the American Chemical Society. 139, 38, p. 13554-13561 8 p.

Research output: Contribution to journalArticle

Insights into a Chemoselective Cobalt Catalyst for the Hydroboration of Alkenes and Nitriles

Ibrahim, A. D., Entsminger, S. W. & Fout, A. R., May 5 2017, In : ACS Catalysis. 7, 5, p. 3730-3734 5 p.

Research output: Contribution to journalArticle

Synthesis and Characterization of Bidentate NHC-CAryl Nickel(II) Complexes: Isocyanide Insertion to Form NHC-n2-iminoacyl Complexes

Nugent, J. W., Espinosa Martinez, G., Gray, D. L. & Fout, A. R., Aug 14 2017, In : Organometallics. 36, 15, p. 2987-2995 9 p.

Research output: Contribution to journalArticle

Tuning the Fe(II/III) Redox Potential in Nonheme Fe(II)-Hydroxo Complexes through Primary and Secondary Coordination Sphere Modifications

Gordon, Z., Drummond, M. J., Matson, E. M., Bogart, J. A., Schelter, E. J., Lord, R. L. & Fout, A. R., May 1 2017, In : Inorganic Chemistry. 56, 9, p. 4852-4863 12 p.

Research output: Contribution to journalArticle

2016

A bioinspired iron catalyst for nitrate and perchlorate reduction

Ford, C. L., Park, Y. J., Matson, E. M., Gordon, Z. & Fout, A. R., Nov 11 2016, In : Science. 354, 6313, p. 741-743 3 p.

Research output: Contribution to journalArticle

Accessing Pincer Bis(carbene) Ni(IV) Complexes from Ni(II) via Halogen and Halogen Surrogates

Martinez, G. E., Ocampo, C., Park, Y. J. & Fout, A. R., Apr 20 2016, In : Journal of the American Chemical Society. 138, 13, p. 4290-4293 4 p.

Research output: Contribution to journalArticle

A Highly Chemoselective Cobalt Catalyst for the Hydrosilylation of Alkenes using Tertiary Silanes and Hydrosiloxanes

Ibrahim, A. D., Entsminger, S. W., Zhu, L. & Fout, A. R., Jun 3 2016, In : ACS Catalysis. 6, 6, p. 3589-3593 5 p.

Research output: Contribution to journalArticle

Alkyne Semihydrogenation with a Well-Defined Nonclassical Co-H2 Catalyst: A H2 Spin on Isomerization and E-Selectivity

Tokmic, K. & Fout, A. R., Oct 19 2016, In : Journal of the American Chemical Society. 138, 41, p. 13700-13705 6 p.

Research output: Contribution to journalArticle

Monoanionic bis(carbene) pincer complexes featuring cobalt(I-III) oxidation states

Ibrahim, A. D., Tokmic, K., Brennan, M. R., Kim, D., Matson, E. M., Nilges, M. J., Bertke, J. A. & Fout, A. R., Jan 1 2016, In : Dalton Transactions. 45, 24, p. 9805-9811 7 p.

Research output: Contribution to journalArticle

Well-Defined Cobalt(I) Dihydrogen Catalyst: Experimental Evidence for a Co(I)/Co(III) Redox Process in Olefin Hydrogenation

Tokmic, K., Markus, C. R., Zhu, L. & Fout, A. R., Sep 14 2016, In : Journal of the American Chemical Society. 138, 36, p. 11907-11913 7 p.

Research output: Contribution to journalArticle

2015

Exploring Mn-O bonding in the context of an electronically flexible secondary coordination sphere: Synthesis of a Mn(iii)-oxo

Park, Y. J., Matson, E. M., Nilges, M. J. & Fout, A. R., Mar 28 2015, In : Chemical Communications. 51, 25, p. 5310-5313 4 p.

Research output: Contribution to journalArticle

Nickel(II) pincer carbene complexes: Oxidative addition of an aryl C-H bond to form a Ni(II) hydride

Matson, E. M., Espinosa Martinez, G., Ibrahim, A. D., Jackson, B. J., Bertke, J. A. & Weitzel, A. R., Jan 26 2015, In : Organometallics. 34, 2, p. 399-407 9 p.

Research output: Contribution to journalArticle

Synthesis and characterization of M(II) (M = Mn, Fe and Co) azafulvene complexes and their X3- derivatives

Matson, E. M., Park, Y. J., Bertke, J. A. & Fout, A. R., Jun 14 2015, In : Dalton Transactions. 44, 22, p. 10377-10384 8 p.

Research output: Contribution to journalArticle

2014

A synthetic and mechanistic investigation into the cobalt(i) catalyzed amination of aryl halides

Brennan, M. R., Kim, D. & Fout, A. R., Dec 1 2014, In : Chemical Science. 5, 12, p. 4831-4839 9 p.

Research output: Contribution to journalArticle

Dehydrogenation of hydrocarbons with metal-carbon multiple bonds and trapping of a titanium(ii) intermediate

Hickey, A. K., Crestani, M. G., Fout, A. R., Gao, X., Chen, C. H. & Mindiola, D. J., Jul 14 2014, In : Dalton Transactions. 43, 26, p. 9834-9837 4 p.

Research output: Contribution to journalArticle

Facile nitrite reduction in a non-heme iron system: Formation of an iron(III)-oxo

Matson, E. M., Park, Y. J. & Weitzel, A. R., Dec 17 2014, In : Journal of the American Chemical Society. 136, 50, p. 17398-17401 4 p.

Research output: Contribution to journalArticle

Isolation of Iron(II) aqua and hydroxyl complexes featuring a tripodal H-bond donor and acceptor ligand

Matson, E. M., Bertke, J. A. & Fout, A. R., May 5 2014, In : Inorganic Chemistry. 53, 9, p. 4450-4458 9 p.

Research output: Contribution to journalArticle

Meridional vs. facial coordination geometries of a dipodal ligand framework featuring a secondary coordination sphere

Matson, E. M., Gordon, Z., Lin, B., Nilges, M. J. & Fout, A. R., Dec 7 2014, In : Dalton Transactions. 43, 45, p. 16992-16995 4 p.

Research output: Contribution to journalArticle

2013

Synthesis of open-shell, bimetallic Mn/Fe trinuclear clusters

Powers, T. M., Gu, N. X., Fout, A. R., Baldwin, A. M., Hernández Sánchez, R., Alfonso, D. M., Chen, Y. S., Zheng, S. L. & Betley, T. A., Sep 25 2013, In : Journal of the American Chemical Society. 135, 38, p. 14448-14458 11 p.

Research output: Contribution to journalArticle

2012

Trigonal Mn 3 and Co 3 clusters supported by weak-field ligands: A structural, spectroscopic, magnetic, and computational investigation into the correlation of molecular and electronic structure

Fout, A. R., Xiao, D. J., Zhao, Q., Harris, T. D., King, E. R., Eames, E. V., Zheng, S. L. & Betley, T. A., Oct 1 2012, In : Inorganic Chemistry. 51, 19, p. 10290-10299 10 p.

Research output: Contribution to journalArticle

2011

1,2-CF bond activation of perfluoroarenes and alkylidene isomers of titanium. DFT analysis of the C-F bond activation pathway and rotation of the titanium alkylidene moiety

Andino, J. G., Fan, H., Fout, A. R., Bailey, B. C., Baik, M. H. & Mindiola, D. J., Dec 15 2011, In : Journal of Organometallic Chemistry. 696, 25, p. 4138-4146 9 p.

Research output: Contribution to journalArticle

Atom-economical route to substituted pyridines via a scandium imide

Wicker, B. F., Scott, J., Fout, A. R., Pink, M. & Mindiola, D. J., May 9 2011, In : Organometallics. 30, 9, p. 2453-2456 4 p.

Research output: Contribution to journalArticle

Oxidative atom-transfer to a trimanganese complex to form Mn 66-E) (E = O, N) clusters featuring interstitial oxide and nitride functionalities

Fout, A. R., Zhao, Q., Xiao, D. J. & Betley, T. A., Oct 26 2011, In : Journal of the American Chemical Society. 133, 42, p. 16750-16753 4 p.

Research output: Contribution to journalArticle

Oxidative group transfer to a triiron complex to form a nucleophilic μ3-nitride, [Fe33-N)]-

Powers, T. M., Fout, A. R., Zheng, S. L. & Betley, T. A., Mar 16 2011, In : Journal of the American Chemical Society. 133, 10, p. 3336-3338 3 p.

Research output: Contribution to journalArticle

2010

Synthetic and mechanistic studies of the ring opening and denitrogenation of pyridine and picolines by Ti-C multiple bonds

Weitzel, A. R., Bailey, B. C., Buck, D. M., Fan, H., Huffman, J. C., Baik, M. H. & Mindiola, D. J., Nov 8 2010, In : Organometallics. 29, 21, p. 5409-5422 14 p.

Research output: Contribution to journalArticle

2009

Dehydrofluorination of hydrofluorocarbons by titanium alkylidynes via sequential C-H/C-F bond activation reactions. A synthetic, structural, and mechanistic study of 1,2-CH bond addition and β-fluoride elimination

Fout, A. R., Scott, J., Miller, D. L., Bailey, B. C., Pink, M. & Mindiola, D. J., Jan 12 2009, In : Organometallics. 28, 1, p. 331-347 17 p.

Research output: Contribution to journalArticle

2008

A transient VIII-alkylidene complex: Oxidation chemistry including the activation of N2 to afford a highly porous honeycomb-like framework

Kilgore, U. J., Sengelaub, C. A., Pink, M., Fout, A. R. & Mindiola, D. J., May 5 2008, In : Angewandte Chemie - International Edition. 47, 20, p. 3769-3772 4 p.

Research output: Contribution to journalArticle

Evidence for the existence of a terminal imidoscandium compound: Intermolecular C-H activation and complexation reactions with the transient Sc=NAr species

Scott, J., Basuli, F., Fout, A. R., Huffman, J. C. & Mindiola, D. J., Oct 20 2008, In : Angewandte Chemie - International Edition. 47, 44, p. 8502-8505 4 p.

Research output: Contribution to journalArticle

Lewis acid stabilized methylidene and oxoscandium complexes

Scott, J., Fan, H., Wicker, B. F., Fout, A. R., Baik, M. H. & Mindiola, D. J., Nov 5 2008, In : Journal of the American Chemical Society. 130, 44, p. 14438-14439 2 p.

Research output: Contribution to journalArticle

2007

An alkylidyne analogue of Tebbe's reagent: Trapping reactions of a titanium neopentylidyne by incomplete and complete 1,2-additions

Bailey, B. C., Fout, A. R., Fan, H., Tomaszewski, J., Huffman, J. C. & Mindiola, D. J., Nov 19 2007, In : Angewandte Chemie - International Edition. 46, 43, p. 8246-8249 4 p.

Research output: Contribution to journalArticle

Cyclic denitrogenation of N-heterocycles applying a homogeneous titanium reagent

Fout, A. R., Bailey, B. C., Tomaszewski, J. & Mindiola, D. J., Oct 24 2007, In : Journal of the American Chemical Society. 129, 42, p. 12640-12641 2 p.

Research output: Contribution to journalArticle

Snapshots of an alkylidyne for nitride triple-bond metathesis

Bailey, B. C., Fout, A. R., Fan, H., Tomaszewski, J., Huffman, J. C., Gary, J. B., Johnson, M. J. A. & Mindiola, D. J., Feb 28 2007, In : Journal of the American Chemical Society. 129, 8, p. 2234-2235 2 p.

Research output: Contribution to journalArticle

The progression of synthetic strategies to assemble titanium complexes bearing the terminal imide group

Fout, A. R., Kilgore, U. J. & Mindiola, D. J., Dec 7 2007, In : Chemistry - A European Journal. 13, 34, p. 9428-9440 13 p.

Research output: Contribution to journalArticle

2006

A Co2N2 diamond-core resting state of cobalt(I): A three-coordinate CoI synthon invoking an unusual pincer-type rearrangement

Fout, A. R., Basuli, F., Fan, H., Tomaszewski, J., Huffman, J. C., Baik, M. H. & Mindiola, D. J., May 12 2006, In : Angewandte Chemie - International Edition. 45, 20, p. 3291-3295 5 p.

Research output: Contribution to journalArticle

2005

Manganese(I) poly(mercaptoimidazolyl)borate complexes: Spectroscopic and structural characterization of Mn ⋯ H-B interactions in solution and in the solid state

Graham, L. A., Fout, A. R., Kuehne, K. R., White, J. L., Mookherji, B., Marks, F. M., Yap, G. P. A., Zakharov, L. N., Rheingold, A. L. & Rabinovich, D., Jan 7 2005, In : Dalton Transactions. 1, p. 171-180 10 p.

Research output: Contribution to journalArticle

Titanium complexes supported by a sterically encumbering N-anchored tris-arylphenoxide ligand

Cortes, S. A., Muñoz Hernández, M. A., Nakai, H., Castro-Rodriguez, I., Meyer, K., Fout, A. R., Miller, D. L., Huffman, J. C. & Mindiola, D. J., Oct 1 2005, In : Inorganic Chemistry Communications. 8, 10, p. 903-907 5 p.

Research output: Contribution to journalArticle